Abstract: The present invention relates to novel energy efficient sorption processes and systems for cooling, dehumidifying and heating using multistage liquid desiccant regenerators, or hybrid cooling systems or adsorption cooling systems involving appropriate combinations of rotating contacting devises, adsorption modules with heat transfer passages in thermal contact with the adsorption module wall and switchable heat pipes. The sorption processes of this invention help in flexible designing of compact cooling, dehumidifing, heating systems easy operability. The adsorption module of this invention leads to lower cycle times as low as 5 minutes; makes it possible to achieve high system Coefficient of Performance (COP) up to 0.9 due to reduced thermal mass; offers high specific cooling power in the range of 50 to 750 W/kg of AC; is easy to manufacture and operates at low costs.