Abstract: A process is provided for the catalytic cracking of a glyceride oil feedstock with a catalyst composition containing a phosphorus-containing ZSM-5 light olefins additive.

Abstract: A process is provided for upgrading a renewable feedstock. The process includes introducing the renewable feedstock into a fluid catalytic cracking (FCC) reactor unit operating under catalytic cracking conditions and comprising a circulating inventory of an equilibrium catalyst composition; removing a portion of the equilibrium catalyst inventory from the FCC reactor unit while replacing all the equilibrium catalyst removed from the unit with a spent catalyst to obtain a composite circulating catalyst within the FCC reactor unit; and contacting the composite circulating catalyst with the renewable feedstock in the FCC reactor unit under a steady state environment to provide a product stream comprising cracked products.

Abstract: Disclosed herein is a method for making diesel, gasoline and LPG comprising coprocessing a petroleum-derived feedstock with up to 50 wt. %, relative to the total weight of the feedstocks, of a lipid-containing feedstock in the presence of a catalyst under fluidized catalyst cracking conditions. Also disclosed herein is a method for making a diesel fuel or a combined diesel and gasoline fuel by injecting up to 50 wt. %, relative to the total weight of the feedstocks, of a lipid-containing feedstock to a stripper or a riser quench downstream from a petroleum derived feedstock injection point in a fluid catalytic cracking unit.

Abstract: In the regeneration of a cracking catalyst in a regeneration zone operated in a partial combustion mode, NH3 and HCN in the regenerator flue gas are reduced by incorporating into the regenerator precious metals such as ruthenium, rhodium, iridium, or mixtures thereof.

Abstract: A novel method of forming ZSM-5 comprises reacting calcined kaolin microspheres with silicate and a seed solution used for forming zeolite Y under conditions of pH, temperature, and time to yield ZSM-5 crystals formed in-situ on said calcined kaolin microspheres. The reaction medium does not contain any organic templates or ZSM-5 seeding crystals.

Abstract: A fluid catalytic cracking catalyst is provided with a high porosity by in-situ crystallizing an aluminosilicate zeolite from a reactive microsphere comprising metakaolin and hydrous kaolin. Any calcination of the reactive microsphere before reaction with a zeolite-forming solution is done at low temperatures so as to ensure the hydrous kaolin is not converted to metakaolin.

Abstract: A novel method of forming ZSM-5 comprises reacting calcined kaolin microspheres with silicate and a seed solution used for forming zeolite Y under conditions of pH, temperature, and time to yield ZSM-5 crystals formed in-situ on said calcined kaolin microspheres. The reaction medium does not contain any organic templates or ZSM-5 seeding crystals.

Abstract: A novel method of forming ZSM-5 comprises reacting calcined kaolin microspheres with silicate and a seed solution used for forming zeolite Y under conditions of pH, temperature, and time to yield ZSM-5 crystals formed in-situ on said calcined kaolin microspheres. The reaction medium does not contain any organic templates or ZSM-5 seeding crystals.

Abstract: The amount of NOx formed during regeneration of a cracking catalyst in the presence of a metallic carbon monoxide combustion catalyst is decreased by utilizing as the carbon monoxide combustion catalyst rhodium and/or iridium on an oxide support such as alumina.

Abstract: In the regeneration of a cracking catalyst in a regeneration zone operated in a partial combustion mode, NH3 and HCN in the regenerator flue gas are reduced by incorporating into the regenerator precious metals such as ruthenium, rhodium, iridium, or mixtures thereof.

Abstract: A novel method of forming ZSM-5 comprises reacting calcined kaolin microspheres with silicate and a seed solution used for forming zeolite Y under conditions of pH, temperature, and time to yield ZSM-5 crystals formed in-situ on said calcined kaolin microspheres. The reaction medium does not contain any organic templates or ZSM-5 seeding crystals.

Abstract: A fluid catalytic cracking catalyst is provided with a high porosity by in-situ crystallizing an aluminosilicate zeolite from a reactive microsphere comprising metakaolin and hydrous kaolin. Any calcination of the reactive microsphere before reaction with a zeolite-forming solution is done at low temperatures so as to ensure the hydrous kaolin is not converted to metakaolin.

Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally spinel, or mullite, or both spinel and mullite made via kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and a particular kaolin which has been calcined through its characteristic exotherm and which produces a catalyst having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. Calcination of the hydrous kaolin to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and a particular kaolin which has been calcined through its characteristic exotherm and which produces a catalyst having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. Calcination of the hydrous kaolin to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally spinel, or mullite, or both spinel and mullite made via kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.

Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina which contains a gamma alumina phase. The transitional alumina may contain a delta alumina phase as well. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.