Patents by Inventor Mitsutoshi Aritomi

Mitsutoshi Aritomi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6160048
    Abstract: There is provided a modified ethylene resin produced by subjecting (a) an ethylene resin to modification with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a hydrocarbon-terminated polyalkylene oxide chain, and with (c) an aromatic vinyl compound and/or (d) an ester of an .alpha.,.beta.-unsaturated carboxylic acid with an aliphatic alcohol.There is also provided an ethylene resin composition comprising: (A) 80 to 99.9% by weight of a modified ethylene resin produced by subjecting (a) an ethylene resin to modification at least with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a polyalkylene oxide chain; and (B) 20 to 0.1% by weight of a surfactant.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: December 12, 2000
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tadashi Uyeda, Keiko Matsuhisa, Kenjiro Takayanagi, Mitsutoshi Aritomi
  • Patent number: 5939181
    Abstract: A porous molded article having microvoids therein which comprises a stretched product of a resin molded material made up of, as the base material, an olefinic resin composition containing from 95 to 50% by weight of a crystalline olefinic resin component (A) and from 5 to 50% by weight of a polymer of a cyclic olefin having a weight average molecular weight of not less than 1,000 and less than 10,000 and a glass transition point of from 180 to 400.degree. C. component (B).
    Type: Grant
    Filed: September 10, 1997
    Date of Patent: August 17, 1999
    Assignee: Oji-Yuka Synthetic Paper Co., Ltd.
    Inventors: Yuuta Kumano, Mitsutoshi Aritomi, Kenji Takasaki, Osamu Nishizawa, Nobuhiro Shibuya, Hisao Ochiai, Kenji Nakajima
  • Patent number: 5444125
    Abstract: An aminated polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an amino group, into an isotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated isotactic or syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the amino group is obtained by the amination of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: August 22, 1995
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Masayuki Tomita, Hideshi Uchino, Toshihiko Sugano, Takashi Fujita, Mitsutoshi Aritomi
  • Patent number: 5424359
    Abstract: Disclosed is a thermoplastic resin composition comprising(A) 90 to 10% by weight of a modified polyolefin type resin obtained by subjecting 100 parts by weight of a polyolefin type resin to graft polymerization with 0.01 to 20 parts by weight of an .alpha.,.beta.-unsaturated carboxylate having a hydroxyl group and 0.01 to 50 parts by weight of an aromatic vinyl compound; and(B) 10 to 90% by weight of a saturated polyester.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: June 13, 1995
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Yusuke Arashiro, Yoshio Katoh, Keiko Matsuhisa, Mitsutoshi Aritomi
  • Patent number: 5334664
    Abstract: A method for producing a graft-modified copolymer comprising the step of subjecting 100 parts by weight of an unsaturated copolymer comprising an .alpha.-olefin of 3 to 12 carbon atoms and a cyclic olefin represented by the following formula (I), and 0.1 to 300 parts by weight of a radically polymerizable monomer to the radical polymerization conditions: ##STR1## wherein R.sup.1 is a C.sub.2-5 alkylidene group or a C.sub.2-5 alkenyl group, R.sup.2 is a C.sub.1-5 hydrocarbon radical or H, and n is 0, 1 or 2.The graft-modified copolymer is imparted with various properties which are attributed to the polymer chain formed from the radically polymerizable monomer, without the excellent properties inherent in an .alpha.-olefin polymer being impaired. The copolymer is excellent in compatibility with other resins.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: August 2, 1994
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Masayuki Tomida, Hitoshi Nimura, Mitsutoshi Aritomi
  • Patent number: 5332801
    Abstract: Disclosed are processes for preparing a process for preparing a modified polyphenylene ether which comprises reacting any one of a borane compound having at least one boronhydrogen bond, an .alpha.,.beta.-unsaturated carbonyl compound or a mercaptane having a carbonyl group, a hydroxyl group or an alkoxysilyl group with a polyphenylene ether having a carbon-carbon unsaturated bond in a substituent, and optionally oxidizing the resulting borane-modified PPE under alkaline conditions.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: July 26, 1994
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Toru Tsukahara, Mitsutoshi Aritomi
  • Patent number: 5266673
    Abstract: A hydroxy-substituted poly(phenylene ether) resin can be produced by copolymerizing from 1.5 to 8 mol % of a phenol compound selected from those represented by the following formulae (a), (b), (c), (d), and (e): ##STR1## and from 98.5 to 92 mol % of a phenol compound of the following formula (f): ##STR2## The hydroxy-substituted poly(phenylene ether) resin shows excellent compatibility with a polyamide, a polycarbonate, a poly(butylene terephthalate), a poly(phenylene sulfide), and is useful as a copatibilizer or a modified resin for engineering plastics.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: November 30, 1993
