Patents by Inventor Milan Fedurco

Milan Fedurco has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20170137993
    Abstract: A threadlike metallic or metallized reinforcer, for example a thread, film, tape or cord made of carbon steel, at the periphery of which is positioned a layer of metal referred to as “surface metal” chosen from copper, nickel and copper/nickel alloys, is characterized in that this surface metal layer is itself coated, at least in part, with at least one layer of graphene; preferably, there is grafted, to this graphene, at least one functional group which can crosslink to a polymer matrix. This reinforcer of the invention is effectively protected from corrosion by virtue of the graphene present at the surface; advantageously, it can be adhesively bonded directly, without adhesion primer or addition of metal salt, to an unsaturated rubber matrix, such as natural rubber, by virtue of the possible functionalization of this graphene.
    Type: Application
    Filed: May 20, 2015
    Publication date: May 18, 2017
    Inventors: ROBERT NIKOLAUS GRASS, WENDELIN JAN STARK, MILAN FEDURCO, ANTONIO DELFINO, JEAN-PAUL MERALDI
  • Publication number: 20170121806
    Abstract: A process for depositing, with forward progression, graphene on the surface of a metallic or metallized continuous reinforcer, at the periphery of which is positioned a layer of surface metal chosen from copper, nickel and copper/nickel alloys, comprises at least one stage of flame spray pyrolysis (“FSP”), under a reducing atmosphere, of a carbon precursor which generates, in the flame, at least one carbon-based gas such as carbon monoxide which is sprayed onto the surface of the reinforcer in forward progression, and is decomposed thereon to form one or more graphene layers at the surface of the surface metal; an additional stage of graphene functionalization makes it possible to adhere the reinforcer to a polymer matrix such as rubber.
    Type: Application
    Filed: May 20, 2015
    Publication date: May 4, 2017
    Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: WENDELIN JAN STARK, ROBERT NIKOLAUS GRASS, Milan Fedurco, ANTONIO DELFINO, JEAN-PAUL MERALDI
  • Patent number: 9617372
    Abstract: A sulphur-comprising polyaromatic polyamine compound can be used as a monomer or prepolymer, when n is different from zero, in the synthesis of polyurea. The compound corresponds to the formula (I): H2N—Ar1—NH—CH2—CH(OH)—(CH2)m—O—Z1—O—(CH2)m—CH(OH)—CH2—[X]n—HN—Ar2—NH2 in which X represents the string: —HN—Ar3—NH—(CH2)—CH(OH)—(CH2)m—O—Z2—O—(CH2)m—CH(OH)—(CH2)— and in which n represents an integer equal to zero or different from zero; m, which are identical or different, represent an integer within a range from 1 to 10; Z1 and Z2, which are identical or different, represent a divalent bonding group comprising from 1 to 30 carbon atoms; and Ar1, Ar2 and Ar3, which are identical or different, each represent a phenylene group, at least one of these phenylene groups bearing one, two, three or four groups of formula —Sx—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon group which can comprise a heteroatom and which comprises from 1 to 10 carbon atoms.
    Type: Grant
    Filed: October 16, 2013
    Date of Patent: April 11, 2017
    Assignees: Compagnie Generale Des Etablissements Michelin, Michelin Recherche Et Technique S.A.
    Inventors: Milan Fedurco, Marco Ribezzo
  • Publication number: 20160208324
    Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using this additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.
    Type: Application
    Filed: February 22, 2016
    Publication date: July 21, 2016
    Applicant: Illumina Cambridge Limited
    Inventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
  • Publication number: 20160122460
    Abstract: A polymer has urethane or thiourethane units, which can be used, in particular, as an adhesion primer for the adhesive bonding of metal or glass to rubber. The polymer comprises base units comprising at least a sub-unit of formula —X1—CO—NH— in which X1 respectively represents O or S, and additional units comprising at least a secondary alcohol function and a thioether function in the ? position relative to the alcohol function. The polymer can be used as an adhesion primer for the adhesive bonding of a substrate, for example glass or metal, to an unsaturated rubber, or as a corrosion-resistant protective coating for a metal substrate. A metal reinforcer, such as wire, cord, film or plate, can be coated with the polymer.
    Type: Application
    Filed: April 18, 2014
    Publication date: May 5, 2016
    Inventors: MILAN FEDURCO, MARCO RIBEZZO, ANTONIO DELFINO
  • Patent number: 9303290
    Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using this additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.
