Patents by Inventor Milan Fedurco
Milan Fedurco has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20170137993Abstract: A threadlike metallic or metallized reinforcer, for example a thread, film, tape or cord made of carbon steel, at the periphery of which is positioned a layer of metal referred to as “surface metal” chosen from copper, nickel and copper/nickel alloys, is characterized in that this surface metal layer is itself coated, at least in part, with at least one layer of graphene; preferably, there is grafted, to this graphene, at least one functional group which can crosslink to a polymer matrix. This reinforcer of the invention is effectively protected from corrosion by virtue of the graphene present at the surface; advantageously, it can be adhesively bonded directly, without adhesion primer or addition of metal salt, to an unsaturated rubber matrix, such as natural rubber, by virtue of the possible functionalization of this graphene.Type: ApplicationFiled: May 20, 2015Publication date: May 18, 2017Inventors: ROBERT NIKOLAUS GRASS, WENDELIN JAN STARK, MILAN FEDURCO, ANTONIO DELFINO, JEAN-PAUL MERALDI
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Publication number: 20170121806Abstract: A process for depositing, with forward progression, graphene on the surface of a metallic or metallized continuous reinforcer, at the periphery of which is positioned a layer of surface metal chosen from copper, nickel and copper/nickel alloys, comprises at least one stage of flame spray pyrolysis (“FSP”), under a reducing atmosphere, of a carbon precursor which generates, in the flame, at least one carbon-based gas such as carbon monoxide which is sprayed onto the surface of the reinforcer in forward progression, and is decomposed thereon to form one or more graphene layers at the surface of the surface metal; an additional stage of graphene functionalization makes it possible to adhere the reinforcer to a polymer matrix such as rubber.Type: ApplicationFiled: May 20, 2015Publication date: May 4, 2017Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: WENDELIN JAN STARK, ROBERT NIKOLAUS GRASS, Milan Fedurco, ANTONIO DELFINO, JEAN-PAUL MERALDI
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Patent number: 9617372Abstract: A sulphur-comprising polyaromatic polyamine compound can be used as a monomer or prepolymer, when n is different from zero, in the synthesis of polyurea. The compound corresponds to the formula (I): H2N—Ar1—NH—CH2—CH(OH)—(CH2)m—O—Z1—O—(CH2)m—CH(OH)—CH2—[X]n—HN—Ar2—NH2 in which X represents the string: —HN—Ar3—NH—(CH2)—CH(OH)—(CH2)m—O—Z2—O—(CH2)m—CH(OH)—(CH2)— and in which n represents an integer equal to zero or different from zero; m, which are identical or different, represent an integer within a range from 1 to 10; Z1 and Z2, which are identical or different, represent a divalent bonding group comprising from 1 to 30 carbon atoms; and Ar1, Ar2 and Ar3, which are identical or different, each represent a phenylene group, at least one of these phenylene groups bearing one, two, three or four groups of formula —Sx—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon group which can comprise a heteroatom and which comprises from 1 to 10 carbon atoms.Type: GrantFiled: October 16, 2013Date of Patent: April 11, 2017Assignees: Compagnie Generale Des Etablissements Michelin, Michelin Recherche Et Technique S.A.Inventors: Milan Fedurco, Marco Ribezzo
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Publication number: 20160208324Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using this additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.Type: ApplicationFiled: February 22, 2016Publication date: July 21, 2016Applicant: Illumina Cambridge LimitedInventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
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Publication number: 20160122460Abstract: A polymer has urethane or thiourethane units, which can be used, in particular, as an adhesion primer for the adhesive bonding of metal or glass to rubber. The polymer comprises base units comprising at least a sub-unit of formula —X1—CO—NH— in which X1 respectively represents O or S, and additional units comprising at least a secondary alcohol function and a thioether function in the ? position relative to the alcohol function. The polymer can be used as an adhesion primer for the adhesive bonding of a substrate, for example glass or metal, to an unsaturated rubber, or as a corrosion-resistant protective coating for a metal substrate. A metal reinforcer, such as wire, cord, film or plate, can be coated with the polymer.Type: ApplicationFiled: April 18, 2014Publication date: May 5, 2016Inventors: MILAN FEDURCO, MARCO RIBEZZO, ANTONIO DELFINO
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Patent number: 9303290Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using this additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.Type: GrantFiled: June 3, 2014Date of Patent: April 5, 2016Assignee: Illumina Cambridge LimitedInventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
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Patent number: 9217178Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using the additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.Type: GrantFiled: December 13, 2005Date of Patent: December 22, 2015Assignee: Illumina Cambridge LimitedInventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
