Abstract: A drilling fluid composition comprising an aqueous base fluid, a viscosifier, and a H2S scavenger comprising copper nitrate, wherein the drilling fluid composition has a H2S sorption capacity from about 4.0 to about 6.0 gram per one milliliter of the drilling fluid composition; and a method of drilling a subterranean geological formation using thereof are provided. Various embodiments of the drilling fluid composition and the method are also provided.

Abstract: The present invention relates to a process for treating a sandstone formation comprising introducing a fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA) and having a pH of between 1 and 14 into the formation. The invention in addition relates to a fluid suitable for use in the above process containing 5-30 wt % of glutamic acid N,N-diacetic acid or a salt thereof (GLDA) and/or methylglycine N,N-diacetic acid or a salt thereof (MGDA), a corrosion inhibitor, a surfactant, and a mutual solvent.

Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.

Abstract: A drilling fluid composition comprising an aqueous base fluid, a viscosifier, and a H2S scavenger comprising copper nitrate, wherein the drilling fluid composition has a H2S sorption capacity from about 4.0 to about 6.0 gram per one milliliter of the drilling fluid composition; and a method of drilling a subterranean geological formation using thereof are provided. Various embodiments of the drilling fluid composition and the method are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: A fracturing fluid composition that includes a chelating agent, e.g. GLDA, and a polymeric additive comprising a copolymer of acrylamido-tert-butyl sulfonate and hydrolyzed polyacrylamide diluted in an aqueous base fluid, e.g. seawater, and a method of fracking a geological formation using the fracturing fluid composition. Various embodiments of the fracturing fluid composition and the method of fracking are also provided.

Abstract: The present invention relates to a process for treating a subterranean formation wherein a fluid containing an ammonium salt of glutamic acid N,N-diacetic acid (GLDA) or methylglycine N,N-diacetic acid (MGDA) is introduced into the formation.

Abstract: The chelating fluid for enhanced oil recovery in carbonate reservoirs and the method of using the same utilizes a chelating fluid injected into a carbonate oil reservoir through a fluid injection system. The chelating fluid is a solution of a polyamino carboxylic acid chelating agent in brine, with the polyamino carboxylic acid chelating agent having a concentration of approximately 5.0 wt % of the solution, with the solution having a pH of approximately 11.0. The polyamino carboxylic acid chelating agent is preferably ethylenediaminetetraacetic acid (EDTA). The brine preferably has a relatively high salinity, with a sodium chloride concentration preferably on the order of approximately 18,300 ppm.

Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.

Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.

Abstract: The enhanced oil recovery using seawater and EDTA (ethylenediaminetetraacetic acid) is a method that uses injection of EDTA in seawater to enhance the recovery of oil from sandstone reservoirs. The EDTA may be introduced into seawater during the initial extraction of oil from the reservoir by seawater injection, or a solution of EDTA in seawater may be used to flush residual oil from the reservoir after the initial extraction by seawater injection. In either case, the EDTA is present in about 1.0 wt % to about 5.0 wt % of the seawater solution, and the solution has a pH of between 10.5 and 11.0.

Abstract: The chelating fluid for enhanced oil recovery in carbonate reservoirs and the method of using the same utilizes a chelating fluid injected into a carbonate oil reservoir through a fluid injection system. The chelating fluid is a solution of a polyamino carboxylic acid chelating agent in brine, with the polyamino carboxylic acid chelating agent having a concentration of approximately 5.0 wt % of the solution, with the solution having a pH of approximately 11.0. The polyamino carboxylic acid chelating agent is preferably ethylenediaminetetraacetic acid (EDTA). The brine preferably has a relatively high salinity, with a sodium chloride concentration preferably on the order of approximately 18,300 ppm.

Abstract: The method of maintaining oil reservoir pressure involves injecting seawater having a concentration of about 1 wt % of a polyamino carboxylic acid or salt thereof as a chelating agent into the water zone of an oil reservoir, which reduces the formation of scale, thereby maintaining oil reservoir pressure. The polyamino carboxylic acid may be ethylenediaminetetraacetic acid (EDTA), acid (HEDTA), or hydroxyethyliminodiacetic acid (HEIDA). When used in larger concentrations, e.g., between 5 to 10 wt %, flooding the core with seawater containing the polyamino carboxylic acids not only prevents scale formation, but also improves core permeability. Instead of seawater, low salinity water may be used for the latter purpose.

Abstract: The method for enhanced oil recovery by in situ carbon dioxide generation utilizes a chelating fluid injected into an oil reservoir through a fluid injection system. The chelating fluid is a low pH solution of a polyamino carboxylic acid chelating agent. The polyamino carboxylic acid chelating agent may have a concentration of about 5 wt %. The polyamino carboxylic acid chelating agent is preferably either an aqueous solution of H2Na2-ethylenediaminetetraacetic acid (pH 4.5), H3-hydroxyethyl ethylenediamine triacetic acid (pH 2.5), or an aqueous solution of H2NaHEDTA (pH 4). The injection of the chelating fluid may be preceded by flooding the core with seawater, and is followed by injection of either to seawater, a high pH chelating agent, or low salinity water to ensure maximal extraction of oil from the reservoir. The method is particularly for use in formations where the core of the reservoir has a carbonate rock matrix.

Abstract: The present invention relates to a process for fracturing a subterranean formation comprising a step of fracturing the formation and a step of introducing a treatment fluid containing glutamic acid N,N-diacetic acid or a salt thereof (GLDA), methylglycine N,N-diacetic acid or a salt thereof (MGDA) and/or N-hydroxyethyl ethylenediamine N,N?,N?-triacetic acid or a salt thereof (HEDTA) into the formation, wherein the fracturing step can take place before introducing the treatment fluid into the formation, while introducing the treatment fluid into the formation or subsequent to introducing the treatment fluid into the formation.