Patents by Inventor Mitsuji Tsuji

Mitsuji Tsuji has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5084511
    Abstract: A novel thermoplastic composition having improved paint adhesion strength and excellent impact strength comprising,A) from about 5 to 95 weight % of at least one polyphenylene ether,B) from about 95 to 5 weight % of at least one polyamide,C) from about 5 to 50 parts by weight based on 100 parts by weight of the total of polyphenylene ether and polyamide, of at least one elastomeric material selected from ethylene .alpha.-olefin (diene) copolymers with at least one vinyl aromatic monomer and at least one unsaturated functional monomer selected from unsaturated nitrile monomers and alkyl(meth)acrylates grafted thereto, andD) from about 0.01 to 30 parts by weight of at least one compatibilizer, based on 100 parts by weight of the total of polyphenylene ether and polyamide.
    Type: Grant
    Filed: July 7, 1989
    Date of Patent: January 28, 1992
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Hiroomi Abe, Yasurou Suzuki, Mitsuji Tsuji, Kenji Nagaoka, Takashi Sanada
  • Patent number: 5037891
    Abstract: A modified copolymer rubber obtained by kneading at 200.degree.-280.degree. C.(A) at least one copolymer rubber material selected from the group consisting of an ethylene-.alpha.-olefin copolymer rubber having a number-average molecular weight of 10,000-100,000 and an ethylene content of 15-85% by weight and an ethylene-.alpha.-olefin-nonconjugated diene copolymer rubber having a number-average molecular weight of 10,000-100,000, an ethylene content of 15-85% by weight and a nonconjugated diene content of 3.0% by weight or less,(B) a free-radical initiator,(C) at least one vinyl aromatic monomer and(D) an unsaturated dicarboxylic anhydride, wherein the weight ratios of (B):(A), (C):(A), (D):(A) and (C):(D) are 0.005-1.0:100, 0.2-20:100, 0.5-15:100 and 0.1-3:1, respectively.The process is suited for industrially producing a modified copolymer rubber having a high bound unsaturated dicarboxylic anhydride content, a low tendency of increase of the Mooney viscosity [ML.sub.1+4 (121.degree. C.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: August 6, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyoshi Takao, Akio Imai, Mitsuji Tsuji
  • Patent number: 5036141
    Abstract: According to the present invention, there is provided a modified polyolefin resin having the following merits:(1) The amount of bound unsaturated carboxylic acid, a derivative thereof or unsaturated epoxy compound is high.(2) The change of the melt flow rate during the modification is small.(3) The physical properties are of high grade.(4) The transparency is improved due to the graft of unsaturated aromatic compound.The modified polyolefin resin of the present invention can be used for adhesives, covering materials, binders, laminate bonding agent and polymer alloy constituents.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: July 30, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshiki Toyoshima, Mitsuyuki Okada, Takeshi Fujii, Kentaro Yamaguchi, Mitsuji Tsuji
  • Patent number: 5032459
    Abstract: According to the present invention, there is provided a modified polyolefin resin having the following merits:(1) The amount of bound unsaturated carboxylic acid, a derivative thereof of unsaturated epoxy compound is high.(2) The change of the melt flow rate during the modification is small.(3) The physical properties are of high grade.(4) The coating affinity with urethane coatings and resistance to falling off of the coating layer are excellent.The modified polyolefin resin of the present invention can be used for adhesives, covering materials, binders, laminate bonding agent and polymer alloy constituents.
    Type: Grant
    Filed: September 4, 1990
    Date of Patent: July 16, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshiki Toyoshima, Mitsuyuki Okada, Takeshi Fujii, Kentaro Yamaguchi, Mitsuji Tsuji, Hideo Shinonaga
  • Patent number: 5015692
    Abstract: A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitro compound, a phosphoryl chloride compound of the formula: ##STR1## wherein R.sup.1 to R.sup.4 are independently an alkyl group, and an aminosilane compound of the formula: ##STR2## wherein R.sup.5 to R.sup.7 are independently an alkyl group or an alkoxyl group, R.sup.8 and R.sup.9 are independently an alkyl group, and n is an integer,said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent.
    Type: Grant
    Filed: March 30, 1990
    Date of Patent: May 14, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyoshi Takao, Akio Imai, Tomoaki Seki, Mitsuji Tsuji
  • Patent number: 4981896
    Abstract: There is disclosed a thermoplastic resin composition comprising a blend of100 parts by weight of a resin composition composed of 1 to 99% by weight of a polypropylene type resin (C) selected from the group consisting of a modified polypropylene (A) obtained by graft copolymerizing an unsaturated carboxylic acid or a derivative thereof and an unsaturated aromatic monomer onto polypropylene, and a composition composed of the modified polypropylene (A) and a polypropylene (B), and 99 to 1% by weight of at least one saturated polyester resin (D),0.1 to 300 parts by weight of an epoxy group containing copolymer (E),0.
