Patents by Inventor Mitsutoshi Aritomi
Mitsutoshi Aritomi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 6160048Abstract: There is provided a modified ethylene resin produced by subjecting (a) an ethylene resin to modification with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a hydrocarbon-terminated polyalkylene oxide chain, and with (c) an aromatic vinyl compound and/or (d) an ester of an .alpha.,.beta.-unsaturated carboxylic acid with an aliphatic alcohol.There is also provided an ethylene resin composition comprising: (A) 80 to 99.9% by weight of a modified ethylene resin produced by subjecting (a) an ethylene resin to modification at least with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a polyalkylene oxide chain; and (B) 20 to 0.1% by weight of a surfactant.Type: GrantFiled: August 14, 1998Date of Patent: December 12, 2000Assignee: Mitsubishi Chemical CorporationInventors: Tadashi Uyeda, Keiko Matsuhisa, Kenjiro Takayanagi, Mitsutoshi Aritomi
-
Patent number: 5939181Abstract: A porous molded article having microvoids therein which comprises a stretched product of a resin molded material made up of, as the base material, an olefinic resin composition containing from 95 to 50% by weight of a crystalline olefinic resin component (A) and from 5 to 50% by weight of a polymer of a cyclic olefin having a weight average molecular weight of not less than 1,000 and less than 10,000 and a glass transition point of from 180 to 400.degree. C. component (B).Type: GrantFiled: September 10, 1997Date of Patent: August 17, 1999Assignee: Oji-Yuka Synthetic Paper Co., Ltd.Inventors: Yuuta Kumano, Mitsutoshi Aritomi, Kenji Takasaki, Osamu Nishizawa, Nobuhiro Shibuya, Hisao Ochiai, Kenji Nakajima
-
Patent number: 5444125Abstract: An aminated polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an amino group, into an isotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated isotactic or syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the amino group is obtained by the amination of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.Type: GrantFiled: April 30, 1992Date of Patent: August 22, 1995Assignee: Mitsubishi Petrochemical Company LimitedInventors: Masayuki Tomita, Hideshi Uchino, Toshihiko Sugano, Takashi Fujita, Mitsutoshi Aritomi
-
Patent number: 5424359Abstract: Disclosed is a thermoplastic resin composition comprising(A) 90 to 10% by weight of a modified polyolefin type resin obtained by subjecting 100 parts by weight of a polyolefin type resin to graft polymerization with 0.01 to 20 parts by weight of an .alpha.,.beta.-unsaturated carboxylate having a hydroxyl group and 0.01 to 50 parts by weight of an aromatic vinyl compound; and(B) 10 to 90% by weight of a saturated polyester.Type: GrantFiled: February 24, 1994Date of Patent: June 13, 1995Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Yusuke Arashiro, Yoshio Katoh, Keiko Matsuhisa, Mitsutoshi Aritomi
-
Patent number: 5334664Abstract: A method for producing a graft-modified copolymer comprising the step of subjecting 100 parts by weight of an unsaturated copolymer comprising an .alpha.-olefin of 3 to 12 carbon atoms and a cyclic olefin represented by the following formula (I), and 0.1 to 300 parts by weight of a radically polymerizable monomer to the radical polymerization conditions: ##STR1## wherein R.sup.1 is a C.sub.2-5 alkylidene group or a C.sub.2-5 alkenyl group, R.sup.2 is a C.sub.1-5 hydrocarbon radical or H, and n is 0, 1 or 2.The graft-modified copolymer is imparted with various properties which are attributed to the polymer chain formed from the radically polymerizable monomer, without the excellent properties inherent in an .alpha.-olefin polymer being impaired. The copolymer is excellent in compatibility with other resins.Type: GrantFiled: April 30, 1993Date of Patent: August 2, 1994Assignee: Mitsubishi Petrochemical Company LimitedInventors: Masayuki Tomida, Hitoshi Nimura, Mitsutoshi Aritomi
-