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Toru Tsukahara, Hiromi Nishimura, Mitsutoshi Aritomi, Yusuke Arashiro, Shinichi Yamauchi
  • Patent number: 5252677
    Abstract: A functionalized polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an epoxy group, a hydroxyl group or a sulfonic group into a syndiotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the functional groups are obtained by the oxidation, sulfonation or the like of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: October 12, 1993
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Masayuki Tomita, Hiroshi Nakano, Hideshi Uchino, Toshihiko Sugano, Mitsutoshi Aritomi
  • Patent number: 5202409
    Abstract: Disclosed is a process for preparing a polyhydroxyphenylene ether resin which comprises copolymerizing a phenol-substituted compound having hydroxyl group as a substituent, represented by the formula (I): ##STR1## wherein m and n each represents an integer satisfying the formulae 1.ltoreq.m and m+n.ltoreq.4; J represents {(HO).sub.a --R.sup.1 --S}.sub.b --R.sup.2 -- where a and b each represents an integer of 1 to 6; and R.sup.1 and R.sup.2 each represents unsubstituted or halogen-substituted alkylene, alkenylene or arylene, or alkylene; K represents halogen, primary or secondary alkyl, alkenyl, phenyl, aminoalkyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy;with at least one phenol-substituted compound represented by the formula (II): ##STR2## wherein Qs each represents hydrogen, halogen, primary or secondary alkyl, alkenyl, aromatic, aminoalkyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy,and a resin composition containing the polyhydroxyphenylene ether resin prepared by the above method.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: April 13, 1993
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Toru Tsukahara, Mitsutoshi Aritomi, Yusuke Arashiro, Shinichi Yamauchi, Hiromi Nishimura
  • Patent number: 5191030
    Abstract: A process for producing an amino group terminated polyphenylene ether represented by the following general formula (I) ##STR1## wherein Q.sup.1 s each represents a halogen atom, a primary or secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group or a halohydrocarbon oxy group; Q.sup.2 s each represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group or halohydrocarbon oxy group; R represents an aliphatic hydrocarbon group having 1 to 32 carbon atoms, an aromatic hydrocarbon group or an araliphatic hydrocarbon group; and n is a number of 10 to 500, which process comprises reacting a polyphenylene ether represented by the following general formula (II) ##STR2## wherein Q.sub.1, Q.sub.2 and n are as define above, with a primary amine halide represented by the following general formula (III)X--R--NH.sub.2 (III)wherein R is as defined above, and X represents a halogen atom.
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: March 2, 1993
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Haruo Ohmura, Mitsutoshi Aritomi, Michiharu Kihira, Hiroshi Nakano
  • Patent number: 5177156
    Abstract: A process for producing a terminal-modified polyphenylene ether represented by formula (III): ##STR1## wherein Q.sup.1 represents a halogen atom, a primary of secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; Q.sup.2 represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; n represents an integer of at least 10; X represents an oxygen atom or a nitrogen atom;R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from from 1 to 3,which comprises reacting a polyphenylene ether represented by formula (I): ##STR2## wherein Q.sup.1, Q.sup.
    Type: Grant
    Filed: May 17, 1991
    Date of Patent: January 5, 1993
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Mitsutoshi Aritomi, Haruo Ohmura, Hiroshi Nakano, Michiharu Kihira, Yusuke Arashiro, Fumiyoshi Yamada, Shinako Mori, Fumiyo Ikehata
  • Patent number: 5128421
    Abstract: Disclosed is a method for preparing a hydroxyalkyl-functionalized polyphenylene ether which comprises reacting a polyphenylene ether represented by the formula: ##STR1## wherein Q.sub.1 each represents a halogen atom, a primary or secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbonoxy group or a halohydrocarbonoxy group; Q.sub.2 each represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbonoxy group or a halohydrocarbonoxy group; and m is an integer of 10 or more,with a functionalizing agent in the presence or absence of an organic solvent capable of dissolving the polyphenylene ether and in the presence of a basic catalyst.
    Type: Grant
    Filed: February 26, 1991
    Date of Patent: July 7, 1992
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Haruo Ohmura, Mitsutoshi Aritomi
  • Patent number: 5120800
    Abstract: Disclosed are processes for preparing a process for preparing a modified polyphenylene ether which comprises reacting any one of a borane compound having at least one boron-hydrogen bond, an .alpha.,.beta.-unsaturated carbonyl compound or a mercaptane having a carbonyl group, a hydroxyl group or an alkoxysilyl group with a polyphenylene ether having a carbon-carbon unsaturated bond in a substituent, and optionally oxidizing the resulting borane-modified PPE under alkaline conditions.
    Type: Grant
    Filed: April 5, 1991
    Date of Patent: June 9, 1992
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Toru Tsukahara, Mitsutoshi Aritomi
  • Patent number: 5004800
    Abstract: An aromatic polythioetherimide is disclosed, which comprises at least 50 mol % of a repeating unit represented by formula (I): ##STR1## wherein Ar is as defined in the specification, with the total of the repeating unit(s) being 100 mol %. The polythioetherimide has an excellent balance between heat resistance and mechanical properties as well as improved moldability.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: April 2, 1991
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Makoto Terauchi, Chikako Ikeda, Mitsutoshi Aritomi
  • Patent number: 4923942
    Abstract: An optical resin consisting essentially of a radical polymerization polymer of an ethylenically unsaturated monomer, characterized in that at least a major part of the ethlenically unsaturated monomer is an ester of 1 mole of tricyclo[5,2,1,0.sup.2,6 ]decanedimethanol with 2 moles of a mixture of acrylic acid and metharcylic acid. Because the resin is a polymer obtained from the restricted monomer as specified above, the resin possesses high thermal resistance and high heat stability as well as low hygroscopic property. Dimethanol compounds from higher Diels-Alder adducts of cyclopentadine are also used in place of the tricyclo [5,2,1,0.sup.2,6 ]decanedimthanol which is a Diels-Alder adduct of two moles of cyclopentadiene.
    Type: Grant
    Filed: September 30, 1988
    Date of Patent: May 8, 1990
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Tadao Takeyama, Mitsutoshi Aritomi
  • Patent number: 4783522
    Abstract: An aromatic polythioetherimide having a recurring unit of the following general formula (II): ##STR1## wherein --Ar--, which may be the same or different in the polymer, each represents a divalent aromatic residue and ##STR2## which may be the same or different in the polymer, each represents ##STR3## The aromatic polythioetherimides can be melt-molded, are excellent in the balance of mechanical properties and heat resistance, and can be widely used for parts in the electric and electronic fields, housings, automobile parts, aircraft interior parts, sliding parts, gears, cams, insulating materials, heat-resistant films, heat-resistant varnishes, heat-resistant fibers, etc., and preferably can be used as an engineering plastic for gears, cams, etc., and a heat-resistant insulating film material for electronic hardwares.
    Type: Grant
    Filed: July 11, 1986
    Date of Patent: November 8, 1988
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Mitsutoshi Aritomi, Makoto Terauchi
  • Patent number: 4734477
    Abstract: A method for producing a plastic substrate having Tg of 110.degree. C. or more is disclosed, which comprises radical polymerizing a polyfunctional (meth)acrylate compound in a mold by a cast molding method, removing the resulting substrate from the mold when the glass transition temperature of the substrate reaches 10.degree. to 100.degree. C., and then post-curing the substrate. The method of the present invention can provide high quality plastic substrates with high productivity.
    Type: Grant
    Filed: July 16, 1986
    Date of Patent: March 29, 1988
    Assignees: Mitsubishi Petrochemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Takao Inoue, Tadashi Sakairi, Mitsutoshi Aritomi, Tadao Takeyama, Takahiro Matsuo
  • Patent number: 4724257
    Abstract: An aromatic polythioetheramide-imide having a recurring unit of the following general formula (II): ##STR1## wherein --Ar--, which may be the same or different in the polymer, each represents a divalent aromatic residue. The aromatic polythioetheramide-imides are excellent in the balance of mechanical properties, heat resistance and moldability and can be used widely for parts in electric and electronic fields, housings, automobile parts, aircraft interior parts, sliding parts, gears, insulating materials, heat-resistant films, heat-resistant varnishes, heat-resistant fibers, etc.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: February 9, 1988
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Mitsutoshi Aritomi, Makoto Terauchi
  • Patent number: 4654178
    Abstract: A method for producing polyurethane or polyester containing therein the diacetylene group having high rigidity and useful in manufacturing precision mechanical parts, which comprises molding a polymer material containing therein the diacetylene group having a unit structure to be represented by the following general formula and a molecular weight in a range from 5.times.10.sup.2 to 1.times.10.sup.5 under a high pressure and at a temperature below the melting point of the polymer: ##STR1## wherein R is a divalent organic group; and x is an integer of 0 or 1.
    Type: Grant
    Filed: January 14, 1986
    Date of Patent: March 31, 1987
    Assignee: Agency of Industrial Science and Technology
    Inventors: Mitsutoshi Aritomi, Eisuke Fujiwara
  • Patent number: 4621134
    Abstract: Aromatic polythioetheramide polymers having a repeating unit represented by the formulae as shown below and a process for the production thereof are described. These polymers have excellent moldability, flame retardance, heat resistance, and chemical resistance, and are suitable for use as engineering plastics: ##STR1## wherein all the symbols are the same as defined in the specification and claims.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: November 4, 1986
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Mitsutoshi Aritomi, Makoto Terauchi