    Type: Grant
    Filed: March 22, 1989
    Date of Patent: January 1, 1991
    Assignees: Sumitomo Chemical Company, Toyota Jidosha Kabushiki Kaisha
    Inventors: Takayuki Okada, Tatsuyuki Mitsuno, Takeshi Fujii, Kentaro Yamaguchi, Mitsuyuki Okada, Mitsuji Tsuji, Takeyoshi Nishio, Toshio Yokoi, Takao Nomura
  • Patent number: 4966940
    Abstract: A vulcanized, ethylene/.alpha.-olefin copolymer rubber composition obtained by vulcanizing an unvulcanized rubber composition comprising 100 parts by weight of a rubber composition consisting of 0-99% by weight of an ethylene/.alpha.-olefin copolymer rubber and 100-1% by weight of an ethylene/.alpha.-olefin copolymer rubber containing an .alpha.,.beta.-unsaturated carboxylic acid and/or a derivative thereof; and 5-100 parts by weight of a polyamide resin, wherein an ethylene/.alpha.-olefin copolymer rubber is at least one selected from ethylene/.alpha.-olefin copolymers and ethylene/.alpha.-olefin/non-conjugated diene copolymers. The vulcanized, ethylene/.alpha.-olefin copolymer rubber composition of the present invention has a high hardness and is excellent in weather resistance and thermal resistance as compared with natural rubbers and general-purpose rubbers.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: October 30, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Mitsuji Tsuji, Eiichi Usuda, Masashi Aoshima
  • Patent number: 4957976
    Abstract: A process for preparing modified diene polymer rubbers having an increased impact resilience and a reduced hardness at low temperatures and useful as rubber materials for automobile tires and other industries which comprises producing an alkali metal-containing conjugated diene polymer, and reacting the alkali metal-containing polymer with a modifier selected from the group consisting of a nitro compound, a phosphoryl chloride compound of the formula: ##STR1## wherein R.sup.1 to R.sup.4 are independently an alkyl group, and an aminosilane compound of the formula: ##STR2## wherein R.sup.5 to R.sup.7 are independently an alkyl group or an alkoxyl group, R.sup.8 and R.sup.9 are independently an alkyl group, and n is an integer, said alkali metal-containing diene polymer being prepared by a living anionic polymerization using an alkali metal-based catalyst or by an addition reaction of a diene polymer having conjugated diene units and an alkali metal-based catalyst in a hydrocarbon solvent.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: September 18, 1990
    Assignee: Sumitomo Chemical Company Limited
    Inventors: Hiroyoshi Takao, Akio Imai, Tomoski Seki, Mitsuji Tsuji
  • Patent number: 4929675
    Abstract: A thermoplastic resin composition which comprises100 parts by weight of a composition (A) which comprises 5-95% by weight of a polyphenylene ether resin and 95-5% by weight of a polyamide,5-50 parts by weight of a modified rubber-like material (B) wherein 5-100 parts by weight of an aromatic vinyl compound is graft-polymerized with 100 parts by weight of a rubber-like material, the grafting ratio of the aromatic vinyl compound being 50% by weight or more, and0.05-20 parts by weight of an .alpha., .beta.-unsaturated carboxylic acid or its derivative (C).
    Type: Grant
    Filed: June 7, 1988
    Date of Patent: May 29, 1990
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Hiroomi Abe, Taichi Nishio, Yasurou Suzuki, Takashi Sanada, Mitsuji Tsuji
  • Patent number: 4918142
    Abstract: A rubber composition suitable for tire treads having well-balanced excellent steering stability in cornering, wet skid characteristic, ice skid characteristic and rolling characteristic, and an excellent processability, which comprises a rubber component containing a block copolymer consisting essentially of a block A and a block B, obtained by conducting polymerization of an aromatic vinyl compound and a conjugated diene compound in a hydrocarbon solvent in the presence of an organolithium initiator and modifying with a coupling agent, and satisfying the following conditions (A) to (E);(A) the block A having a content of an aromatic vinyl compound of 5 to 29% by weight and a content of 1,2-bonds in the conjugated diene component of 25 to 55% by weight,(B) the block B having a content of an aromatic vinyl compound of 35 to 60% by weight and a content of 1,2-bonds in the conjugated diene component of 20 to 70% by weight,(C) the content of the block A in the block copolymer being from 20 to 80% by weight,(D) th
    Type: Grant
    Filed: March 8, 1989
    Date of Patent: April 17, 1990
    Assignees: Sumitomo Chemical Company, Limited, Sumitomo Rubber Industries, Ltd.
    Inventors: Yuichi Saito, Takuzoh Yabuta, Hiroyoshi Takao, Akio Imai, Mitsuji Tsuji
  • Patent number: 4812527
    Abstract: A rubber composition suitable for tire treads having well-balanced excellent wet skid characteristic, ice skid characteristic and rolling characteristic, and an excellent processability, which comprises a rubber component containing at least 20% by weight of a block copolymer consisting essentially of a block A and a block B, obtained by conducting polymerization of an aromatic vinyl compound and a conjugated diene compound in a hydrocarbon solvent in the presence of an organolithium initiator and modifying with a coupling agent, and satisfying the following conditions (A) to (E);(A) the block A having a content of an aromatic vinyl compound of at most 5% by weight and a content of 1,2-bonds in the conjugated diene component of at least 10% by weight,(B) the block B having a content of an aromatic vinyl compound of 25 to 50% by weight and a content of 1,2-bonds in the conjugated diene component of at least 10% by weight,(C) a content of the block A in the block copolymer being from 20 to 80% by weight,(D) a c
    Type: Grant
    Filed: October 27, 1987
    Date of Patent: March 14, 1989
    Assignees: Sumitomo Chemical Company, Limited, Sumitomo Rubber Industries, Ltd.
    Inventors: Hiroyoshi Takao, Nabuyuki Yoshida, Akio Imai, Mitsuji Tsuji, Yuichi Saito