Patent number: 5332801Abstract: Disclosed are processes for preparing a process for preparing a modified polyphenylene ether which comprises reacting any one of a borane compound having at least one boronhydrogen bond, an .alpha.,.beta.-unsaturated carbonyl compound or a mercaptane having a carbonyl group, a hydroxyl group or an alkoxysilyl group with a polyphenylene ether having a carbon-carbon unsaturated bond in a substituent, and optionally oxidizing the resulting borane-modified PPE under alkaline conditions.Type: GrantFiled: February 10, 1993Date of Patent: July 26, 1994Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Toru Tsukahara, Mitsutoshi Aritomi
-
Patent number: 5266673Abstract: A hydroxy-substituted poly(phenylene ether) resin can be produced by copolymerizing from 1.5 to 8 mol % of a phenol compound selected from those represented by the following formulae (a), (b), (c), (d), and (e): ##STR1## and from 98.5 to 92 mol % of a phenol compound of the following formula (f): ##STR2## The hydroxy-substituted poly(phenylene ether) resin shows excellent compatibility with a polyamide, a polycarbonate, a poly(butylene terephthalate), a poly(phenylene sulfide), and is useful as a copatibilizer or a modified resin for engineering plastics.Type: GrantFiled: May 15, 1992Date of Patent: November 30, 1993Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Toru Tsukahara, Hiromi Nishimura, Mitsutoshi Aritomi, Yusuke Arashiro, Shinichi Yamauchi
-
Patent number: 5252677Abstract: A functionalized polymer having excellent adhesion, printability, and compatibility in polymer blends or the like which are obtained by introducing an epoxy group, a hydroxyl group or a sulfonic group into a syndiotactic .alpha.-olefin polymer having an olefinic unsaturated bond at its terminus is disclosed. The terminal unsaturated syndiotactic .alpha.-olefin polymer is obtained by polymerizing an .alpha.-olefin with a catalyst comprising the combination of a metallocene compound and an alumoxane, and the functional groups are obtained by the oxidation, sulfonation or the like of the terminal unsaturated group, by the addition of a compound containing the corresponding functional group to the unsaturated bond, or by the conversion of a precursor polymer containing a precursor of the functional group into a polymer containing the functional group desired.Type: GrantFiled: January 4, 1993Date of Patent: October 12, 1993Assignee: Mitsubishi Petrochemical Company LimitedInventors: Masayuki Tomita, Hiroshi Nakano, Hideshi Uchino, Toshihiko Sugano, Mitsutoshi Aritomi
-
Patent number: 5202409Abstract: Disclosed is a process for preparing a polyhydroxyphenylene ether resin which comprises copolymerizing a phenol-substituted compound having hydroxyl group as a substituent, represented by the formula (I): ##STR1## wherein m and n each represents an integer satisfying the formulae 1.ltoreq.m and m+n.ltoreq.4; J represents {(HO).sub.a --R.sup.1 --S}.sub.b --R.sup.2 -- where a and b each represents an integer of 1 to 6; and R.sup.1 and R.sup.2 each represents unsubstituted or halogen-substituted alkylene, alkenylene or arylene, or alkylene; K represents halogen, primary or secondary alkyl, alkenyl, phenyl, aminoalkyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy;with at least one phenol-substituted compound represented by the formula (II): ##STR2## wherein Qs each represents hydrogen, halogen, primary or secondary alkyl, alkenyl, aromatic, aminoalkyl, haloalkyl, hydrocarbonoxy or halohydrocarbonoxy,and a resin composition containing the polyhydroxyphenylene ether resin prepared by the above method.Type: GrantFiled: November 29, 1991Date of Patent: April 13, 1993Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Toru Tsukahara, Mitsutoshi Aritomi, Yusuke Arashiro, Shinichi Yamauchi, Hiromi Nishimura
-