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Publication number: 20150352900Abstract: A ready-for-use metal reinforcer, for example, of the wire or cord type, made of brass-coated carbon steel, is capable of adhering directly by vulcanization to a matrix of unsaturated rubber such as natural rubber. The surface of the reinforcer is provided with nanoparticles of at least one sulfide of a metal chosen from cobalt, copper, iron, zinc and the alloys comprising at least one of these elements. Such a reinforcer can be used as the reinforcing element of a finished article made of rubber, such as a tire.Type: ApplicationFiled: December 16, 2013Publication date: December 10, 2015Inventors: ANTONIO DELFINO, MILAN FEDURCO, JEAN PAUL MERALDI, ROBERT NIKOLAUS GRASS, WENDELIN JAN STARK
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Publication number: 20150307981Abstract: The surface of a body, in particular a metal reinforcer, at least the surface of which comprises a layer of metal referred to as surface metal capable of forming sulphides, is sulfurized. The metal can be chosen from copper, zinc and their alloys. The process comprises at least one stage of flame spray pyrolysis (FSP) of a sulphur-donating precursor, for example, thiophene, which generates hydrogen sulphide in the flame. The metal bodies or reinforcers thus treated can be directly adhesively bonded, without adhesion primer or addition of metal salt, such as a cobalt salt, to matrices of unsaturated rubber such as natural rubber.Type: ApplicationFiled: December 16, 2013Publication date: October 29, 2015Inventors: ROBERT NIKOLAUS GRASS, MILAN FEDURCO, ANTONIO DELFINO, JEAN PAUL MERALDI, WENDELIN JAN STARK
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Publication number: 20150274878Abstract: A sulphur-comprising polyaromatic polyamine compound can be used as a monomer or prepolymer, when n is different from zero, in the synthesis of polyurea. The compound corresponds to the formula (I): H2N—Ar1—NH—CH2—CH(OH)—(CH2)m—O—Z1—O—(CH2)m—CH(OH)—CH2—[X]n—HN—Ar2—NH2 in which X represents the string: —HN—Ar3—NH—(CH2)—CH(OH)—(CH2)m—O—Z2—O—(CH2)m—CH(OH)—(CH2)— and in which n represents an integer equal to zero or different from zero; m, which are identical or different, represent an integer within a range from 1 to 10; Z1 and Z2, which are identical or different, represent a divalent bonding group comprising from 1 to 30 carbon atoms; and Ar1, Ar2 and Ar3, which are identical or different, each represent a phenylene group, at least one of these phenylene groups bearing one, two, three or four groups of formula —Sx—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon group which can comprise a heteroatom and which comprises from 1 to 10 carbon atoms.Type: ApplicationFiled: October 16, 2013Publication date: October 1, 2015Inventors: Milan Fedurco, Marco Ribezzo
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Publication number: 20150259463Abstract: A polyurea comprises at least urea base units of formula —NH—CO—NH— and additional units. The additional units comprise at least, on the one hand, a secondary alcohol functional group and, on the other hand, an ether, thioether or secondary amine functional group in the alpha position with respect to the secondary alcohol functional group. Such a polymer can be used as an adhesion primer for the adhesive bonding of a substrate, for example, glass or metal, to an unsaturated rubber or as corrosion-resistant protective coating for a metal substrate. Metal reinforcers, such as thread, cord, film or plate, coated can also be coated with such a polymer.Type: ApplicationFiled: October 16, 2013Publication date: September 17, 2015Inventors: Milan Fedurco, Marco Ribezzo, Antonio Delfino
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Patent number: 9126907Abstract: A sulphur-containing and sulphonated aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer is a functionalized polymer that has a structure corresponding to a formula (I): E1-Ar1—X1—(CF2)n—X2—Ar2-E2??(I) in which: n is in a range from 1 to 20; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, which are identical or different, represent a phenylene group, at least one of Ar1 and Ar2 bearing a sulphonic (—SO3H) group or a sulphonate (—SO3M) group, in which M represents an alkali metal cation; and E1 and E2, which are identical or different, represent an electrophilic group such as a halogen, specifically fluorine or chlorine.Type: GrantFiled: July 6, 2011Date of Patent: September 8, 2015Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventor: Milan Fedurco
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Patent number: 9120725Abstract: An aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer has a structure corresponding to a formula (I): Z1—Ar3—C(O)—Ar1—(CF2)n—Ar2—C(O)—Ar4—Z2??(I) in which: n is in a range from 1 to 20; Ar1, Ar2, Ar3, Ar4 which are identical or different, represent a substituted or unsubstituted phenylene group; and Z1 and Z2, which are identical or different, represent an electrophilic or nucleophilic polymerizable functional group.Type: GrantFiled: July 6, 2011Date of Patent: September 1, 2015Assignees: COMPAGNIE GENERALE DES ESTABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventor: Milan Fedurco
