Patents by Inventor Morio Yagihara

Morio Yagihara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5532120
    Abstract: A silver halide photographic material comprises a silver halide emulsion layer provided on a support. The silver halide emulsion layer contains a selenium compound represented by the formula (I), (IIa) or (IIb): ##STR1## in which each of R.sup.11 and R.sup.12 is hydrogen, an aliphatic group, an aromatic group, a heterocyclic group, --OR.sup.13 or --NR.sup.14 R.sup.15 ; each of R.sup.21 and R.sup.31 is an aliphatic group, an aromatic group, a heterocyclic group, --OR.sup.23 or --NR.sup.24 R.sup.25 ; each of R.sup.22 and R.sup.32 is an aliphatic group, an aromatic group or a heterocyclic group; each of R.sup.13, R.sup.14, R.sup.15, R.sup.23, R.sup.24 and R.sup.25 is hydrogen, an aliphatic group, an aromatic group or a heterocyclic group; and Ch is S, Se or Te.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: July 2, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hirotomo Sasaki, Hiroyuki Mifune, Shinji Kato
  • Patent number: 5527664
    Abstract: A silver halide photographic emulsion, a method of preparing the same, and a light-sensitive material containing this emulsion, wherein silver halide grains are formed while rapidly producing iodide ions from an iodide ion-releasing agent represented by Formula (I) below:R--I Formula (I)wherein R represents a monovalent organic residue which releases the iodine atom in the form of iodide ion upon reacting with a base and/or a nucleophilic reagent.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: June 18, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Makoto Kikuchi, Morio Yagihara, Hisashi Okamura, Hiroshi Kawamoto
  • Patent number: 5525460
    Abstract: A silver halide photographic emulsion comprising silver halide grains which are formed while iodide ions are rapidly being generated from an iodide ion-releasing agent represented by Formula (I) below, and which are chemically sensitized with a selenium sensitizer. Formula (I)R--Iwhere R represents a monovalent organic residue which releases the iodine atom in the form of iodide ions upon reacting with a base and/or a nucleophilic reagent.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: June 11, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Maruyama, Morio Yagihara, Hisashi Okamura, Hiroshi Kawamoto, Makoto Kikuchi
  • Patent number: 5447821
    Abstract: A reducer containing a ferric chelate compound of an amino compound and further containing an reduction accelerator and/or a complex-forming agent and a dye. ##STR1## wherein A.sub.41, A.sub.42 and A.sub.43 each individually represents a carboxyl group, a phosphono group, a sulfo group or a hydroxyl group; L.sub.41 and L.sub.42 each individually represents a divalent coupling group containing an aliphatic group, an aromatic group, a heterocyclic group or combinations thereof; R.sub.41 represents a substituent; and a represents 0, 1, 2, 3 or 4. The reducer is superior in the rate of reduction, reducibility and reduction working properties and so stable that no precipitate will separate out with time. Also disclosed is a silver image reducing method wherein a silver image formed by exposing and developing a silver halide photosensitive material is reduced in the presence of the above-described reducer. The reducer and the reducing method are suitable for application to high-contrast photosensitive materials.
    Type: Grant
    Filed: January 4, 1995
    Date of Patent: September 5, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Morio Yagihara, Katsumi Hayashi
  • Patent number: 5418124
    Abstract: A silver halide photographic emulsion, in which silver halide grains have been formed while iodide ions are rapidly being generated in a reactor vessel to form a silver iodide-containing region in the silver halide grains, and the silver halide grains have been spectrally sensitized by a sensitizing dye represented by the following formula (I): ##STR1## wherein Z.sub.1 and Z.sub.2.sup.- represent non-metallic atom group which form a 5- or 6-membered heterocyclic ring having nitrogen atom and carbon atom in the ring, R.sub.3 and R.sub.4 represent alkyl groups, X.sub.1.sup.- represents an anion, and p represents 1 or 2.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: May 23, 1995
    Assignee: Fuji Photo Film Co. Ltd.
    Inventors: Yoichi Suga, Makoto Kikuchi, Morio Yagihara, Hisashi Okamura, Hiroshi Kawamoto
  • Patent number: 5395732
    Abstract: A silver halide photographic material is disclosed, which comprises (a) at least one light-sensitive silver halide emulsion layer containing a hydrazine derivative and (b) a hydrophilic colloid layer which is different from the light-sensitive silver halide emulsion layer and which contains a redox compound capable of releasing a development inhibitor as a result of oxidation.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: March 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Morio Yagihara, Takahiro Goto
  • Patent number: 5389508
    Abstract: A silver halide photographic light-sensitive material comprising at least one light-sensitive silver halide emulsion layer formed on a support. The emulsion layer containing at least one silver halide emulsion which comprises regular-crystal grains having a silver halide phase containing silver iodide. The silver halide phase has been formed while iodide ions are rapidly being generated.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: February 14, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunji Takada, Morio Yagihara, Hisashi Okamura, Hiroshi Kawamoto, Makoto Kikuchi
  • Patent number: 5374499
    Abstract: A silver halide photographic material comprising a support having thereon at least one of a surface latent image type silver halide emulsion layer and other hydrophilic colloid layers is disclosed, in which said at least one of the emulsion layer and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein X represents ##STR2## R.sub.1 represents a hydrogen atom or a group capable of being converted to a hydrogen atom on hydrolysis; R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent group; R.sub.5 and R.sub.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: December 20, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Senzo Sasaoka, Morio Yagihara
  • Patent number: 5352567
    Abstract: A novel method for processing a silver halide color photographic material which comprises color developing an imagewise exposed silver halide color photographic material and then processing the material with a having a bleaching ability containing at least one bleaching agent a ferric complex of a compound represented by at least one of formula (I) and formula (II): ##STR1## wherein W.sup.1 represents an alkylene group containing 3 or less carbon atoms in total; L.sup.1, L.sup.2, L.sup.3 and L.sup.4 each represents an alkylene or arylene group; and M.sub.1 to M.sub.6 each represents a hydrogen atom or a cation; ##STR2## wherein W.sup.2 represents an alkylene group having 2 to 8 carbon atoms, an arylene group having 6 to 10 carbon atoms, cyclohexane group, ##STR3## (in which W.sup.21 and W.sup.22 each represents an alkylene group, and m represents an integer of 1 to 3, and A represents a hydrogen atom, hydrocarbon group, --L.sub.A --COOM, --L.sub.A --PO.sub.3 M.sub.2, --L.sub.A --OH or --L.sub.A --SO.sub.
