Abstract: A group of reductive 2D materials (R2D) with extended reactive vacancies and a method for making the R2D with extended reactive vacancies are provided, especially the example of the reductive boron nitride (RBN). To create defects such as vacancies, boron nitride (BN) powders are milled at cryogenic temperatures. Vacancies are produced by milling, and the vacancies can be used to reduce various metal nanostructures on RBN. Due to the thermal stability of the RBN and the enhanced catalytic performance of metal nanostructures, RBN-metals can be used for different catalysts, including electrochemical catalysts and high temperature catalysts.

Abstract: The invention provides a semipermeable composite membrane that reduces an environmental load, and a method of producing the semipermeable composite membrane. A semipermeable composite membrane 100 includes, on a porous support 102, a semipermeable membrane 104 containing a crosslinked polyamide 120 and a cellulose nanofiber 110. A method of producing the semipermeable composite membrane includes obtaining a mixed solution containing the cellulose nanofiber 110, water, and an amine component, and obtaining the semipermeable composite membrane 100 by making the mixed solution be in contact with the porous support 102, thereafter, causing a cross-linking reaction of the amine component in the mixed solution, with the amine component adhering to the porous support 102.

Abstract: A reverse osmosis membrane of the present invention includes a porous support substrate (2) and a separation active layer (3) formed on a surface of the porous support substrate (2) and formed of a carbon film containing organized carbon.

Abstract: A semipermeable composite membrane that reduces an environmental load, and a method of producing the semipermeable composite membrane. A semipermeable composite membrane includes, on a porous support, a semipermeable membrane containing a crosslinked polyamide and a cellulose nanofiber. A method of producing the semipermeable composite membrane includes obtaining a mixed solution containing the cellulose nanofiber, water, and an amine component, and obtaining the semipermeable composite membrane by making the mixed solution be in contact with the porous support, thereafter, causing a cross-linking reaction of the amine component in the mixed solution, with the amine component adhering to the porous support.

Abstract: A reverse osmosis membrane of the present invention includes a porous support substrate (2) and a separation active layer (3) formed on a surface of the porous support substrate (2) and formed of a carbon film containing organized carbon.

Abstract: A method of manufacturing a reverse osmosis composite membrane, including: (i) bringing a mixed liquid containing carbon nanotubes, water, and an amine component into contact with a porous support, the mixed liquid being produced through a step of pressurizing and compressing an aqueous solution containing the carbon nanotubes while flowing the aqueous solution, followed by releasing or reducing a pressure to return a volume of the aqueous solution to an original volume to mix the carbon nanotubes; and then (ii) subjecting the amine component in the mixed liquid adhering to the porous support to a crosslinking reaction.

Abstract: Provided is a water treatment flow channel member in which the occurrence of fouling is suppressed. A water treatment flow channel member 1 of the present invention is formed from a molded product containing a synthetic resin and a nanocarbon material.

Abstract: A method of forming a reverse osmosis membrane 1 of the present invention includes a coating membrane forming step of forming a coating membrane which is soluble in a predetermined solvent on a surface of a porous support substrate 2 that is insoluble in the solvent, a carbon membrane forming step of forming a carbon membrane 3 on the coating membrane by a physical vapor deposition which deposits carbon as a target material under an atmosphere where rare gas and nitrogen gas are contained, and a removing-by-dissolving step of removing the coating membrane by dissolving the same in the solvent after formation of the carbon membrane 3.

Abstract: A method of manufacturing a reverse osmosis composite membrane, including: (i) bringing a mixed liquid containing carbon nanotubes, water, and an amine component into contact with a porous support, the mixed liquid being produced through a step of pressurizing and compressing an aqueous solution containing the carbon nanotubes while flowing the aqueous solution, followed by releasing or reducing a pressure to return a volume of the aqueous solution to an original volume to mix the carbon nanotubes; and then (ii) subjecting the amine component in the mixed liquid adhering to the porous support to a crosslinking reaction.

Abstract: A low-resistivity carbon nanotube aggregate includes a plurality of carbon nanotubes each having one or more walls, wherein a ratio of a total number of carbon nanotubes that have two or three walls relative to a total number of said plurality of carbon nanotubes is 75% or greater, and wherein, in a G band of a Raman spectrum in the Raman spectroscopy of the plurality of carbon nanotubes, a G+/Gtotal ratio that is indicative of an amount of semiconductor carbon nanotubes relative to metallic carbon nanotubes is 0.70 or greater.

Abstract: A reverse osmosis composite membrane includes: a porous support; and a reverse osmosis membrane arranged on the porous support and containing a crosslinked polyamide and carbon nanotubes. The reverse osmosis membrane contains the carbon nanotubes that are disentangled in the crosslinked polyamide. A distribution of closest distances between the carbon nanotubes in the reverse osmosis membrane has a peak that is within a range of a thickness of the reverse osmosis membrane, and a half width of the peak is equal to or less than the thickness of the reverse osmosis membrane.

