Abstract: A method of coating a metallic substrate includes immersing a metallic substrate in a polymer composition including a conductive 3,4-ethylene dioxythiophene (EDOT) polymer, a gelatin polyelectrolyte, an antibacterial drug, an organic solvent, and an inorganic salt solute, and further coating the polymer composition onto a surface of the metallic substrate by cyclic voltammetry to form a coating on the surface of the metallic substrate. The coating on the metallic substrate is performed such that the gelatin and the antibacterial drug are uniformly distributed throughout the coating, and the coating has a thickness between 7.0 and 15.0 micrometers. The metallic substrate is a stainless steel (SS). An implantable medical device including a metallic substrate coated by the present method.

Abstract: A method to form a metal matrix composite reinforced with eggshell (ES). The method includes preparing an ES powder, blending and milling the ES powder with at least one metal powder selected from the group consisting of magnesium (Mg), zirconium (Zr) to form a powder mixture, compacting and sintering the powder mixture to form the metal matrix composite. In addition, a Mg—Zr-ES metal matrix composite with improved corrosion resistance, having an amount of magnesium from 95 to 97 wt. %, an amount of zirconium from 1 to 2 wt. %, and an amount of ES from 1 to 4 wt. %, may be used for biomedical applications.

Abstract: A saltwater corrosion resistant hybrid composite is provided. The saltwater corrosion resistant hybrid composite coating includes at least one conductive polymer, crumb rubber, and a cured epoxy. The conductive polymer is dispersed in particles of the crumb rubber to form a network. The network is dispersed in the cured epoxy to form the saltwater corrosion resistant hybrid composite coating. A method of making of the saltwater corrosion resistant hybrid composite is also provided. A metal when coated with the resistant hybrid composite of the present disclosure is resistant to salt-water corrosion.

Abstract: A method for producing a biodegradable magnesium metal composite that includes a polycrystalline magnesium matrix and TiB2 grains which are homogenously distributed in the polycrystalline magnesium matrix involving spark plasma sintering a milled mixture of magnesium powder and TiB2 powder. The temperature, pressure, and time of the spark plasma sintering used in the method are used to give high microharness, macrohardness, and density with low porosity by limiting the grain growth in the composite. The method yields a biodegradable magnesium metal composite having an improved microhardness, macrohardness, density, and porosity compared to other composites and methods of making composites.

Abstract: A saltwater corrosion resistant composite coating is described. The coating includes at least one conductive polymer, chitosan, reduced graphene oxide (rGO), and a cured epoxy. The rGO and chitosan are dispersed in particles of the conductive polymer to form a 3D network. At least a portion of the chitosan is covalently bound to the rGO. At least a portion of the conductive polymer is covalently bound to the chitosan, and the 3D network is dispersed in the cured epoxy.

Abstract: A saltwater corrosion resistant hybrid composite is provided. The saltwater corrosion resistant hybrid composite coating includes at least one conductive polymer, crumb rubber, and a cured epoxy. The conductive polymer is dispersed in particles of the crumb rubber to form a network. The network is dispersed in the cured epoxy to form the saltwater corrosion resistant hybrid composite coating. A method of making of the saltwater corrosion resistant hybrid composite is also provided. A metal when coated with the resistant hybrid composite of the present disclosure is resistant to salt-water corrosion.

Abstract: A biocompatible polymer hybrid nanocomposite coating on a surface of a substrate, such as titanium and its alloys. The coating can be achieved by an electrostatic spray coating, preferably using ultra-high molecular weight polyethylene (UHMWPE) as a matrix for the coating. For example, up to 2.95 wt. % carbon nanotubes can be used as reinforcement, as can up to 4.95 wt. % hydroxyapatite. A dispersion of CNTs and HA in the coating is substantially uniform. The tribological performance of such coatings include high hardness, improved scratch resistance, excellent wear resistance, and corrosion resistance compared to pure UHMWPE coatings.

Abstract: A method for producing a biodegradable magnesium metal composite that includes a polycrystalline magnesium matrix and TiB2 grains which are homogenously distributed in the polycrystalline magnesium matrix involving spark plasma sintering a milled mixture of magnesium powder and TiB2 powder. The temperature, pressure, and time of the spark plasma sintering used in the method are used to give high microharness, macrohardness, and density with low porosity by limiting the grain growth in the composite. The method yields a biodegradable magnesium metal composite having an improved microhardness, macrohardness, density, and porosity compared to other composites and methods of making composites.

Abstract: A biocompatible polymer hybrid nanocomposite coating on a surface of a substrate, such as titanium and its alloys. The coating can be achieved by an electrostatic spray coating, preferably using ultra-high molecular weight polyethylene (UHMWPE) as a matrix for the coating. For example, up to 2.95 wt. % carbon nanotubes can be used as reinforcement, as can up to 4.95 wt. % hydroxyapatite. A dispersion of CNTs and HA in the coating is substantially uniform. The tribological performance of such coatings include high hardness, improved scratch resistance, excellent wear resistance, and corrosion resistance compared to pure UHMWPE coatings.

Abstract: Durable, porous alumina-carbon nanotube membranes and methods for making them using spark plasma sintering. Methods for removing heavy metals such as cadmium from waste water using alumina-carbon nanotube membranes.

Abstract: Alloys of titanium with 20-22 at. % niobium and 12-13 at. % zirconium. The alloys are prepared by mechanical alloying of elemental powders and densification by spark plasma sintering. The alloys have a nano-scaled, equiaxed granular structure, a microhardness of at least 650 HV and a modulus of 90-140 GPa. The inventive alloy is corrosion resistant, biocompatible, and is of a higher wear resistance and durability compared to the Ti-6Al-4V alloy. The bioactive surface of the inventive nanostructured alloy promotes a higher protein adsorption that stimulates new bone formation than other titanium-based alloys. These alloys are suitable for various biomedical and dental applications.

Abstract: Alloys of titanium with 20-22 at. % niobium and 12-13 at. % zirconium. The alloys are prepared by mechanical alloying of elemental powders and densification by spark plasma sintering. The alloys have a nano-scaled, equiaxed granular structure, a microhardness of at least 650 HV and a modulus of 90-140 GPa. The inventive alloy is corrosion resistant, biocompatible, and is of a higher wear resistance and durability compared to the Ti-6Al-4V alloy. The bioactive surface of the inventive nanostructured alloy promotes a higher protein adsorption that stimulates new bone formation than other titanium-based alloys. These alloys are suitable for various biomedical and dental applications.

Abstract: A method for preparing an alloy, including mixing elemental powders of Nb and Zr to obtain a powder mixture, and mechanical alloying to obtain an alloyed powder mixture, where the alloyed powder is more than 50% amorphous. The spark plasma sintering machine was used for the consolidation of the Nb60Zr40 sample prepared by mechanical alloying. An Nb—Zr alloy composition obtained by the method, having an average crystallite size of 18 to 26 nm, hardness of 580.