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Patent number: 9035013Abstract: A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): in which: Tz represents a 1,3,5-triazine nucleus; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, Ar4 and Ar5, which are identical or different, represent a substituted or unsubstituted phenylene group; Ar3 represents a substituted or unsubstituted phenyl group; and Z1 and Z2, which are identical or different, are selected from a group that includes halogens, hydroxyl, alkoxyl, thiol, carboxyl, carboxylates, amine, sulphonamide, acyl chlorides, sulphonyl chlorides, sulphonyl fluorides, isocyanates, and combinations thereof.Type: GrantFiled: July 6, 2011Date of Patent: May 19, 2015Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventor: Milan Fedurco
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Publication number: 20140378323Abstract: The invention relates to an additive which can be added to buffers used in nucleotide detection processes and improved methods of nucleic acid sequencing using this additive. In particular the invention relates to use of the additive to improve the efficiency of fluorescence-based multiple cycle nucleic acid sequencing reactions.Type: ApplicationFiled: June 3, 2014Publication date: December 25, 2014Applicant: ILLUMINA CAMBRIDGE LIMITEDInventors: Milan Fedurco, Anthony Romieu, Gerardo Turcatti
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Patent number: 8889817Abstract: Triazine polymer comprising at least a plurality of base structural units comprising at least a moiety corresponding to the formula: in which: the symbols X1 and X2, which are identical or different, represent S, SO, or SO2; the symbols Ar1 and Ar2, which are identical or different, represent a substituted or unsubstituted phenylene group; the symbol Ar3 represents a substituted or unsubstituted phenyl group; the symbol Tz represents the 1,3,5-triazine nucleus. This polymer of the invention, which can be used as electrolyte in a PEM fuel cell, makes it possible to obtain membranes of high chemical and dimensional stability which additionally exhibit a high ion conductivity.Type: GrantFiled: July 6, 2011Date of Patent: November 18, 2014Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventors: Milan Fedurco, Antonio Delfino
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Publication number: 20130231405Abstract: An aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer has a structure corresponding to a formula (I): Z1—Ar3—C(O)—Ar1—(CF2)n—Ar2—C(O)—Ar4—Z2??(I) in which: n is in a range from 1 to 20; Ar1, Ar2, Ar3, Ar4 which are identical or different, represent a substituted or unsubstituted phenylene group; and Z1 and Z2, which are identical or different, represent an electrophilic or nucleophilic polymerizable functional group.Type: ApplicationFiled: July 6, 2011Publication date: September 5, 2013Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventor: Milan Fedurco
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Publication number: 20130217851Abstract: A triazine polymer is provided that can be used as an electrolyte in a PEM fuel cell, and that enables membranes having a high chemical and dimensional stability, as well as a high ion conductivity. The triazine polymer is formed of at least a plurality of base structural units that include a moiety corresponding to a formula (I): in which: X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1 and Ar2, which are identical or different, represent a substituted or unsubstituted phenylene group; Ar3 represents a substituted or unsubstituted phenyl group; and Tz represents a 1,3,5-triazine nucleus.Type: ApplicationFiled: July 6, 2011Publication date: August 22, 2013Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Milan Fedurco, Antonio Delfino
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Publication number: 20130197110Abstract: A sulphur-containing and sulphonated aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer is a functionalized polymer that has a structure corresponding to a formula (I): E1-Ar1—X1—(CF2)n—X2—Ar2-E2??(I) in which: n is in a range from 1 to 20; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, which are identical or different, represent a phenylene group, at least one of Ar1 and Ar2 bearing a sulphonic (—SO3H) group or a sulphonate (—SO3M) group, in which M represents an alkali metal cation; and E1 and E2, which are identical or different, represent an electrophilic group such as a halogen, specifically fluorine or chlorine.Type: ApplicationFiled: July 6, 2011Publication date: August 1, 2013Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventor: Milan Fedurco
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Publication number: 20130184428Abstract: A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): in which: Tz represents a 1,3,5-triazine nucleus; X1 and X2, which are identical or different, represent S, SO, or SO2; Ar1, Ar2, Ar4 and Ar5, which are identical or different, represent a substituted or unsubstituted phenylene group; Ar3 represents a substituted or unsubstituted phenyl group; and Z1 and Z2, which are identical or different, are selected from a group that includes halogens, hydroxyl, alkoxyl, thiol, carboxyl, carboxylates, amine, sulphonamide, acyl chlorides, sulphonyl chlorides, sulphonyl fluorides, isocyanates, and combinations thereof.Type: ApplicationFiled: July 6, 2011Publication date: July 18, 2013Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventor: Milan Fedurco