Patents by Inventor Mitsuaki Makino

Mitsuaki Makino has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8921584
    Abstract: A composition is provided that contains an intermediate for a water-soluble monomer, wherein this intermediate is suitable for producing a water-soluble polyalkylene glycol-type monomer that has a polymerizable terminal double bond, and suitable for the production of water-soluble polymer, and moreover allows the high-yield production of water-soluble polymer. A process of producing this composition and a water-soluble monomer-containing composition obtained therefrom are also provided. A water-soluble monomer is also provided that can be used as a starting material for a water-soluble polymer that even at high hardnesses exhibits an excellent capacity to capture metal ions such as the calcium ion and magnesium ion, an excellent anti-gelation performance, an excellent anti-soil redeposition performance, a better anti-dye transfer performance than in the past, and also an excellent compatibility with surfactants.
    Type: Grant
    Filed: December 3, 2010
    Date of Patent: December 30, 2014
    Assignee: Nippon Shokubai Co, Ltd
    Inventors: Atsuro Yoneda, Makoto Saito, Aki Tsukajima, Daisuke Michitaka, Mitsuaki Makino
  • Patent number: 8796492
    Abstract: An ?-(unsaturated alkoxyalkyl)acrylate composition is provided which enables an ?-(unsaturated alkoxyalkyl)acrylate product to be stored at a high purity for an extended period of time and can fully suppress problems such as discoloration and gelation from arising during polymerization, and a method of safely preparing ?-(unsaturated alkoxyalkyl)acrylate compositions industrially, with high purity. The composition includes an ?-(unsaturated alkoxyalkyl)acrylate of a specific structure and an antioxidant, the content of the antioxidant being from 0.03 to 0.5 wt % per 100 wt % of the ?-(unsaturated alkoxyalkyl)acrylate.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: August 5, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Makoto Saito, Hiroko Izumi, Toshimitsu Moriguchi, Tomomasa Kaneko, Atsushi Tachibana, Mitsuaki Makino, Yasuhiro Mimura
  • Publication number: 20120238717
    Abstract: A composition is provided that contains an intermediate for a water-soluble monomer, wherein this intermediate is suitable for producing a water-soluble polyalkylene glycol-type monomer that has a polymerizable terminal double bond, and suitable for the production of water-soluble polymer, and moreover allows the high-yield production of water-soluble polymer. A process of producing this composition and a water-soluble monomer-containing composition obtained therefrom are also provided. A water-soluble monomer is also provided that can be used as a starting material for a water-soluble polymer that even at high hardnesses exhibits an excellent capacity to capture metal ions such as the calcium ion and magnesium ion, an excellent anti-gelation performance, an excellent anti-soil redeposition performance, a better anti-dye transfer performance than in the past, and also an excellent compatibility with surfactants.
    Type: Application
    Filed: December 3, 2010
    Publication date: September 20, 2012
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Atsuro Yoneda, Makoto Saito, Aki Tsukajima, Daisuke Michitaka, Mitsuaki Makino
  • Publication number: 20120016095
    Abstract: An ?-(unsaturated alkoxyalkyl)acrylate composition is provided which enables an ?-(unsaturated alkoxyalkyl)acrylate product to be stored at a high purity for an extended period of time and can fully suppress problems such as coloration and gelation from arising during polymerization, and also a method of preparing ?-(unsaturated alkoxyalkyl)acrylate compositions for enabling to obtain industrially ?-(unsaturated alkoxyalkyl)acrylates safely in a high purity is also provided. The composition includes an ?-(unsaturated alkoxyalkyl)acrylate of a specific structure and an antioxidant, the content of the antioxidant being from 0.03 to 0.5 wt % per 100 wt % of the ?-(unsaturated alkoxyalkyl)acrylate.
    Type: Application
    Filed: March 31, 2010
    Publication date: January 19, 2012
    Applicant: Nippon Shokubai Co., Ltd.
    Inventors: Makoto Saito, Hiroko Izumi, Toshimitsu Moriguchi, Tomomasa Kaneko, Atsushi Tachibana, Mitsuaki Makino, Yasuhiro Mimura
  • Patent number: 5834576
    Abstract: A novel acrylic ester which is represented by general formula (2) ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or an organic residue, R.sub.3 represents an organic residue, n is a positive number among 1 to 3, and m is a positive number among 1 to 100 and which is applicable to various uses, is obtained by reacting an acrylic ester of general formula (3) ##STR2## wherein R.sub.1 represents a hydrogen atom or an organic residue, and R.sub.3 represents an organic residue, with a cyclic ether compound of general formula (4) ##STR3## wherein R.sub.2 represents a hydrogen atom or an organic residue, and n is a positive number among 1 to 3. Moreover, a novel acrylic acid derivative whose use is even wider is obtained by hydrolyzing the acrylic acid derivative.
    Type: Grant
    Filed: February 27, 1996
    Date of Patent: November 10, 1998
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hideaki Nagano, Koichi Nakagawa, Keiji Yurugi, Mitsuaki Makino, Tsuyoshi Hirata, Koichiro Nagare, Yuichi Kita
  • Patent number: 5760278
    Abstract: A stabilization method of a vinyl compound with hydroxy group of an improved stability is achieved by preventing it from being denatured on storage, transportation, manufacturing process while maintaining its reactivity. A composition containing the vinyl compound with hydroxy group of an improved stability is obtained by the described stabilization method. The stabilization method is characterized by coexisting a vinyl compound with hydroxy group of formula (1), a primary antioxidant, alcohol and/or water, ##STR1## wherein R is a hydrogen atom or an organic residue, X is a --CN group, a --COR.sub.0 group or a --COOR.sub.0 group, and R.sub.0 is a hydrogen atom or an organic residue. In this stabilization method, not less than 50 ppm of alcohol and/or water is added with respect to the vinyl compound with hydroxy group. The stabilization method may be achieved by coexisting the above-defined vinyl compound with hydroxy group, the primary antioxidant and organic acid.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: June 2, 1998
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Koichi Nakagawa, Mitsuaki Makino, Yuichi Kita
  • Patent number: 5703270
    Abstract: A vinyl compound having a hydroxy group of the formula (1) ##STR1## wherein R is a hydrogen atom or an organic residue, X is a --CN group, a --COR.sub.0 group or a --COOR.sub.0 group and R.sub.0 is a hydrogen atom or an organic residue, is prepared by reacting a vinyl compound of the formula (2) ##STR2## wherein X is a --CN group, a --COR.sub.0 group or a --COOR.sub.0 group and R.sub.0 is a hydrogen atom or an organic residue, with an aldehyde series compound in the presence of a tertiary amine compound, and water in a sufficient amount for forming an aqueous phase upon the completion of the reaction. In this method, since the aqueous phase is formed upon the completion of the reaction, the organic phase including the vinyl compound having a hydroxy group and the aqueous phase including the tertiary amine compound can be easily separated.
    Type: Grant
    Filed: February 22, 1995
    Date of Patent: December 30, 1997
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Koichi Nakagawa, Mitsuaki Makino, Yuichi Kita