Patents by Inventor Mohan Raj KRISHNAN
Mohan Raj KRISHNAN has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11912938Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.Type: GrantFiled: May 24, 2023Date of Patent: February 27, 2024Assignees: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11851614Abstract: A coated proppant having a proppant particle, an intermediate cross-linked terpolymer layer encapsulating the proppant particle, and an outer resin layer encapsulating the intermediate cross-linked terpolymer layer. The proppant particle is selected from sand, ceramic, glass, and combinations thereof. The intermediate cross-linked terpolymer layer includes styrene, methyl methacrylate, and divinyl benzene. The outer resin layer includes a cured epoxy resin formed from an epoxy resin and a curing agent.Type: GrantFiled: June 18, 2020Date of Patent: December 26, 2023Assignees: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11827852Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.Type: GrantFiled: October 13, 2022Date of Patent: November 28, 2023Assignee: Saudi Arabian Oil CompanyInventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
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Patent number: 11828116Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilisation in forming the barrier is provided.Type: GrantFiled: January 11, 2023Date of Patent: November 28, 2023Assignees: Alfaisal University, SAUDI ARABIAN OIL COMPANYInventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11802232Abstract: A polymer-nanofiller hydrogel including polymer hydrogel and nanofiller. The nanofiller is or includes nanosand. A method for forming the polymer-nanofiller hydrogel. A method of treating a wellbore in a subterranean formation, including applying a polymer-nanofiller hydrogel to the wellbore.Type: GrantFiled: March 10, 2021Date of Patent: October 31, 2023Assignee: Saudi Arabian Oil CompanyInventors: Ayman Almohsin, Edreese Alsharaeh, Feven Mattews Michael, Mohan Raj Krishnan
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Publication number: 20230313028Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.Type: ApplicationFiled: June 6, 2023Publication date: October 5, 2023Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
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Publication number: 20230313027Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.Type: ApplicationFiled: May 24, 2023Publication date: October 5, 2023Applicants: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11702587Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.Type: GrantFiled: August 6, 2021Date of Patent: July 18, 2023Assignees: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Publication number: 20230142223Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilisation in forming the barrier is provided.Type: ApplicationFiled: January 11, 2023Publication date: May 11, 2023Applicants: Alfaisal University, SAUDI ARABIAN OIL COMPANYInventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
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Publication number: 20230060690Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.Type: ApplicationFiled: October 13, 2022Publication date: March 2, 2023Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
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Patent number: 11578543Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilization in forming the barrier is provided.Type: GrantFiled: October 9, 2020Date of Patent: February 14, 2023Assignees: SAUDI ARABIAN OIL COMPANY, ALFAISAL UNIVERSITYInventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
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Publication number: 20230040360Abstract: Coated proppants include a proppant particle, a surface copolymer layer surrounding the proppant particle, and a resin layer surrounding the surface copolymer layer. The surface copolymer layer includes a copolymer of at least two monomers chosen from styrene, methyl methacrylate, ethylene, propylene, butylene, imides, urethanes, sulfones, carbonates, and acrylamides, where the copolymer is crosslinked by divinyl benzene. The resin layer includes a cured resin.Type: ApplicationFiled: August 6, 2021Publication date: February 9, 2023Applicants: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11499092Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.Type: GrantFiled: February 18, 2021Date of Patent: November 15, 2022Assignee: Saudi Arabian Oil CompanyInventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
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Patent number: 11459503Abstract: A method for producing a coated proppant having an intermediate cross-linked terpolymer layer includes mixing a monomers solution including a first monomer, a second monomer that is different from the first monomer, a cross-linking agent, and an initiator. The proppant particle is combined with the monomers solution, and the monomer solution on the surface of the at least one proppant particle is polymerized to form at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. A resin solution including an epoxy resin, a curing agent, and graphene is mixed, and combined with the at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. The resin solution is cured to form the coated proppant comprising an intermediate cross-linked terpolymer layer.Type: GrantFiled: June 18, 2020Date of Patent: October 4, 2022Assignees: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Publication number: 20220290033Abstract: A polymer-nanofiller hydrogel including polymer hydrogel and nanofiller. The nanofiller is or includes nanosand. A method for forming the polymer-nanofiller hydrogel. A method of treating a wellbore in a subterranean formation, including applying a polymer-nanofiller hydrogel to the wellbore.Type: ApplicationFiled: March 10, 2021Publication date: September 15, 2022Inventors: Ayman Almohsin, Edreese Alsharaeh, Feven Mattews Michael, Mohan Raj Krishnan
