Patents by Inventor Mohan Raj KRISHNAN

Mohan Raj KRISHNAN has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11912938
    Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.
    Type: Grant
    Filed: May 24, 2023
    Date of Patent: February 27, 2024
    Assignees: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Patent number: 11851614
    Abstract: A coated proppant having a proppant particle, an intermediate cross-linked terpolymer layer encapsulating the proppant particle, and an outer resin layer encapsulating the intermediate cross-linked terpolymer layer. The proppant particle is selected from sand, ceramic, glass, and combinations thereof. The intermediate cross-linked terpolymer layer includes styrene, methyl methacrylate, and divinyl benzene. The outer resin layer includes a cured epoxy resin formed from an epoxy resin and a curing agent.
    Type: Grant
    Filed: June 18, 2020
    Date of Patent: December 26, 2023
    Assignees: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Patent number: 11827852
    Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.
    Type: Grant
    Filed: October 13, 2022
    Date of Patent: November 28, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
  • Patent number: 11828116
    Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilisation in forming the barrier is provided.
    Type: Grant
    Filed: January 11, 2023
    Date of Patent: November 28, 2023
    Assignees: Alfaisal University, SAUDI ARABIAN OIL COMPANY
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
  • Patent number: 11802232
    Abstract: A polymer-nanofiller hydrogel including polymer hydrogel and nanofiller. The nanofiller is or includes nanosand. A method for forming the polymer-nanofiller hydrogel. A method of treating a wellbore in a subterranean formation, including applying a polymer-nanofiller hydrogel to the wellbore.
    Type: Grant
    Filed: March 10, 2021
    Date of Patent: October 31, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Feven Mattews Michael, Mohan Raj Krishnan
  • Publication number: 20230313028
    Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.
    Type: Application
    Filed: June 6, 2023
    Publication date: October 5, 2023
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
  • Publication number: 20230313027
    Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.
    Type: Application
    Filed: May 24, 2023
    Publication date: October 5, 2023
    Applicants: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Patent number: 11702587
    Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.
    Type: Grant
    Filed: August 6, 2021
    Date of Patent: July 18, 2023
    Assignees: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Publication number: 20230142223
    Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilisation in forming the barrier is provided.
    Type: Application
    Filed: January 11, 2023
    Publication date: May 11, 2023
    Applicants: Alfaisal University, SAUDI ARABIAN OIL COMPANY
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
  • Publication number: 20230060690
    Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.
    Type: Application
    Filed: October 13, 2022
    Publication date: March 2, 2023
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
  • Patent number: 11578543
    Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilization in forming the barrier is provided.
    Type: Grant
    Filed: October 9, 2020
    Date of Patent: February 14, 2023
    Assignees: SAUDI ARABIAN OIL COMPANY, ALFAISAL UNIVERSITY
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
  • Publication number: 20230040360
    Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.
    Type: Application
    Filed: August 6, 2021
    Publication date: February 9, 2023
    Applicants: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Patent number: 11499092
    Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.
    Type: Grant
    Filed: February 18, 2021
    Date of Patent: November 15, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
  • Patent number: 11459503
    Abstract: A method for producing a coated proppant having an intermediate cross-linked terpolymer layer includes mixing a monomers solution including a first monomer, a second monomer that is different from the first monomer, a cross-linking agent, and an initiator. The proppant particle is combined with the monomers solution, and the monomer solution on the surface of the at least one proppant particle is polymerized to form at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. A resin solution including an epoxy resin, a curing agent, and graphene is mixed, and combined with the at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. The resin solution is cured to form the coated proppant comprising an intermediate cross-linked terpolymer layer.
    Type: Grant
    Filed: June 18, 2020
    Date of Patent: October 4, 2022
    Assignees: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Publication number: 20220290033
    Abstract: A polymer-nanofiller hydrogel including polymer hydrogel and nanofiller. The nanofiller is or includes nanosand. A method for forming the polymer-nanofiller hydrogel. A method of treating a wellbore in a subterranean formation, including applying a polymer-nanofiller hydrogel to the wellbore.
    Type: Application
    Filed: March 10, 2021
    Publication date: September 15, 2022
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Feven Mattews Michael, Mohan Raj Krishnan
  • Publication number: 20220259488
    Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.
    Type: Application
    Filed: February 18, 2021
    Publication date: August 18, 2022
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
  • Publication number: 20220112777
    Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting; a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilization in forming the barrier is provided.
    Type: Application
    Filed: October 9, 2020
    Publication date: April 14, 2022
    Applicants: Alfaisal Univeristy, Saudi Arabian Oil Company
    Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
  • Publication number: 20210395603
    Abstract: A coated proppant having a proppant particle, an intermediate cross-linked terpolymer layer encapsulating the proppant particle, and an outer resin layer encapsulating the intermediate cross-linked terpolymer layer. The proppant particle is selected from sand, ceramic, glass, and combinations thereof. The intermediate cross-linked terpolymer layer includes styrene, methyl methacrylate, and divinyl benzene. The outer resin layer includes a cured epoxy resin formed from an epoxy resin and a curing agent.
    Type: Application
    Filed: June 18, 2020
    Publication date: December 23, 2021
    Applicants: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Publication number: 20210395604
    Abstract: A method for producing a coated proppant having an intermediate cross-linked terpolymer layer includes mixing a monomers solution including a first monomer, a second monomer that is different from the first monomer, a cross-linking agent, and an initiator. The proppant particle is combined with the monomers solution, and the monomer solution on the surface of the at least one proppant particle is polymerized to form at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. A resin solution including an epoxy resin, a curing agent, and graphene is mixed, and combined with the at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. The resin solution is cured to form the coated proppant comprising an intermediate cross-linked terpolymer layer.
    Type: Application
    Filed: June 18, 2020
    Publication date: December 23, 2021
    Applicants: Saudi Arabian Oil Company, Alfaisal University
    Inventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
  • Patent number: 11059205
    Abstract: A method for fabricating nanoporous polymer thin film includes steps as follows. A polymer thin film is provided, wherein a polymer solution including a polymer is coated on a substrate to form the polymer thin film. A swelling and annealing process is provided, wherein the polymer thin film is disposed inside a chamber with a vapor of a first solvent, the polymer thin film is swollen and annealed to form a swollen polymer thin film, and the swollen polymer thin film includes the polymer and the first solvent. A freezing process is provided, wherein the swollen polymer thin film is cooled to a temperature less than or equal to a crystallization temperature of the first solvent to crystallize the first solvent. A first solvent removing process is provided, wherein the first solvent is removed with a second solvent, such that a nanoporous polymer thin film is obtained.
    Type: Grant
    Filed: August 17, 2018
    Date of Patent: July 13, 2021
    Assignee: NATIONAL TSING HUA UNIVERSITY
    Inventors: Rong-Ming Ho, Mohan Raj Krishnan, Suhail Kizhakkeveettil Siddique, Yu-Cheng Chien