Abstract: The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least onealkoxylating agent in the presence of a catalyst system, wherein a polyetheralcohol is obtained. The catalyst system comprises a metallo organic framework mate-rial comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion. Furthermore it relates to polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.

Abstract: The present invention relates to a novel class of shaped bodies containing metal-organic frameworks. Said metal-organic frameworks comprise at least one metal ion and at least one at least bidentate organic compound and contain at least one type of micro- and mesopores or micro- or mesopores. Said shaped bodies comprise at least one metal-organic framework material and may optionally contain further substances, in particular at least one supporting material.

Abstract: The present invention relates to a process for the reaction of at least one organic compound with one oxygen-delivering substance, for example a hydroperoxide, in the presence of at least one catalyst containing a metal-organic framework material comprising pores and a metal ion and an at least bidentate organic compound, said bidentate organic compound being coordinately bound to the metal ion. Further, the present invention is directed to the products being obtainable by the process according to the invention.

Abstract: The present invention relates to a method of using a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is bound, preferably coordinately bound to said metal ion for uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing or uptaking, storing and releasing at least one gas as well as a fuel cell comprising said material for the purposes outlined above.

Abstract: The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least one alkoxylating agent in the presence of a catalyst system, wherein a polyetheralcohol is obtained, characterized in that the catalyst system comprises a metallo organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion, and polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.

Abstract: The ability to design and construct solid-state materials with pre-determined structures is a grand challenge in chemistry. An inventive strategy based on reticulating metal ions and organic carboxylate links into extended networks has been advanced to a point that has allowed the design of porous structures in which pore size and functionality can be varied systematically. MOF-5, a prototype of a new class of porous materials and one that is constructed from octahedral Zn—O—C clusters and benzene links, was used to demonstrate that its 3-D porous system can be functionalized with the organic groups, —Br, —NH2, —OC3H7, —OC5H11, —H4C2, and —H4C4, and its pore size expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl.