Abstract: To form, on a ceramic member or a metal member, a thermal spray ceramic coating film which achieves both the quality of a ceramic coating film and gas barrier property, and with which a composite oxide having a melting point lower than the ambient temperature will not form when used as a coating film on a ceramic member or a metal member constituting a glass article manufacturing apparatus. A ceramic coating film-provided member comprising a ceramic member or a metal member and a thermal spray ceramic coating film formed on at least a part of the surface of the ceramic member or the metal member, wherein the thermal spray ceramic coating film contains Al2O3 and 12CaO.7Al2O3, and the weight ratio of CaO to Al2O3 (CaO/Al2O3) is more than 0.11 to 0.50.

Abstract: To form, on a ceramic member or a metal member, a thermal spray ceramic coating film which achieves both the quality of a ceramic coating film and gas barrier property, and with which a composite oxide having a melting point lower than the ambient temperature will not form when used as a coating film on a ceramic member or a metal member constituting a glass article manufacturing apparatus. A ceramic coating film-provided member comprising a ceramic member or a metal member and a thermal spray ceramic coating film formed on at least a part of the surface of the ceramic member or the metal member, wherein the thermal spray ceramic coating film contains Al2O3 and 12CaO.7Al2O3, and the weight ratio of CaO to Al2O3 (CaO/Al2O3) is more than 0.11 to 0.50.

Abstract: A glass production method is provided that includes a forming step of forming a glass ribbon from molten glass by a glass forming unit, and a conveying step of gradually cooling the glass ribbon to a temperature less than or equal to a strain point temperature of glass while conveying the glass ribbon by conveyance rolls. The conveying step includes a buffer layer forming step of forming a buffer layer made of an inorganic salt by spraying a solution containing the inorganic salt directly onto at least a portion of the conveyance roll and causing the solution sprayed onto the conveyance roll to dry out.