Abstract: A useful partial oxidation catalyst element includes a catalyst component, a support component, and a substrate. The catalyst component is formed by combining a catalytically active metal with a first support material to form a mixture and calcining the mixture. The support component is formed by calcining a second support material, not containing the active metal. The first and second support materials include particles having an average particle diameter of less than 20 microns. A catalyst material is formed by combining the catalyst component and the support component, wherein the catalyst material contains less than 20% of the catalyst component by weight. The catalyst material is applied to a substrate configured for gas flow therethrough, thereby formulating the partial oxidation catalyst element. The partial oxidation catalyst element is especially useful for fuel reforming and fuel cell applications.

Abstract: In an internal combustion engine system having an exhaust aftertreatment system including a selective catalytic reduction (SCR) catalyst, diagnostic methods involve the intrusive perturbation of a target surface coverage parameter theta to determine the state of health of the SCR catalyst or an ammonia concentration sensor. An adaptive learning block adapts the target theta based on the use of NH3 sensing feedback from a mid-brick positioned ammonia concentration sensor to pull in system variation. A further diagnostic monitors the amount of adaptation and when the adaptive learning excessively learns, the diagnostic assumes that some system-level degradation must have occurred and the diagnostic will notify the overall emissions control monitor.

Abstract: An exhaust gas treatment system includes a selective catalytic reduction (SCR) catalyst and a dosing control responsive to exhaust gas operating conditions for controlling the dosing rate of a reductant such as aqueous urea into the exhaust stream. The dosing control is configured to reduce the dosing rate when either a sudden increase in the exhaust mass air flow is detected or when an exhaust gas temperature gradient is in an increasing state. The dosing control is also configured to shut-off dosing when a measured ammonia concentration level exceeds an ammonia slip trip level, provided that the exhaust gas temperature gradient is also in an increasing state.

Abstract: Systems and methods for determining a concentration of biodiesel in a mixture of biodiesel and petrodiesel are provided. In one exemplary embodiment, a method includes receiving an oscillatory signal at an inductance-capacitance-resistance circuit. The circuit has a sensing element fluidly communicating with the mixture of biodiesel and petrodiesel. The method further includes generating a resonant current at a resonant frequency utilizing the circuit in response to the oscillatory signal. The method further includes determining a concentration value indicating the concentration of the biodiesel in the mixture based on an amplitude of the resonant current and/or the resonant frequency, utilizing a microprocessor. The method further includes storing the concentration value in a memory device, utilizing the microprocessor.

Abstract: Systems and methods for determining a total acid number associated with biodiesel in a mixture of biodiesel and petrodiesel are provided. The method includes receiving an oscillatory signal at an inductance-capacitance-resistance circuit. The circuit has a sensing element fluidly communicating with the mixture of biodiesel and petrodiese. The method further includes generating a resonant current at a resonant frequency utilizing the circuit in response to the oscillatory signal. The method further includes determining a dielectric constant value indicating a dielectric constant associated with the biodiesel in the mixture based on the resonant frequency of the resonant current, utilizing a microprocessor. The method further includes determining a concentration value indicating a concentration of the biodiesel in the mixture based on an amplitude of the resonant current and the dielectric constant value, utilizing the microprocessor.

Abstract: A useful partial oxidation catalyst element includes a catalyst component, a support component, and a substrate. The catalyst component is formed by combining a catalytically active metal with a first support material to form a mixture and calcining the mixture. The support component is formed by calcining a second support material, not containing the active metal. The first and second support materials include particles having an average particle diameter of less than 20 microns. A catalyst material is formed by combining the catalyst component and the support component, wherein the catalyst material contains less than 20% of the catalyst component by weight. The catalyst material is applied to a substrate configured for gas flow therethrough, thereby formulating the partial oxidation catalyst element. The partial oxidation catalyst element is especially useful for fuel reforming and fuel cell applications.

Abstract: A method for detecting fuel leaking into an oil pan containing oil which is used to lubricate an internal combustion engine utilizes a plurality of sensors. The method includes the step of measuring a plurality of parameters of the oil using each of the plurality of sensors to create measured values. A fuel leakage value is calculated incorporating each of the measured values. The method then determines when the fuel leakage value exceeds a predetermined value.

Abstract: A method for detecting fuel leaking into an oil pan containing oil which is used to lubricate an internal combustion engine utilizes a plurality of sensors. The method includes the step of measuring a plurality of parameters of the oil using each of the plurality of sensors to create measured values. A fuel leakage value is calculated incorporating each of the measured values. The method then determines when the fuel leakage value exceeds a predetermined value.

Abstract: A CO-selective catalyst comprises a catalytic material, wherein the catalytic material is selected from the group consisting of Pt, Pd, Rh, Ir, Os, Ru, Ta, Zr, Y, Ce, Ni, Cu, and oxides, alloys, compounds, and combinations comprising at least one of the foregoing; a modifying agent selected from the group consisting of Pb, Bi, Ge, Si, Sb, As, P, and combinations comprising at least one of the foregoing; and a support. In one embodiment, the method for forming the CO selective catalyst comprises combining a catalytic material and a support with about 2 to about 25 atomic percent of a modifying agent, based on the total surface atoms of the catalytic material, to form a modified catalyst-containing support and disposing the modified catalyst-containing support on or into a substrate.