    Type: Grant
    Filed: June 3, 2014
    Date of Patent: April 5, 2016
    Assignee: Illumina Cambridge Limited
    Inventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
  • Patent number: 9217178
    Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using the additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: December 22, 2015
    Assignee: Illumina Cambridge Limited
    Inventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
  • Publication number: 20150352900
    Abstract: A ready-for-use metal reinforcer, for example, of the wire or cord type, made of brass-coated carbon steel, is capable of adhering directly by vulcanization to a matrix of unsaturated rubber such as natural rubber. The surface of the reinforcer is provided with nanoparticles of at least one sulfide of a metal chosen from cobalt, copper, iron, zinc and the alloys comprising at least one of these elements. Such a reinforcer can be used as the reinforcing element of a finished article made of rubber, such as a tire.
    Type: Application
    Filed: December 16, 2013
    Publication date: December 10, 2015
    Inventors: ANTONIO DELFINO, MILAN FEDURCO, JEAN PAUL MERALDI, ROBERT NIKOLAUS GRASS, WENDELIN JAN STARK
  • Publication number: 20150307981
    Abstract: The surface of a body, in particular a metal reinforcer, at least the surface of which comprises a layer of metal referred to as surface metal capable of forming sulphides, is sulfurized. The metal can be chosen from copper, zinc and their alloys. The process comprises at least one stage of flame spray pyrolysis (FSP) of a sulphur-donating precursor, for example, thiophene, which generates hydrogen sulphide in the flame. The metal bodies or reinforcers thus treated can be directly adhesively bonded, without adhesion primer or addition of metal salt, such as a cobalt salt, to matrices of unsaturated rubber such as natural rubber.
    Type: Application
    Filed: December 16, 2013
    Publication date: October 29, 2015
    Inventors: ROBERT NIKOLAUS GRASS, MILAN FEDURCO, ANTONIO DELFINO, JEAN PAUL MERALDI, WENDELIN JAN STARK
  • Publication number: 20150274878
    Abstract: A sulphur-comprising polyaromatic polyamine compound can be used as a monomer or prepolymer, when n is different from zero, in the synthesis of polyurea. The compound corresponds to the formula (I): H2N—Ar1—NH—CH2—CH(OH)—(CH2)m—O—Z1—O—(CH2)m—CH(OH)—CH2—[X]n—HN—Ar2—NH2 in which X represents the string: —HN—Ar3—NH—(CH2)—CH(OH)—(CH2)m—O—Z2—O—(CH2)m—CH(OH)—(CH2)— and in which n represents an integer equal to zero or different from zero; m, which are identical or different, represent an integer within a range from 1 to 10; Z1 and Z2, which are identical or different, represent a divalent bonding group comprising from 1 to 30 carbon atoms; and Ar1, Ar2 and Ar3, which are identical or different, each represent a phenylene group, at least one of these phenylene groups bearing one, two, three or four groups of formula —Sx—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon group which can comprise a heteroatom and which comprises from 1 to 10 carbon atoms.
    Type: Application
    Filed: October 16, 2013
    Publication date: October 1, 2015
    Inventors: Milan Fedurco, Marco Ribezzo
  • Publication number: 20150259463
    Abstract: A polyurea comprises at least urea base units of formula —NH—CO—NH— and additional units. The additional units comprise at least, on the one hand, a secondary alcohol functional group and, on the other hand, an ether, thioether or secondary amine functional group in the alpha position with respect to the secondary alcohol functional group. Such a polymer can be used as an adhesion primer for the adhesive bonding of a substrate, for example, glass or metal, to an unsaturated rubber or as corrosion-resistant protective coating for a metal substrate. Metal reinforcers, such as thread, cord, film or plate, coated can also be coated with such a polymer.
    Type: Application
    Filed: October 16, 2013
    Publication date: September 17, 2015
    Inventors: Milan Fedurco, Marco Ribezzo, Antonio Delfino
  • Patent number: 9126907
    Abstract: A sulphur-containing and sulphonated aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer is a functionalized polymer that has a structure corresponding to a formula (I): E1-Ar1—X1—(CF2)n—X2—Ar2-E2??(I) in which: n is in a range from 1 to 20; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, which are identical or different, represent a phenylene group, at least one of Ar1 and Ar2 bearing a sulphonic (—SO3H) group or a sulphonate (—SO3M) group, in which M represents an alkali metal cation; and E1 and E2, which are identical or different, represent an electrophilic group such as a halogen, specifically fluorine or chlorine.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: September 8, 2015
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventor: Milan Fedurco
  • Patent number: 9120725
    Abstract: An aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer has a structure corresponding to a formula (I): Z1—Ar3—C(O)—Ar1—(CF2)n—Ar2—C(O)—Ar4—Z2??(I) in which: n is in a range from 1 to 20; Ar1, Ar2, Ar3, Ar4 which are identical or different, represent a substituted or unsubstituted phenylene group; and Z1 and Z2, which are identical or different, represent an electrophilic or nucleophilic polymerizable functional group.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: September 1, 2015
    Assignees: COMPAGNIE GENERALE DES ESTABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventor: Milan Fedurco
  • Patent number: 9035013
    Abstract: A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): in which: Tz represents a 1,3,5-triazine nucleus; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, Ar4 and Ar5, which are identical or different, represent a substituted or unsubstituted phenylene group; Ar3 represents a substituted or unsubstituted phenyl group; and Z1 and Z2, which are identical or different, are selected from a group that includes halogens, hydroxyl, alkoxyl, thiol, carboxyl, carboxylates, amine, sulphonamide, acyl chlorides, sulphonyl chlorides, sulphonyl fluorides, isocyanates, and combinations thereof.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: May 19, 2015
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventor: Milan Fedurco
  • Publication number: 20140378323
    Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using this additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.
