Abstract: A surface-modified activated carbon is provided to reduce the amount of free fine carbon particles among the activated carbon. By surface-modifying the activated carbon with a layer, the activated carbon can have increased mechanical strength and the fine carbon particles among the activated carbon can be fastened to the layer. Therefore, the layer allows for the level of free fine carbon particles among the activated carbon to be reduced. Surface-modified activated carbon can be used in smoking articles so as to allow for adsorption by the activated carbon with reduced free fine carbon particles in the smoking article and the smoke produced.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of nanoparticle additives capable of reducing at least one constituent from mainstream and/or sidestream tobacco smoke, the at least one constituent being selected from the group consisting of aldehyde, carbon monoxide, 1,3-butadiene, isoprene, acrolein, acrylonitrile, hydrogen cyanide, o-toluidine, 2-naphtylamine, nitrogen oxide, benzene, N-nitrosonornicotine, phenol, catechol, benz(a)anthracene, benzo(a)pyrene, and mixtures thereof. Preferably, the nanoparticle additives are effective as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide and/or catalyst for conversion of aldehydes such as acetaldehyde and acrolein, hydrocarbons such as isoprene and/or phenolic compounds such as catechol to carbon dioxide and water vapor.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of nanoparticle additives capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide. Cut filler compositions are described which comprise tobacco and at least one nanoparticle additive. Cigarettes are provided, which comprise a tobacco rod, containing a cut filler having at least one nanoparticle additive. Methods for making a cigarette are provided, which involve (i) adding a nanoparticle additive to a cut filler; (ii) providing the cut filler comprising the additive to a cigarette making machine to form a tobacco rod; and (iii) placing a paper wrapper around the tobacco rod to form the cigarette.

Abstract: Mixed metal oxide catalysts are prepared by combining first nanoscale particles and second nanoscale particles to form a mixture of nanoscale particles and then the mixture is heated to form a mixed metal oxide catalyst. The mixed metal oxide catalysts, which are capable of reducing the concentration of carbon monoxide in the mainstream smoke of a cigarette during smoking, are incorporated into a smoking article component such as tobacco cut filler, cigarette paper and/or cigarette filter material.

Abstract: Smoking article components, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided that use transition metal oxide clusters capable of catalyzing and/or oxidizing the conversion of carbon monoxide to carbon dioxide and/or adsorbing carbon monoxide. Cut filler compositions, cigarette paper and cigarette filter material can comprise transition metal oxide clusters.

Abstract: Nanoscale particles are formed and deposited in situ on tobacco cut filler, cigarette paper and/or cigarette filter materials by physical vapor deposition. The nanoscale particles are capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide.

Abstract: Smoking article components, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided that use transition metal oxide clusters capable of catalyzing and/or oxidizing the conversion of carbon monoxide to carbon dioxide and/or adsorbing carbon monoxide. Cut filler compositions, cigarette paper and cigarette filter material can comprise transition metal oxide clusters.

Abstract: A smoking article composition and a method of making a smoking article composition and an additive, wherein the additive comprises particles anchored to the cut filler by a metal oxide support. The additive can be formed by combining particles and a metal oxide precursor solution with the smoking article composition. The smoking article composition can comprise tobacco cut filler, cigarette paper and/or cigarette filter material.

Abstract: Cigarettes and cigarette components such as tobacco cut filler and cigarette paper, and methods for making cigarette components are provided that comprise nanostructured fibrils. The nanostructured fibrils, which can be formed and deposited in situ on tobacco cut filler and/or cigarette paper by laser vaporization controlled condensation or chemical reaction, are capable of acting as an oxidant for the conversion of carbon monoxide carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide. Cigarettes are provided that comprise tobacco cut filler and cigarette paper, wherein nanostructured fibrils are deposited on, or incorporated in, at least one of the tobacco cut filler and cigarette paper.

Abstract: A wrapper for a smoking article includes a web including cellulosic fibers and a catalyst modified web-filler incorporated into the web. The catalyst modified web-filler includes a web-filler supporting a nanoparticle carbon monoxide catalyst. The nanoparticle carbon monoxide catalyst can be a nanoparticle iron oxide catalyst. Also provided is a smoking article including a cigarette tobacco rod having a wrapper including a web, a web-filler, and a nanoparticle carbon monoxide catalyst, the web-filler supporting the nanoparticle catalyst. A method of making the wrapper and a method of making a smoking article utilizing the wrapper are also provided.

Abstract: A filler composition of a tobacco rod for a smoking article includes a tobacco cut filler and a catalytic paper containing a nanoparticle carbon monoxide catalyst. The nanoparticle carbon monoxide catalyst is incorporated into a web-filler material utilized in production of the catalytic paper. The nanoparticle carbon monoxide catalyst includes a nanoparticle iron oxide catalytic particle. Also provided is a smoking article including the tobacco rod having a paper wrapper encasing a tobacco column containing a catalytic paper.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of a catalyst capable converting carbon monoxide to carbon dioxide and/or nitric oxide to nitrogen. Cut filler compositions comprise tobacco and at least one catalyst. Cigarettes are provided, which comprise a cut filler having at least one catalyst. The catalyst comprises nanoscale metal and/or metal oxide particles supported on a fibrous support. The catalyst can be prepared by combining a dispersion of nanoscale particles with a fibrous support, or by combining a metal precursor solution with a fibrous support and then heat treating the fibrous support.