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Publication number: 20220259488Abstract: Polyacrylamide (PAM)-coated nanosand that may be a relative permeability modifier (RPM) and that is applied to treat a wellbore in a subterranean formation. The treatment may be for excess water production. The PAM-coated nanosand is PAM-hydrogel-coated nanosand. The PAM-coated nanosand os nanosand coated with PAM hydrogel. The PAM hydrogel includes crosslinked PAM in water. Application of the PAM-coated nanosand may reduce water production from the subterranean formation into the wellbore. The PAM hydrogel of the PAM-coated nanosand may expand in a water zone of the subterranean formation to restrict water flow into the wellbore. The PAM hydrogel of the PAM-coated nanosand may contract in an oil zone of the subterranean formation so not to significantly restrict crude oil flow into the wellbore.Type: ApplicationFiled: February 18, 2021Publication date: August 18, 2022Inventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan, Mohieddin Alghazali
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Publication number: 20220112777Abstract: A method of forming a barrier to overcome lost circulation in a subterranean formation. The method includes injecting; a polymer-sand nanocomposite into one or more lost circulation zones in the subterranean formation where the polymer-sand nanocomposite is formed from sand mixed with a polymer hydrogel. Further, the polymer hydrogel includes a hydrogel polymer, an organic cross-linker, and a salt. The sand additionally comprises a surface modification. The associated method of preparing a polymer-sand nanocomposite lost circulation material for utilization in forming the barrier is provided.Type: ApplicationFiled: October 9, 2020Publication date: April 14, 2022Applicants: Alfaisal Univeristy, Saudi Arabian Oil CompanyInventors: Ayman Almohsin, Edreese Alsharaeh, Mohan Raj Krishnan
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Publication number: 20210395603Abstract: A coated proppant having a proppant particle, an intermediate cross-linked terpolymer layer encapsulating the proppant particle, and an outer resin layer encapsulating the intermediate cross-linked terpolymer layer. The proppant particle is selected from sand, ceramic, glass, and combinations thereof. The intermediate cross-linked terpolymer layer includes styrene, methyl methacrylate, and divinyl benzene. The outer resin layer includes a cured epoxy resin formed from an epoxy resin and a curing agent.Type: ApplicationFiled: June 18, 2020Publication date: December 23, 2021Applicants: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Publication number: 20210395604Abstract: A method for producing a coated proppant having an intermediate cross-linked terpolymer layer includes mixing a monomers solution including a first monomer, a second monomer that is different from the first monomer, a cross-linking agent, and an initiator. The proppant particle is combined with the monomers solution, and the monomer solution on the surface of the at least one proppant particle is polymerized to form at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. A resin solution including an epoxy resin, a curing agent, and graphene is mixed, and combined with the at least one proppant particle having the intermediate cross-linked terpolymer layer on a surface of the at least one proppant particle. The resin solution is cured to form the coated proppant comprising an intermediate cross-linked terpolymer layer.Type: ApplicationFiled: June 18, 2020Publication date: December 23, 2021Applicants: Saudi Arabian Oil Company, Alfaisal UniversityInventors: Wengang Li, Edreese Alsharaeh, Mohan Raj Krishnan
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Patent number: 11059205Abstract: A method for fabricating nanoporous polymer thin film includes steps as follows. A polymer thin film is provided, wherein a polymer solution including a polymer is coated on a substrate to form the polymer thin film. A swelling and annealing process is provided, wherein the polymer thin film is disposed inside a chamber with a vapor of a first solvent, the polymer thin film is swollen and annealed to form a swollen polymer thin film, and the swollen polymer thin film includes the polymer and the first solvent. A freezing process is provided, wherein the swollen polymer thin film is cooled to a temperature less than or equal to a crystallization temperature of the first solvent to crystallize the first solvent. A first solvent removing process is provided, wherein the first solvent is removed with a second solvent, such that a nanoporous polymer thin film is obtained.Type: GrantFiled: August 17, 2018Date of Patent: July 13, 2021Assignee: NATIONAL TSING HUA UNIVERSITYInventors: Rong-Ming Ho, Mohan Raj Krishnan, Suhail Kizhakkeveettil Siddique, Yu-Cheng Chien