Abstract: A crystalline AlH3 is ball-milled in a hydrogen atmosphere while applying a force of 10 G to 30 G (in which G is gravitational acceleration). The milling time is more than 10 minutes and less than 60 minutes. The hydrogen storage material thus produced has a structure containing a plurality of matrix phases and a grain boundary phase disposed between the matrix phases. The matrix phases comprise Al and have a side length of 1 to 200 nm, and the grain boundary phase comprises an amorphous phase and contains hydrogen in the state of a solid solution.

Abstract: A mixed powder of AlH3 and MgH2 is ball-milled in a hydrogen atmosphere while applying force of 5 G through 30 G (in which G is gravitational acceleration), and the thus-obtained milled product is dehydrogenated to produce a hydrogen storage material. The hydrogen storage material comprises an amorphous phase containing an Al—Mg alloy as a mother phase, and a crystalline Al phase having a maximum length of 100 nm or less, the crystalline Al phase being distributed as a dispersed phase in the mother phase.

Abstract: An organometallic complex [Cu2(pyridine-3,5-dicarboxylate)2]n is provided by bonding a plurality of Cu2(pyridine-3,5-dicarboxylate)2 repeating units to each other. The organometallic complex can be obtained by the steps of dissolving copper acetate monohydrate or anhydrate and pyridine-3,5-dicarboxylic acid in a solvent, heating the solution at 50° C. to 140° C. for 24 to 168 hours to generate a reaction product, and then removing a guest molecule from the reaction product.

Abstract: A crystalline Al phase and a crystalline TiH2 phase each having a maximum length of 200 nm or less are dispersed in an amorphous phase containing an Al—Mg alloy to obtain a hydrogen storage material capable of reversibly storing and releasing hydrogen.

Abstract: A mixed powder of AlH3 and MgH2 is ball-milled in a hydrogen atmosphere while applying force of 5 G through 30 G (in which G is gravitational acceleration), and the thus-obtained milled product is dehydrogenated to produce a hydrogen storage material. The hydrogen storage material comprises an amorphous phase containing an Al—Mg alloy as a mother phase, and a crystalline Al phase having a maximum length of 100 nm or less, the crystalline Al phase being distributed as a dispersed phase in the mother phase.

Abstract: A crystalline Al phase and a crystalline TiH2 phase each having a maximum length of 200 nm or less are dispersed in an amorphous phase containing an Al—Mg alloy to obtain a hydrogen storage material capable of reversibly storing and releasing hydrogen.

Abstract: A crystalline Al phase and a crystalline TiH2 phase each having a maximum length of 200 nm or less are dispersed in an amorphous phase containing an Al—Mg alloy to obtain a hydrogen storage material capable of reversibly storing and releasing hydrogen.

Abstract: An organometallic complex [Cu2(pyridine-3,5-dicarboxylate)2]n is provided by bonding a plurality of Cu2(pyridine-3,5-dicarboxylate)2 repeating units to each other. The organometallic complex can be obtained by the steps of dissolving copper acetate monohydrate or anhydrate and pyridine-3,5-dicarboxylic acid in a solvent, heating the solution at 50° C. to 140° C. for 24 to 168 hours to generate a reaction product, and then removing a guest molecule from the reaction product.

Abstract: A hydrogen tank filling station includes a high-pressure hydrogen storage tank, a hydrogen supply nozzle for filling a hydrogen tank mounted on a vehicle with hydrogen from the high-pressure hydrogen storage tank, a hydrogen supply pipe, a holder stand for holding the hydrogen supply nozzle, a limit switch for detecting whether the hydrogen supply nozzle is held on the holder stand or not, a cooling system for cooling the hydrogen tank, and a valve controller for controlling a cooling operation performed by the cooling system on the hydrogen tank.

Abstract: After AlH3 is synthesized, ball milling is performed under a condition in which a force of 2 G to 20 G (G represents the acceleration of gravity) is applied, to thereby provide AlH3 having an X-ray diffraction pattern in the form of a halo pattern. That is, for example, nanostructured AlH3 is provided, in which a grain boundary phase intervenes in a matrix phase, a side length t2 of the matrix phase is not more than 20 nm, and a width w2 of the grain boundary phase is not more than 10 nm. Alternatively, amorphous AlH3 may be provided. Further, hydrogen is released from AlH3 on which ball milling has been completed, and then the hydrogen is absorbed to induce a change into AlHx (provided that 0<x?3 is satisfied). A dopant may also be added. A hydrogen storage container is constructed accommodating the hydrogen absorbing material, which is obtained as described above, inside the container.

Abstract: A crystalline AlH3 is ball-milled in a hydrogen atmosphere while applying a force of 10 G to 30 G (in which G is gravitational acceleration). The milling time is more than 10 minutes and less than 60 minutes. The hydrogen storage material thus produced has a structure containing a plurality of matrix phases and a grain boundary phase disposed between the matrix phases. The matrix phases comprise Al and have a side length of 1 to 200 nm, and the grain boundary phase comprises an amorphous phase and contains hydrogen in the state of a solid solution.

