Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of a second surface of the element body on a side opposite to the first surface and including one or more exposed spaces (a lower space) to which the second surface is exposed.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of the first surface of the element body and including one or more exposed spaces (an upper space) to which the first surface is exposed.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of the first surface of the element body and including one or more spaces (an upper space) that are present apart from the first surface in a direction perpendicular to the first surface.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of a second surface of the element body on a side opposite to the first surface and including one or more spaces (a lower space) that are present apart from the second surface in a direction perpendicular to the second surface.

Abstract: In a sensor element, a fourth diffusion rate-controlling portion includes a diffusion rate-controlling portion. The diffusion rate-controlling portion is formed between one or more and three or less surfaces, e.g., an upper surface, of upper, lower, left and right inner peripheral surfaces of a measurement-object gas flowing portion and a partition wall. A measurement electrode is formed on one, e.g., a lower surface, of upper, lower, left and right inner peripheral surfaces of a third inner cavity, the one surface being different in orientation from the Csurface along which the diffusion rate-controlling portion is formed. The diffusion rate-controlling portion and the measurement electrode may be formed on surfaces opposite to each other. A distance L between the measurement electrode and the diffusion rate-controlling portion may be 0.1 mm or more.

Abstract: A gas sensor includes a sensor element that includes a gas inlet through which a measurement target gas is introduced into the sensor element and a protective cover that contains a substance having a capability of decomposing ammonia. The protective cover has a gas-contact surface area within a range of 450 mm2 to 1145 mm2, the gas-contact surface area being a sum of a surface area of a portion facing the inlet-side gas flow path and a surface area of a portion facing an in-element-chamber flow path of the sensor element chamber that is a shortest flow path for the measurement target gas from the element-chamber inlet to the gas inlet.

Abstract: The gas sensor 100 has a gas flow channel 127 formed therein by an inner protection cover 130. The gas flow channel 127 is formed in the pathway of measured gas from a first outer gas hole 144a formed in an outer protection cover 140 that covers the tip end of a sensor element 110 to a gas inlet port 111 of the sensor element 110. The gas flow channel 127 extends from the rear end side to the tip end side of the sensor element 110 and is open to the sensor element chamber 124 having the gas inlet port 111 disposed therein.

Abstract: First inner gas holes 134a and first outer gas holes 144a of a gas sensor are formed so that the following conditions are satisfied: a first-inner-hole count Nin?3, 0<an inner/outer hole count ratio Nr?0.5, and 0<an inner/outer hole-area ratio Ar?0.25, where the first-inner-hole count Nin represents the number of first inner gas holes 134a, a first-inner-hole average area Ain [mm2] represents (the total opening area of the first inner gas holes 134a)/(the first-inner-hole count Nin), a first-outer-hole count Nout represents the number of the first outer gas holes 144a, a first-outer-hole average area Aout represents (the total opening area of the first outer gas holes 144a)/(the first-outer-hole count Nout), the inner/outer hole count ratio Nr represents the first-inner-hole count Nin/the first-outer-hole count Nout, and the inner/outer hole-area ratio Ar represents the first-inner-hole average area Ain/the first-outer-hole average area Aout.

Abstract: A sensor element 101 of a gas sensor 100 includes a blocking portion 65 including an outer blocking layer 67 that is formed to cover, in an upper surface of a multilayer body, at least a part of an upper closest region 6a where an outer pump electrode 23 is not disposed and a distance up to a third inner cavity 61 is minimal. The outer blocking layer 67 does not have conductivity for one or more among various types of substances containing oxygen. The outer blocking layer 67 is disposed between a lead line 93 for the outer pump electrode and the upper surface of the multilayer body to provide insulation therebetween, and is disposed between an upper connector pad 91 and the upper surface of the multilayer body to provide insulation therebetween. A porous protective layer 24 covers the outer pump electrode 23.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of a second surface of the element body on a side opposite to the first surface and including one or more exposed spaces (a lower space) to which the second surface is exposed.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of the first surface of the element body and including one or more spaces (an upper space) that are present apart from the first surface in a direction perpendicular to the first surface.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of the first surface of the element body and including one or more exposed spaces (an upper space) to which the first surface is exposed.

Abstract: A sensor element includes an element body having an elongate rectangular parallelepiped shape and including solid electrolyte layers with oxygen ion conductivity, an outer pump electrode disposed on a first surface of the element body, and a protective layer covering at least a part of a second surface of the element body on a side opposite to the first surface and including one or more spaces (a lower space) that are present apart from the second surface in a direction perpendicular to the second surface.

