Abstract: The present invention generally relates to a method for producing hybrid materials of thin polymer films with single, laminated, complete and/or partially embedded nanofibers to obtain products with unique functional properties. In one embodiment, the present relates to a hybrid process that utilizes both melt casting and electrospinning to produce nanofiber embedded functional films. In another embodiment, the process of the present invention involves nanofiber-containing products that are formed by producing a plurality of nanofibers via one or more nanofiber producing nozzles; depositing such nanofibers onto a melt cast polymer film; and either partially and/or completely embedding such nanofibers into the melt cast polymer film via one or more electrical forces.