Abstract: A probe coil for an NMR apparatus including a superconductor coil formed from a superconductor made of magnesium 2-boride formed on the surface of a substrate, and a coil bobbin around which the superconductor coil is wound, wherein the substrate is made of a material that contains no hydrogen atoms.

Abstract: A superconducting magnet configured for an NMR spectrometer includes a split type superconducting magnet having left solenoid superconducting magnets and right solenoid superconducting magnets with a center space therebetween for receiving a sample tube. A permanent current switch is provided and the left and right solenoid superconducting magnets are arranged symmetrically with respect to a center face of the center space. The left and right solenoid superconducting magnets are constituted by an outermost magnet and a plurality of innermost magnets and are arranged in concentric relation with respect to a vertical axis of the center space. A direction of current in at least one of the plurality of innermost magnets is minus when a direction of current in the outermost magnet is plus.

Abstract: In a nuclear magnetic resonance spectrometer, the shape of a detection coil is changed from a conventional cage type to a solenoid type of higher sensitivity. Accordingly, differing from the conventional superconductive magnet of multilayer air core solenoids, a superconductive magnet is right and left divided to split magnets for generating 11 T preferably, 14.1 T in the horizontal direction, and the magnetic field uniformity is set to 0.001 ppm or less and the temporal stability is set to 0.001 ppm or less.

Abstract: There is disclosed a permanent current switch which has a high temperature margin and which is thermally stable and which securely performs a switching operation between a superconducting state and a normal conducting state. The permanent current switch of the present invention has a coiled superconducting wire and a heater wire which switches the superconducting wire between the superconducting state and the normal conducting state, the superconducting wire is a magnesium diboride superconducting wire having a high-resistance metal on an outer side and a magnesium diboride superconducting portion on an inner side and prepared by forming a superconducting metal on a layer between the high-resistance metal and the magnesium diboride superconducting portion, and the permanent current switch further comprises a superconductive connecting section superconductively connected to a lead wire guided from the superconducting wire and a superconducting wire for a wiring line.

Abstract: In an NMR apparatus provided with a split type magnet, in order to position a probe at a high precision in a narrow homogeneous magnetic field space, a positioning of a center of a probe coil is first located to a proper position by inserting an NMR probe from a horizontal bore. At this position, a sample tube is inserted from a vertical bore, and an NMR signal is measured from the probe coil. An NMR signal measuring apparatus amplifies the NMR signal from the probe coil, and executes an A/D conversion so as to determine an NMR spectrum signal, and an NMR signal analyzing apparatus compares the NMR spectrum signal. A probe is set at a position where a sharpness of the spectrum is largest, that is, a magnetic field homogeneity coefficient is high, by repeating the operations mentioned above.

Abstract: It is an object of the present invention to provide means for forming a good bonded interface with a high process yield in the bonding of metal surfaces. Provided is a method of bonding metal surfaces together, and this method includes the steps of: forming a metal-added layer on one metal surface; forming a metal film, which is made of a metal of the same kind as the other metal surface or a metal capable of being alloyed with the other metal surface, as a layer above the metal-added layer; and performing large deformation, with the other metal surface brought into close contact with the metal film.

Abstract: An NMR apparatus which includes an NMR probe coil of a superconductor made of magnesium 2-boride formed on the surface of a substrate made of a flexible organic polymer material.

Abstract: The invention provides a low temperature probe having a high sensitivity by reducing a heat intrusion into a receive coil. A heat making an intrusion into a coil is suppressed by inserting a heat radiation shield in which a temperature is controlled at about 100 K to a portion between an outer container of a probe and a coil portion. A heat radiation shield bore sleeve is provided in a heat radiation bore, is connected to the heat radiation shield, and is cooled by a second heat exchanger. Further, the coil portion is cooled by a first heat exchanger. In preparation for a contraction at a time of being cooled, the outer container, the heat radiation shield and the coil portion are connected by using a fixing portion, and a heat relieving mechanism or a contraction relieving mechanism is provided in a root side (an opposite side to the fixing portion) of the heat radiation shield and the coil portion.

Abstract: A first room-temperature space is formed penetrating through a cryostat along a center axis of a split-type multi-layer cylindrical superconducting coil system which has a ratio of the maximum empirical magnetic field to the central magnetic field of not larger than 1.3 and is horizontally arranged such that the center axis of the coil is in the horizontal direction, a room-temperature shim coil system is arranged in said first room-temperature space to improve the homogeneity of the magnetic field, a second room-temperature space is formed penetrating through the cryostat and passing through the center of said split gap in the vertical direction, and a sample to be measured and an NMR probe having a solenoid-type probe coil are inserted in said second room-temperature space. Further, the NMR analyzer has a new function constituted by a system for irradiating and detecting the electromagnetic waves having wavelengths of shorter than 0.1 mm.

Abstract: A first room-temperature space is formed penetrating through a cryostat along a center axis of a split-type multi-layer cylindrical superconducting coil system which has a ratio of the maximum empirical magnetic field to the central magnetic filed of not larger than 1.3 and is horizontally arranged such that the center axis of the coil is in the horizontal direction, a room-temperature shim coil system is arranged in said first room-temperature space to improve the homogeneity of the magnetic field, a second room-temperature space is formed penetrating through the cryostat and passing through the center of said split gap in the vertical direction, and a sample to be measured and an NMR probe having a solenoid-type probe coil are inserted in said second room-temperature space. Further, the NMR analyzer has a new function constituted by a system for irradiating and detecting the electromagnetic waves having wavelengths of shorter than 0.1 mm.

