Abstract: A process and catalyst blend for selectively producing mercaptans and sulfides from alcohols. The alcohol is reacted with hydrogen sulfide, in the presence of a catalyst blend containing a hydrotreating catalyst and a dehydration catalyst to convert the alcohol to mercaptan or sulfide in one-pass. The alcohols can include primary and secondary alcohols. The mercaptan or sulfide having less than about 30% unreacted alcohol contained therein.

Abstract: Removing impurities from a heptane stream by contacting the heptane stream with an acidic catalyst, wherein the contacting reduces a concentration of one or more close boiling impurities, one or more olefins, or both. The impurities are isomerized via contact with the acidic catalyst into species that possess lower octane levels or that do not possess boiling points as near to the boiling point of n-heptane, which promotes separation of the impurities via distillation. Close boiling impurities may include such compounds as cis-1,2-dimethylcyclopentane and methylcyclohexane or may be compounds having boiling points at a standard pressure of 760 Torr in the range of about 96.5 to about 100.5 degrees Celsius including such compounds as cis-1,2-dimethylcyclopentane and methylcyclohexane. The concentration of cis-1,2-dimethylcyclopentane and methylcyclohexane may be reduced by at least about 25 and 10 percent by weight, respectively.

Abstract: A process for selectively making 2-thiols from alpha olefins is described. The process includes contacting a linear or branched alpha olefin having with H2S in the presence of a catalyst and recovering the 2-thiol from a product mixture. The catalyst includes a support and at least one metal selected from Group IIIA-VIIIA and the branched olefin is branched at the 3-position or higher with respect to the olefin double bond. Compositions wherein the 2-thiols are substantially free of 1-thiol and 3-thiol isomers are also described.

Abstract: A process is provided to produce a 2-alkene product from a 1-alkene-containing feed stream. The process comprises contacting the 1-alkene-containing feed stream in a reactor zone to isomerize the 1-alkene-containing feed stream to produce the 2-alkene product. More specifically, a process is provided to produce a 2-butene product from a 1-butene containing feed stream.

Abstract: A process is provided to produce a 2-alkene product from a 1-alkene-containing feed stream. The process comprises contacting the 1-alkene-containing feed stream in a reactor zone to isomerize the 1-alkene-containing feed stream to produce the 2-alkene product. More specifically, a process is provided to produce a 2-butene product from a 1-butene containing feed stream.

Abstract: An adsorption method is disclosed for removal of acid gas from a sulfur compound stream. The method relates to a novel process to remove acid gas from a sulfur compound stream by adsorption on an adsorption media adsorbent followed by regeneration of the adsorption media after the adsorption capacity has been reached. The adsorption media comprises an activated alumina, which has been previously treated with one or more alkali metal compounds, one or more alkaline earth metal compounds, or a mixture thereof; and then regenerating the adsorbent after the adsorption capacity has been reached.

Abstract: An adsorption method is disclosed for removal of acid gas from a sulfur compound stream. The method relates to a novel process to remove acid gas from a sulfur compound stream by adsorption on an adsorption media adsorbent followed by regeneration of the adsorption media after the adsorption capacity has been reached. The adsorption media comprises an activated alumina, which has been previously treated with one or more alkali metal compounds, one or more alkaline earth metal compounds, or a mixture thereof; and then regenerating the adsorbent after the adsorption capacity has been reached.

Abstract: A novel composition having the formula: wherein R1 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group, and R2 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group. The composition is made by combining an amine compound, a carbonyl compound, a solvent, and a sulfur-containing compound. The composition is used as a detergent additive in cleaning process.

Abstract: A novel composition having the formula: wherein R1 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group, and R2 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group. The composition is made by combining an amine compound, a carbonyl compound, a solvent, and a sulfur-containing compound. The composition is used as a detergent additive in cleaning process.

Abstract: A novel composition having the formula: 1

Abstract: A process useful for producing an organic disulfide is disclosed. The process can include contacting mercaptans with a solid catalyst selected from the group consisting of a Group IIA metal oxide; 2) an alumina material consisting essentially of alumina; 3) an impregnated alumina impregnated with a metal selected from the group consisting of cobalt, molybdenum, tungsten, nickel and combinations of any two or more thereof; 4) an acidic ion-exchange resin; 5) a basic ion-exchange resin; and 6) combinations of any two or more thereof; in the presence of sulfur dioxide and in the substantial absence of a liquid oxidation catalyst to thereby produce organic disulfides.