Abstract: A method of forming a reverse osmosis membrane 1 of the present invention includes a coating membrane forming step of forming a coating membrane which is soluble in a predetermined solvent on a surface of a porous support substrate 2 that is insoluble in the solvent, a carbon membrane forming step of forming a carbon membrane 3 on the coating membrane by a physical vapor deposition which deposits carbon as a target material under an atmosphere where rare gas and nitrogen gas are contained, and a removing-by-dissolving step of removing the coating membrane by dissolving the same in the solvent after formation of the carbon membrane 3.

Abstract: A low-resistivity carbon nanotube aggregate includes a plurality of carbon nanotubes each having one or more walls, wherein a ratio of a total number of carbon nanotubes that have two or three walls relative to a total number of said plurality of carbon nanotubes is 75% or greater, and wherein, in a G band of a Raman spectrum in the Raman spectroscopy of the plurality of carbon nanotubes, a G+/Gtotal ratio that is indicative of an amount of semiconductor carbon nanotubes relative to metallic carbon nanotubes is 0.70 or greater.

Abstract: A reverse osmosis composite membrane includes: a porous support; and a reverse osmosis membrane arranged on the porous support and containing a crosslinked polyamide and carbon nanotubes. The reverse osmosis membrane contains the carbon nanotubes that are disentangled in the crosslinked polyamide. A distribution of closest distances between the carbon nanotubes in the reverse osmosis membrane has a peak that is within a range of a thickness of the reverse osmosis membrane, and a half width of the peak is equal to or less than the thickness of the reverse osmosis membrane.

Abstract: We report a method of preparation of highly elastic graphene oxide films, and their transformation into graphene oxide fibers and electrically conductive graphene fibers by spinning. Methods typically include: 1) oxidation of graphite to graphene oxide, 2) preparation of graphene oxide slurry with high solid contents and residues of sulfuric acid impurities. 3) preparation of large area films by bar-coating or dropcasting the graphene oxide dispersion and drying at low temperature. 4) spinning the graphene oxide film into a fiber, and 5) thermal or chemical reduction of the graphene oxide fiber into an electrically conductive graphene fiber. The resulting films and fiber have excellent mechanical properties, improved morphology as compared with current graphene oxide fibers, high electrical conductivity upon thermal reduction, and improved field emission properties.

Abstract: We report a method of preparation of highly elastic graphene oxide films, and their transformation into graphene oxide fibers and electrically conductive graphene fibers by spinning. Methods typically include: 1) oxidation of graphite to graphene oxide, 2) preparation of graphene oxide slurry with high solid contents and residues of sulfuric acid impurities. 3) preparation of large area films by bar-coating or dropcasting the graphene oxide dispersion and drying at low temperature. 4) spinning the graphene oxide film into a fiber, and 5) thermal or chemical reduction of the graphene oxide fiber into an electrically conductive graphene fiber. The resulting films and fiber have excellent mechanical properties, improved morphology as compared with current graphene oxide fibers, high electrical conductivity upon thermal reduction, and improved field emission properties.

Abstract: A method of producing a carbon fiber composite resin material including (a) a first mixing step, (b) a second mixing step, and (c) a step of curing a second mixture. In the first mixing step (a), an epoxy resin is mixed with an epoxidized elastomer to obtain a first mixture. In the second mixing step (b), vapor-grown carbon fibers having an average diameter of 20 to 200 nm and an average length of 5 to 20 micrometers are mixed with the first mixture to obtain a second mixture in which the vapor-grown carbon fibers are dispersed. In the step (c) of curing the second mixture, the second mixture is cured to obtain a highly rigid carbon fiber composite resin material.

Abstract: A method of producing a carbon material which is mainly composed of graphene-containing carbon particles is provided. The method includes a step of producing carbon particles from an organic material by maintaining a mixture containing the organic substance as a starting material, hydrogen peroxide and water under conditions of a temperature of 300° C. to 1000° C. and a pressure of 22 MPa or more. The method further includes a step of heat-treating the carbon particles at a higher temperature than the temperature maintained in the carbon particle producing step. The carbon material produced by the present method has a structure in which substances such as ions can easily enter and leave the graphene structures of the carbon particles, making the carbon material be useful as active materials of secondary batteries and electric double layer capacitors.

Abstract: A seal member includes a hydrogenated acrylonitrile-butadiene rubber (HNBR) and carbon nanofibers. The seal member has a number of cycles to fracture of 7000 or more when subjected to a tensile fatigue test at a temperature of 70° C., a maximum tensile stress of 4 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent abrasion resistance.

Abstract: The seal member includes a tetrafluoroethylene-propylene copolymer (FEPM) and carbon nanofibers. The seal member has a number of cycles to fracture of 10 or more when subjected to a tension fatigue test at a temperature of 150° C., a maximum tensile stress of 2 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent heat resistance and abrasion resistance.