Patent number: 5191030Abstract: A process for producing an amino group terminated polyphenylene ether represented by the following general formula (I) ##STR1## wherein Q.sup.1 s each represents a halogen atom, a primary or secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group or a halohydrocarbon oxy group; Q.sup.2 s each represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group or halohydrocarbon oxy group; R represents an aliphatic hydrocarbon group having 1 to 32 carbon atoms, an aromatic hydrocarbon group or an araliphatic hydrocarbon group; and n is a number of 10 to 500, which process comprises reacting a polyphenylene ether represented by the following general formula (II) ##STR2## wherein Q.sub.1, Q.sub.2 and n are as define above, with a primary amine halide represented by the following general formula (III)X--R--NH.sub.2 (III)wherein R is as defined above, and X represents a halogen atom.Type: GrantFiled: September 19, 1991Date of Patent: March 2, 1993Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Haruo Ohmura, Mitsutoshi Aritomi, Michiharu Kihira, Hiroshi Nakano
-
Patent number: 5177156Abstract: A process for producing a terminal-modified polyphenylene ether represented by formula (III): ##STR1## wherein Q.sup.1 represents a halogen atom, a primary of secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; Q.sup.2 represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; n represents an integer of at least 10; X represents an oxygen atom or a nitrogen atom;R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from from 1 to 3,which comprises reacting a polyphenylene ether represented by formula (I): ##STR2## wherein Q.sup.1, Q.sup.Type: GrantFiled: May 17, 1991Date of Patent: January 5, 1993Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Mitsutoshi Aritomi, Haruo Ohmura, Hiroshi Nakano, Michiharu Kihira, Yusuke Arashiro, Fumiyoshi Yamada, Shinako Mori, Fumiyo Ikehata
-
Patent number: 5128421Abstract: Disclosed is a method for preparing a hydroxyalkyl-functionalized polyphenylene ether which comprises reacting a polyphenylene ether represented by the formula: ##STR1## wherein Q.sub.1 each represents a halogen atom, a primary or secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbonoxy group or a halohydrocarbonoxy group; Q.sub.2 each represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbonoxy group or a halohydrocarbonoxy group; and m is an integer of 10 or more,with a functionalizing agent in the presence or absence of an organic solvent capable of dissolving the polyphenylene ether and in the presence of a basic catalyst.Type: GrantFiled: February 26, 1991Date of Patent: July 7, 1992Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Haruo Ohmura, Mitsutoshi Aritomi
-
Patent number: 5120800Abstract: Disclosed are processes for preparing a process for preparing a modified polyphenylene ether which comprises reacting any one of a borane compound having at least one boron-hydrogen bond, an .alpha.,.beta.-unsaturated carbonyl compound or a mercaptane having a carbonyl group, a hydroxyl group or an alkoxysilyl group with a polyphenylene ether having a carbon-carbon unsaturated bond in a substituent, and optionally oxidizing the resulting borane-modified PPE under alkaline conditions.Type: GrantFiled: April 5, 1991Date of Patent: June 9, 1992Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Toru Tsukahara, Mitsutoshi Aritomi
-
Patent number: 5004800Abstract: An aromatic polythioetherimide is disclosed, which comprises at least 50 mol % of a repeating unit represented by formula (I): ##STR1## wherein Ar is as defined in the specification, with the total of the repeating unit(s) being 100 mol %. The polythioetherimide has an excellent balance between heat resistance and mechanical properties as well as improved moldability.Type: GrantFiled: June 9, 1988Date of Patent: April 2, 1991Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Makoto Terauchi, Chikako Ikeda, Mitsutoshi Aritomi
-
Patent number: 4923942Abstract: An optical resin consisting essentially of a radical polymerization polymer of an ethylenically unsaturated monomer, characterized in that at least a major part of the ethlenically unsaturated monomer is an ester of 1 mole of tricyclo[5,2,1,0.sup.2,6 ]decanedimethanol with 2 moles of a mixture of acrylic acid and metharcylic acid. Because the resin is a polymer obtained from the restricted monomer as specified above, the resin possesses high thermal resistance and high heat stability as well as low hygroscopic property. Dimethanol compounds from higher Diels-Alder adducts of cyclopentadine are also used in place of the tricyclo [5,2,1,0.sup.2,6 ]decanedimthanol which is a Diels-Alder adduct of two moles of cyclopentadiene.Type: GrantFiled: September 30, 1988Date of Patent: May 8, 1990Assignee: Mitsubishi Petrochemical Company, Ltd.Inventors: Tadao Takeyama, Mitsutoshi Aritomi