Abstract: An hydrogen tank filling apparatus includes a first hydrogen supply pipe for supplying hydrogen substantially at an atmospheric temperature from a high-pressure hydrogen storage tank to a hydrogen tank, a second hydrogen supply pipe for supplying cooled hydrogen from the high-pressure hydrogen storage tank to the hydrogen tank, and an internal tank temperature measuring unit for measuring the temperature inside the hydrogen tank. The first hydrogen supply pipe and the second hydrogen supply pipe are selectively switched by a control unit, depending on changes in the temperature inside the hydrogen tank.

Abstract: An unactivated, poorly activatable hydrogen storage component and an activated hydrogen storage component are mixed to prepare a hydrogen storage material. When the hydrogen storage material is activated, the poorly activatable hydrogen storage component is converted to a hydrogen storable state in a remarkably short time. The poorly activatable hydrogen storage component may be a V—Cr—Ti hydrogen storage alloy having a body-centered cubic (BCC) crystal structure. The activated hydrogen storage component preferably is MgHx (0.1?x?2) doped with a nanoparticle of at least one atom selected from the group of Ni, Fe, Ti, Mn, and V.

Abstract: A hydrogen storage tank comprises a hydrogen adsorbent accommodated in a pressure-resistant container. The hydrogen adsorbent is capable of adsorbing and retaining hydrogen gas of a volume exceeding an occupation volume occupied by the hydrogen adsorbent itself. As for the hydrogen adsorbent, the amount of endothermic heat, which is generated when the adsorbed hydrogen gas is released, is not more than 16 kJ per mol of hydrogen molecules. The hydrogen adsorbent is prevented from leaking outside of the pressure-resistant container by a filter.

Abstract: After AlH3 is synthesized, ball milling is performed under a condition in which a force of 2 G to 20 G (G represents the acceleration of gravity) is applied, to thereby provide AlH3 having an X-ray diffraction pattern in the form of a halo pattern. That is, for example, nanostructured AlH3 is provided, in which a grain boundary phase intervenes in a matrix phase, a side length t2 of the matrix phase is not more than 20 nm, and a width w2 of the grain boundary phase is not more than 10 nm. Alternatively, amorphous AlH3 may be provided. Further, hydrogen is released from AlH3 on which ball milling has been completed, and then the hydrogen is absorbed to induce a change into AlHx (provided that 0<x?3 is satisfied). A dopant may also be added. A hydrogen storage container is constructed accommodating the hydrogen absorbing material, which is obtained as described above, inside the container.

Abstract: An hydrogen tank filling apparatus includes a first hydrogen supply pipe for supplying hydrogen substantially at an atmospheric temperature from a high-pressure hydrogen storage tank to a hydrogen tank, a second hydrogen supply pipe for supplying cooled hydrogen from the high-pressure hydrogen storage tank to the hydrogen tank, and an internal tank temperature measuring unit for measuring the temperature inside the hydrogen tank. The first hydrogen supply pipe and the second hydrogen supply pipe are selectively switched by a control unit, depending on changes in the temperature inside the hydrogen tank.

Abstract: A hydrogen tank filling station includes a high-pressure hydrogen storage tank, a hydrogen supply nozzle for filling a hydrogen tank mounted on a vehicle with hydrogen from the high-pressure hydrogen storage tank, a hydrogen supply pipe, a holder stand for holding the hydrogen supply nozzle, a limit switch for detecting whether the hydrogen supply nozzle is held on the holder stand or not, a cooling system for cooling the hydrogen tank, and a valve controller for controlling a cooling operation performed by the cooling system on the hydrogen tank.

Abstract: A heater is disposed in contact with a hydrogen storage unit filled with a hydrogen absorption material. The heater includes at least one combustion chamber which includes a catalyst carrier and in which a combustible gas is burned, a combustible gas burning catalyst carried on the catalyst carrier, at least one combustible gas introduction chamber adjoining the combustion chamber with its chamber wall interposed therebetween, a plurality of combustible gas inlets disposed in a dispersed manner in the chamber wall to permit the combustion chamber and the introduction chamber to communicate with each other, and a combustion gas outlet communicating with the combustion chamber. Thus, the degree of uniformity of a temperature profile is decreased.

Abstract: To produce a hydrogen absorbing alloy powder which is an aggregate of alloy particles each including a metal matrix and added-components, an aggregate of metal matrix particles and an aggregate of added-component particles are used, and mechanical alloying is carried out. In this case, the relationship between the particle size D of the metal matrix particles and the particle size d of the added-component particles is set at d?D/6. Thus, the milling time can be shortened remarkably.

Abstract: To produce high-pressure hydrogen, water and a hydrogen-generating material (MgH2) which reacts with water to generate hydrogen are weighed so that a target high hydrogen pressure is generated in a high-pressure container. Then, the hydrogen-generating material is introduced into the high-pressure container through its supply port, and water is introduced into the high-pressure container through the supply port. Thereafter, the supply port is closed, thereby causing a reaction between the hydrogen-generating material and the water, so that the hydrogen pressure in the high-pressure container reaches a target high hydrogen pressure.