Abstract: A cigarette paper includes heat-degradable filler particles to increase the porosity of the cigarette paper during smoking of the cigarette. The porosity of the cigarette paper during smoking of the cigarette will typically be from about 30% to abut 60%. The heat-degradable filler particles are capable of being dissipated at temperatures from about 25° C. to about 350° C. and/or at distances from about 0.1 mm to about 10 mm in advance of a charline formed in the cigarette paper during combustion of the cigarette. Methods of making the cigarette paper, a cigarette using the cigarette paper, and methods for making and smoking such a cigarette are also provided.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes which involve the use of manganese oxide mixtures that include nanoparticle manganese oxide and other nanoparticle additive(s) capable of converting carbon monoxide to carbon dioxide and/or converting nitric oxide to nitrogen. The compositions, articles and methods of the invention can be used to reduce the amount of carbon monoxide and/or nitric oxide present in mainstream smoke reaching the smoker and/or given off in secondhand smoke. The manganese oxide can be co-precipitated with the additive(s), or mechanically mixed with the additive(s) to form the manganese oxide mixture. The manganese oxide may have a lower light-off temperature than the additive, such that during smoking of the cigarette, the heat generated from the oxidation of carbon monoxide by manganese oxide is capable of activating the additive. The additive may include iron oxide (Fe2O3) nanoparticles.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of an oxyhydroxide compound that is capable of decomposing to form at least one product capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide. The oxyhydroxide compound and/or the product formed from the decomposition of the oxyhydroxide can be in the form of nanoparticles. Cut filler compositions are described which comprise tobacco and at least one such oxyhydroxide compound. Cigarettes are provided, which comprise a tobacco rod, containing a cut filler having at least one such oxyhydroxide compound.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of an oxyhydroxide compound that is capable of decomposing to form at least one product capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide. The oxyhydroxide compound and/or the product formed from the decomposition of the oxyhydroxide can be in the form of nanoparticles. Cut filler compositions are described which comprise tobacco and at least one such oxyhydroxide compound. Cigarettes are provided, which comprise a tobacco rod, containing a cut filler having at least one such oxyhydroxide compound.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes which involve the use of manganese oxide mixtures that include nanoparticle manganese oxide and other nanoparticle additive(s) capable of converting carbon monoxide to carbon dioxide and/or converting nitric oxide to nitrogen. The compositions, articles and methods of the invention can be used to reduce the amount of carbon monoxide and/or nitric oxide present in mainstream smoke reaching the smoker and/or given off in secondhand smoke. The manganese oxide can be co-precipitated with the additive(s), or mechanically mixed with the additive(s) to form the manganese oxide mixture. The manganese oxide may have a lower light-off temperature than the additive, such that during smoking of the cigarette, the heat generated from the oxidation of carbon monoxide by manganese oxide is capable of activating the additive. The additive may include iron oxide (Fe2O3) nanoparticles.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of nanoparticle additives capable of reducing amounts of at least one constituent from mainstream and/or sidestream tobacco smoke, the at least one constituent being selected from the group consisting of aldehyde, carbon monoxide, 1,3-butadiene, isoprene, acrolein, acrylonitrile, hydrogen cyanide, o-toluidine, 2-naphtylamine, nitrogen oxide, benzene, N-nitrosonornicotine, phenol, catechol, benz(a)anthracene, benzo(a)pyrene, and mixtures thereof. Preferably, the nanoparticle additives are effective as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide and/or catalyst for conversion of aldehydes such as acetaldehyde and acrolein, hydrocarbons such as isoprene and/or phenolic compounds such as catechol to carbon dioxide and water vapor.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of an oxyhydroxide compound that is capable of decomposing to form at least one product capable of acting as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide. The oxyhydroxide compound and/or the product formed from the decomposition of the oxyhydroxide can be in the form of nanoparticles. Cut filler compositions are described which comprise tobacco and at least one such oxyhydroxide compound. Cigarettes are provided, which comprise a tobacco rod, containing a cut filler having at least one such oxyhydroxide compound.

Abstract: Cut filler compositions, cigarettes, methods for making cigarettes and methods for smoking cigarettes are provided, which involve the use of nanoparticle additives capable of reducing at least one constituent from mainstream and/or sidestream tobacco smoke, the at least one constituent being selected from the group consisting of aldehyde, carbon monoxide, 1,3-butadiene, isoprene, acrolein, acrylonitrile, hydrogen cyanide, o-toluidine, 2-naphtylamine, nitrogen oxide, benzene, N-nitrosonornicotine, phenol, catechol, benz(a)anthracene, benzo(a)pyrene, and mixtures thereof. Preferably, the nanoparticle additives are effective as an oxidant for the conversion of carbon monoxide to carbon dioxide and/or as a catalyst for the conversion of carbon monoxide to carbon dioxide and/or catalyst for conversion of aldehydes such as acetaldehyde and acrolein, hydrocarbons such as isoprene and/or phenolic compounds such as catechol to carbon dioxide and water vapor.