-
Patent number: 4783522Abstract: An aromatic polythioetherimide having a recurring unit of the following general formula (II): ##STR1## wherein --Ar--, which may be the same or different in the polymer, each represents a divalent aromatic residue and ##STR2## which may be the same or different in the polymer, each represents ##STR3## The aromatic polythioetherimides can be melt-molded, are excellent in the balance of mechanical properties and heat resistance, and can be widely used for parts in the electric and electronic fields, housings, automobile parts, aircraft interior parts, sliding parts, gears, cams, insulating materials, heat-resistant films, heat-resistant varnishes, heat-resistant fibers, etc., and preferably can be used as an engineering plastic for gears, cams, etc., and a heat-resistant insulating film material for electronic hardwares.Type: GrantFiled: July 11, 1986Date of Patent: November 8, 1988Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Mitsutoshi Aritomi, Makoto Terauchi
-
Patent number: 4734477Abstract: A method for producing a plastic substrate having Tg of 110.degree. C. or more is disclosed, which comprises radical polymerizing a polyfunctional (meth)acrylate compound in a mold by a cast molding method, removing the resulting substrate from the mold when the glass transition temperature of the substrate reaches 10.degree. to 100.degree. C., and then post-curing the substrate. The method of the present invention can provide high quality plastic substrates with high productivity.Type: GrantFiled: July 16, 1986Date of Patent: March 29, 1988Assignees: Mitsubishi Petrochemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.Inventors: Takao Inoue, Tadashi Sakairi, Mitsutoshi Aritomi, Tadao Takeyama, Takahiro Matsuo
-
Patent number: 4724257Abstract: An aromatic polythioetheramide-imide having a recurring unit of the following general formula (II): ##STR1## wherein --Ar--, which may be the same or different in the polymer, each represents a divalent aromatic residue. The aromatic polythioetheramide-imides are excellent in the balance of mechanical properties, heat resistance and moldability and can be used widely for parts in electric and electronic fields, housings, automobile parts, aircraft interior parts, sliding parts, gears, insulating materials, heat-resistant films, heat-resistant varnishes, heat-resistant fibers, etc.Type: GrantFiled: July 14, 1986Date of Patent: February 9, 1988Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Mitsutoshi Aritomi, Makoto Terauchi
-
Patent number: 4654178Abstract: A method for producing polyurethane or polyester containing therein the diacetylene group having high rigidity and useful in manufacturing precision mechanical parts, which comprises molding a polymer material containing therein the diacetylene group having a unit structure to be represented by the following general formula and a molecular weight in a range from 5.times.10.sup.2 to 1.times.10.sup.5 under a high pressure and at a temperature below the melting point of the polymer: ##STR1## wherein R is a divalent organic group; and x is an integer of 0 or 1.Type: GrantFiled: January 14, 1986Date of Patent: March 31, 1987Assignee: Agency of Industrial Science and TechnologyInventors: Mitsutoshi Aritomi, Eisuke Fujiwara
-
Patent number: 4621134Abstract: Aromatic polythioetheramide polymers having a repeating unit represented by the formulae as shown below and a process for the production thereof are described. These polymers have excellent moldability, flame retardance, heat resistance, and chemical resistance, and are suitable for use as engineering plastics: ##STR1## wherein all the symbols are the same as defined in the specification and claims.Type: GrantFiled: April 8, 1985Date of Patent: November 4, 1986Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Mitsutoshi Aritomi, Makoto Terauchi