    Type: Application
    Filed: June 3, 2014
    Publication date: December 25, 2014
    Applicant: ILLUMINA CAMBRIDGE LIMITED
    Inventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
  • Patent number: 8889817
    Abstract: Triazine polymer comprising at least a plurality of base structural units comprising at least a moiety corresponding to the formula: in which: the symbols X1 and X2, which are identical or different, represent S, SO, or SO2; the symbols Ar1 and Ar2, which are identical or different, represent a substituted or unsubstituted phenylene group; the symbol Ar3 represents a substituted or unsubstituted phenyl group; the symbol Tz represents the 1,3,5-triazine nucleus. This polymer of the invention, which can be used as electrolyte in a PEM fuel cell, makes it possible to obtain membranes of high chemical and dimensional stability which additionally exhibit a high ion conductivity.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: November 18, 2014
    Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.
    Inventors: Milan Fedurco, Antonio Delfino
  • Publication number: 20130231405
    Abstract: An aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer has a structure corresponding to a formula (I): Z1—Ar3—C(O)—Ar1—(CF2)n—Ar2—C(O)—Ar4—Z2??(I) in which: n is in a range from 1 to 20; Ar1, Ar2, Ar3, Ar4 which are identical or different, represent a substituted or unsubstituted phenylene group; and Z1 and Z2, which are identical or different, represent an electrophilic or nucleophilic polymerizable functional group.
    Type: Application
    Filed: July 6, 2011
    Publication date: September 5, 2013
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventor: Milan Fedurco
  • Publication number: 20130217851
    Abstract: A triazine polymer is provided that can be used as an electrolyte in a PEM fuel cell, and that enables membranes having a high chemical and dimensional stability, as well as a high ion conductivity. The triazine polymer is formed of at least a plurality of base structural units that include a moiety corresponding to a formula (I): in which: X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1 and Ar2, which are identical or different, represent a substituted or unsubstituted phenylene group; Ar3 represents a substituted or unsubstituted phenyl group; and Tz represents a 1,3,5-triazine nucleus.
    Type: Application
    Filed: July 6, 2011
    Publication date: August 22, 2013
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Milan Fedurco, Antonio Delfino
  • Publication number: 20130197110
    Abstract: A sulphur-containing and sulphonated aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer is a functionalized polymer that has a structure corresponding to a formula (I): E1-Ar1—X1—(CF2)n—X2—Ar2-E2??(I) in which: n is in a range from 1 to 20; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, which are identical or different, represent a phenylene group, at least one of Ar1 and Ar2 bearing a sulphonic (—SO3H) group or a sulphonate (—SO3M) group, in which M represents an alkali metal cation; and E1 and E2, which are identical or different, represent an electrophilic group such as a halogen, specifically fluorine or chlorine.
    Type: Application
    Filed: July 6, 2011
    Publication date: August 1, 2013
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventor: Milan Fedurco
  • Publication number: 20130184428
    Abstract: A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): in which: Tz represents a 1,3,5-triazine nucleus; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, Ar4 and Ar5, which are identical or different, represent a substituted or unsubstituted phenylene group; Ar3 represents a substituted or unsubstituted phenyl group; and Z1 and Z2, which are identical or different, are selected from a group that includes halogens, hydroxyl, alkoxyl, thiol, carboxyl, carboxylates, amine, sulphonamide, acyl chlorides, sulphonyl chlorides, sulphonyl fluorides, isocyanates, and combinations thereof.
    Type: Application
    Filed: July 6, 2011
    Publication date: July 18, 2013
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventor: Milan Fedurco