Abstract: The present disclosure relates to a high molecular weight furan-based aromatic polyamide, which is derived from a diacid monomer comprising substituted or unsubstituted furandicarboxylic acid or derivatives thereof and a diamine monomer comprising substituted or unsubstituted 4,4?-diaminodiphenyl ether or derivatives thereof, and thus comprises a repeating unit of Formula (I), wherein R1-R10 are each independently H or a C1-6-alkyl. The furan-based aromatic polyamide of the present disclosure has obtained with mild preparation conditions and simple preparation process. The high molecular weight furan-based aromatic polyamide provided in the present disclosure has excellent thermodynamic properties and mechanical properties, and can be used for preparing a fiber, a film material, or a nanomaterial/polymer composite material.