Abstract: In a nuclear magnetic resonance spectrometer, the shape of a detection coil is changed from a conventional cage type to a solenoid type of higher sensitivity. Accordingly, differing from the conventional superconductive magnet of multilayer air core solenoids, a superconductive magnet is right and left divided to split magnets for generating 11 T, preferably, 14.1 T in the horizontal direction, and the magnetic field uniformity is set to 0.001 ppm or less and the temporal stability is set to 0.001 ppm or less.

Abstract: A magnet for an NMR analyzer includes a superconductor coil for generating a magnetic field in a magnetic space surrounded by the superconductor coil. The superconductor coil has a shim coil group disposed at least one of inside and outside of the superconducting coil. The superconducting coil provides a first access port for receiving a probe inserted into the magnetic space along a central axis thereof and a second access port having one end for receiving a sample tube containing a sample inserted into the magnetic space in a direction transverse to the central axis of the magnetic space. The second access port is open at an other end thereof.

Abstract: A magnet for an NMR an analyzer includes a superconductor coil which is operated under a permanent current mode so as to generate a magnetic field in a space surrounded by the superconductor coil, and which enables a sample to be inserted into a measurement space in the magnetic space for analization. The superconductor coil includes a first access port for enabling access to the measurement space and a second access port for enabling insertion of the sample into the measurement space in a direction different from a direction of the first access port. An effective diameter of the first access port is larger than an effective diameter of the second access port when the effective diameters of the first and second access ports are defined as a diameter of a cylinder that is insertable into the first and second access ports.

Abstract: A configuration of an NMR apparatus is provided. In the NMR apparatus, a magnetic field space of higher uniformity is generated by split superconducting magnets. At the same time, it is provided with a cryo probe excellent in cooling capability and sensitivity between two superconducting solenoid coils constructed in very close proximity to each other. For this purpose, a probe coil provided between the two superconducting solenoid coils is so constructed that the following is implemented: a certain distance is ensured between a substrate with a coil formed thereon and another, and the substrates and spacer substrates for cooling are alternately laminated. The spacer substrates are cooled by a cold head of sapphire. When the probe coil is inserted in the same direction as a sample tube (direction perpendicular to the static magnetic field), the spacer substrates cannot be coupled directly by the cold head of sapphire.

Abstract: A superconducting magnet device configured for an NMR spectrometer includes a split type superconducting magnet having left and right solenoid superconducting magnets, wherein the split type superconducting magnet has a center space around a vertical center axis between the left and right solenoid superconducting magnets, a sample tube placed in the center space in order to enable placement of a sample therein, which is energized by the magnetic field generated by the split type superconducting magnet, a solenoid coil configured for detecting signals due to magnetic resonance from the energized sample, and a permanent current switch for holding the split type superconducting magnet to a permanent current mode.

Abstract: A method of producing an electrical connection structure between at least two superconducting lines. The method comprises adding metal powder or alloy powder to a superconducting material comprising magnesium diboride, intervening the superconducting material between at least two superconducting lines, and heating said superconducting lines and said superconducting material to a temperature lower than the melting point of said superconducting material prior to the addition of said metal powder or alloy powder thereto, but higher than the melting point of said metal powder or alloy powder.

Abstract: To access a measurement space located at the center of the magnet, an access port is provided in the direction of the magnet's axis, a clearance is provided in the coil winding portion, and another access port passes through the clearance so that a sample can be positioned perpendicularly to the coil axis. According to this configuration, an access port passing through the coil winding portion can be smaller than the access port passing through the coil axis, a sample is inserted from the access port, and a probe is inserted from the access port passing through the magnet axis, and thus the clearance can be minimized.

Abstract: An NMR system that enables multiplex resonance measurement includes a superconductivity reception coil, a transmission coil, and four electric current loops. The NMR system also includes an additional coil in which directions of currents that flow in an inner loop and an outer loop are opposite to each other. The additional coil and the transmission coil are arranged such that a direction of a high frequency magnetic field that is developed in the center of the additional coil when electricity is fed to the additional coil is substantially identical with a direction of a high frequency magnetic field that is developed in the center of the transmission coil when electricity is fed to the transmission coil. The electric current loop of the transmission coil is arranged substantially in the middle of the inner loop and the outer loop of the additional coil in which directions of electric currents that flow in the inner loop and the outer loop are opposite to each other.

Abstract: A nuclear magnetic resonance apparatus comprises a superconducting magnet that produces a static magnetic field, a probe having a probe coil that irradiates an RF pulse magnetic field and receives a free induction decay signal (FID signal) emitted therefrom, an RF power source that supplies the probe with an RF current, an amplifier that amplifies the FID signal, a detector that detects a signal, and an analyzer that analyzes the signal detected by the detector, wherein the probe coil includes a solenoid coil and a saddle type coil.

Abstract: A superconducting magnet configured for an NMR spectrometer includes a split type superconducting magnet having left solenoid superconducting magnets and right solenoid superconducting magnets with a center space therebetween for receiving a sample tube. A permanent current switch is provided and the left and right solenoid superconducting magnets are arranged symmetrically with respect to a center face of the center space. The left and right solenoid superconducting magnets are constituted by an outermost magnet and a plurality of innermost magnets and are arranged in concentric relation with respect to a vertical axis of the center space. A direction of current in at least one of the plurality of innermost magnets is minus when a direction of current in the outermost magnet is plus.