Abstract: A gas sensor includes a sensor element that includes a gas inlet through which a measurement target gas is introduced into the sensor element and a protective cover that contains a substance having a capability of decomposing ammonia. The protective cover has a gas-contact surface area within a range of 450 mm2 to 1145 mm2, the gas-contact surface area being a sum of a surface area of a portion facing the inlet-side gas flow path and a surface area of a portion facing an in-element-chamber flow path of the sensor element chamber that is a shortest flow path for the measurement target gas from the element-chamber inlet to the gas inlet.

Abstract: The gas sensor 100 has a gas flow channel 127 formed therein by an inner protection cover 130. The gas flow channel 127 is formed in the pathway of measured gas from a first outer gas hole 144a formed in an outer protection cover 140 that covers the tip end of a sensor element 110 to a gas inlet port 111 of the sensor element 110. The gas flow channel 127 extends from the rear end side to the tip end side of the sensor element 110 and is open to the sensor element chamber 124 having the gas inlet port 111 disposed therein.

Abstract: First inner gas holes 134a and first outer gas holes 144a of a gas sensor are formed so that the following conditions are satisfied: a first-inner-hole count Nin?3, 0<an inner/outer hole count ratio Nr?0.5, and 0<an inner/outer hole-area ratio Ar?0.25, where the first-inner-hole count Nin represents the number of first inner gas holes 134a, a first-inner-hole average area Ain [mm2] represents (the total opening area of the first inner gas holes 134a)/(the first-inner-hole count Nin), a first-outer-hole count Nout represents the number of the first outer gas holes 144a, a first-outer-hole average area Aout represents (the total opening area of the first outer gas holes 144a)/(the first-outer-hole count Nout), the inner/outer hole count ratio Nr represents the first-inner-hole count Nin/the first-outer-hole count Nout, and the inner/outer hole-area ratio Ar represents the first-inner-hole average area Ain/the first-outer-hole average area Aout.

Abstract: In a gas sensor, a ratio A2/A1 defined by a ratio of an opening area A1 per first inner gas hole and an opening area A2 per second inner gas hole is set to higher than or equal to 0.9 and lower than or equal to 3.8 and, more preferably, to higher than or equal to 1.5 and lower than or equal to 1.9. Accordingly, adhesion of water to a sensor element can be sufficiently prevented. In addition, a ratio B2/B1 defined by a ratio of a total opening area B1 of the first inner gas holes to a total opening area B2 of the second inner gas holes is set to higher than or equal to 0.85 and, more preferably, higher than or equal to 1.5. Accordingly, adhesion of water to the sensor element can be more reliably, effectively prevented.

Abstract: A sensor element 101 of a gas sensor 100 includes a blocking portion 65 including an outer blocking layer 67 that is formed to cover, in an upper surface of a multilayer body, at least a part of an upper closest region 6a where an outer pump electrode 23 is not disposed and a distance up to a third inner cavity 61 is minimal. The outer blocking layer 67 does not have conductivity for one or more among various types of substances containing oxygen. The outer blocking layer 67 is disposed between a lead line 93 for the outer pump electrode and the upper surface of the multilayer body to provide insulation therebetween, and is disposed between an upper connector pad 91 and the upper surface of the multilayer body to provide insulation therebetween. A porous protective layer 24 covers the outer pump electrode 23.

Abstract: In a sensor element 101, a fourth diffusion rate-controlling portion 54 includes a diffusion rate-controlling portion 54a. The diffusion rate-controlling portion 54a is formed between one or more and three or less surfaces, e.g., an upper surface 58a, of upper, lower, left and right inner peripheral surfaces of a measurement-object gas flowing portion and a partition wall 56. A measurement electrode 44 is formed on one, e.g., a lower surface 62b, of upper, lower, left and right inner peripheral surfaces of a third inner cavity 61, the one surface being different in orientation from the surface along which the diffusion rate-controlling portion 54a is formed. The diffusion rate-controlling portion 54 and the measurement electrode 44 may be formed on surfaces opposite to each other. A distance L between the measurement electrode 44 and the diffusion rate-controlling portion 54a may be 0.1 mm or more.

Abstract: A method of the present invention is a method for producing a film laminated structure, including the steps of: (a) preparing a substrate; (b) achieving a state that a mold is charged with a slurry that contains a raw material powder, a gelling agent containing at least two polymerizable organic compounds, and an organic solvent serving as a dispersion medium, and that the substrate is placed at a predetermined position in the mold; (c) molding and hardening the slurry through a polymerization reaction of the gelling agent to combine the substrate and a green film to form a green structure; and (d) firing the green structure to form a film laminated structure, the film laminated structure including a porous film formed from the green film by firing.