Abstract: A method for detecting fuel leaking into an oil pan containing oil which is used to lubricate an internal combustion engine utilizes a plurality of sensors. The method includes the step of measuring a plurality of parameters of the oil using each of the plurality of sensors to create measured values. A fuel leakage value is calculated incorporating each of the measured values. The method then determines when the fuel leakage value exceeds a predetermined value.

Abstract: In one embodiment, the method for operating an exhaust system can comprise determining a stream temperature of an exhaust stream, and desulfating the NOx adsorber. Desulfating the NOx adsorber can comprise determining an amount of oxygen needed to increase an initial temperature of a NOx adsorber to a desulfation temperature of greater than or equal to about 600° C., producing reformate comprising hydrogen and carbon monoxide in an on-board reformer, introducing the amount of oxygen to the NOx adsorber, and introducing a sufficient amount of reformate to the NOx adsorber to attain an air to fuel ratio that is less than a combustion stoichiometric A/F ratio.

Abstract: A method of making a sensor element comprises: combining coarse aluminium oxide with fine aluminium oxide and a binder to form a mixture, milling the mixture to form a base slurry, mixing a supported catalyst with the base slurry and a fugitive material to form a final slurry, applying the slurry to a sensor element precursor over at porous protective layer at least in an area opposite a sensing electrode, and calcining the sensor element precursor to form a calcined sensor element with a catalyzed coating over at least a portion of the porous protective layer. The coarse aluminium oxide has a coarse agglomerate size and the fine aluminium oxide has a fine particle size less than the coarse agglomerate size.

Abstract: Disclosed is a method for direct application of a catalyst to a substrate for treatment of atmospheric pollution including ozone. The method includes applying a catalytic metal to a substrate utilizing a thermal spray process. The process can be utilized to apply a base metal such as copper to a substrate and the base metal becomes the catalytically active oxide during and following application to the substrate. This system replaces a multi-step process within a single step process to provide a catalytically active surface that can be utilized to reduce ground level ozone and other atmospheric pollutants.

Abstract: One embodiment of a method of fabricating a sensor element for an exhaust gas sensing device, comprises disposing an electrolyte in ionic communication with a sensing electrode and a reference electrode to form the sensor element. The sensing electrode comprises an activator comprising silica and an oxide of an element. The element is selected from the group consisting of alkaline earth elements, rare earth elements, and combinations comprising at least one of the foregoing elements.

Abstract: Disclosed is a method for direct application of a catalyst to a substrate for treatment of atmospheric pollution including ozone. The method includes applying a catalytic metal to a substrate utilizing a thermal spray process. The process can be utilized to apply a base metal such as copper to a substrate and the base metal becomes the catalytically active oxide during and following application to the substrate. This system replaces a multi-step process within a single step process to provide a catalytically active surface that can be utilized to reduce ground level ozone and other atmospheric pollutants.

Abstract: A stored relationship between air/fuel ratio and the output voltage of a wide-range exhaust gas oxygen sensor is automatically re-calibrated under any air/fuel ratio condition. Once an engine control module records oxygen sensor voltages under stoichiometric and deceleration fuel cut-off conditions, the air/fuel ratio that corresponding to any sensor voltage can be calculated. In operation, the sensor voltage recorded during fuel cut-off is used to determine first and second lump-sum parameters that relate sensor output voltage to air/fuel ratio under lean and rich operating conditions, respectively. The determined parameters are compared with previously determined values, and when the comparison indicates that at least a predetermined change the sensor operating characteristics has occurred, the parameters are used to re-calibrate the stored sensor voltage vs. air/fuel ratio relationship.

Abstract: A method for direct application of a catalyst to a substrate for treatment of atmospheric pollution including ozone. The method includes applying a catalytic metal to a substrate utilizing a kinetic spray process. The process can be utilized to apply a base metal such as copper to a substrate and the base metal becomes the catalytically active oxide following application to the substrate. This system replaces a multi-step process with a single step process to provide a catalytically active surface that can be utilized to reduce ground level ozone and other atmospheric pollutants.

Abstract: Disclosed is a method for direct application of a catalyst to a substrate for treatment of atmospheric pollution including ozone. The method includes applying a catalytic metal to a substrate utilizing a kinetic spray process. The process can be utilized to apply a base metal such as copper to a substrate and the base metal becomes the catalytically active oxide following application to the substrate. This system replaces a multi-step process within a single step process to provide a catalytically active surface that can be utilized to reduce ground level ozone and other atmospheric pollutants.

Abstract: A sensor and a method for making a sensor is disclosed. The method for making the sensor comprises: mixing a first metal oxide stabilized alumina with alpha alumina in a liquid to create a base slurry, mixing into said base slurry a second metal oxide stabilized alumina and a fugitive material to create a composition; applying said composition to at least a portion of a sensing element comprising two electrodes with an electrolyte disposed therebetween; and calcining said sensing element.

Abstract: A CO-selective catalyst comprises a catalytic material, wherein the catalytic material is selected from the group consisting of Pt, Pd, Rh, Ir, Os, Ru, Ta, Zr, Y, Ce, Ni, Cu, and oxides, alloys, compounds, and combinations comprising at least one of the foregoing; a modifying agent selected from the group consisting of Pb, Bi, Ge, Si, Sb, As, P, and combinations comprising at least one of the foregoing; and a support.