    Type: Grant
    Filed: September 22, 1992
    Date of Patent: October 4, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Tadashi Inaba, Morio Yagihara
  • Patent number: 5348845
    Abstract: Disclosed is a color image-stabilization processing solution for a silver halide color photographic material containing at least one of (a) an N-methylol compound represented by the following formula (I): ##STR1## wherein X represents a group of non-metallic atoms necessary to form a 1H-pyrazole ring or 1H-1,2,4-triazole ring together with the nitrogen atom;and (b) an N-methylol compound satisfying the condition that an equilibrium constant in water at room temperature is 2.times.10.sup.-2 mol/liter or less and a formaldehyde-releasing rate constant is 1.times.10.sup.-5 sec.sup.-1 or more. This solution permits one to dispense formaldehyde and its attendant risks. Also disclosed is a method for processing silver halide color photographic materials using such a solution.
    Type: Grant
    Filed: March 18, 1993
    Date of Patent: September 20, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Morigaki, Hiroshi Kawamoto, Yoshihiro Fujita, Shigeru Nakamura, Hiroyuki Watanabe, Morio Yagihara
  • Patent number: 5334493
    Abstract: A photographic processing solution for processing a silver halide color photographic light-sensitive material and a processing method using the same is disclosed. The photographic processing solution comprises formaldehyde and an amine compound having at least one --NH-- group in the --NH-- equivalent amount per liter of the photographic processing solution being greater than the molar concentration of formaldehyde in the photographic processing solution. The photographic processing solution is stable and has a reduced formaldehyde vapor pressure. The processing method provides excellent image stability.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: August 2, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Fujita, Masakazu Morigaki, Hiroshi Kawamoto, Shigeru Nakamura, Morio Yagihara, Hiroyuki Watanabe
  • Patent number: 5322767
    Abstract: A silver halide color photographic material having at least three light-sensitive silver halide emulsion layers, each sensitive in a different wavelength region. At least one of the silver halide emulsion layers contains at least one adsorbable reducing compound represented by a hydroquinone containing a group capable of promoting adsorption to silver halide grains and a silver halide emulsion having a silver chloride content of at least 90 mol %. The photographic material is well adapted for rapid processing and maintains constant sensitivity with a change in humidity upon exposure and when stored for a long period of time prior to use.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: June 21, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Ohshima, Morio Yagihara
  • Patent number: 5306613
    Abstract: A silver halide photographic material comprises a silver halide emulsion layer and a non-light-sensitive hydrophilic colloidal layer provided on a support. The silver halide emulsion layer or the hydrophilic colloidal layer contains a selenium compound represented by the formula (I), (II) or (III): ##STR1## in which R.sup.11 is an aliphatic, aromatic or heterocyclic group, --OR.sup.13 or --NR.sup.14 R.sup.15 ; each of R.sup.13, R.sup.14 and R.sup.15 is hydrogen or an aliphatic or aromatic group; Ch is S, Se or Te; R.sup.12 is an aliphatic, aromatic or heterocyclic group or --COR.sup.16 ; each of R.sup.16, R.sup.21 and R.sup.31 has the same meaning as that of R.sup.11 ; M.sup.1 is Ge, Sn or Pb; M.sup.2 is Ni, Pd or Pt; each of R.sup.22 and R.sup.32 is an aliphatic or aromatic group; and each of n and m is 1 or 2.
    Type: Grant
    Filed: August 24, 1993
    Date of Patent: April 26, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hiroyuki Mifune, Hirotomo Sasaki, Shinji Kato
  • Patent number: 5290661
    Abstract: A method for sorting images by silver salt diffusion transfer comprisingimagewise exposing a light-sensitive element comprising a light-sensitive silver halide emulsion layer,developing the light-sensitive element in the presence of a silver halide solvent using an alkaline processing composition to turn at least a part of unexposed silver halide of the light-sensitive silver halide emulsion layer into a transfer silver halide complex salt, andtransferring at least a part of the silver halide complex salt to an image receiving layer comprising a silver precipitating agent to form images on the image receiving layer,wherein at least one compound represented by formula (I) is added to at least one of the light-sensitive element, an image receiving element comprising the image receiving layer, and the processing composition in an amount of at least 1.times.10.sup.-6 and less than 1.times.10.sup.-2 mol based on one mol of silver applied per unit area (m.sup.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: March 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Idota, Makoto Ishihara, Morio Yagihara
  • Patent number: 5278032
    Abstract: A process for the continuous treatment of silver halide color photographic light-sensitive materials comprising the developing of the material while supplying a replenisher to a developing bath, where the amount of the replenisher is 900 m or less per m.sup.2 of the light-sensitive materials, and an average ratio of silver iodide to the whole silver halide included in the light-sensitive material is 8 mol % or less.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: January 11, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunichi Aida, Morio Yagihara, Shinzo Kishimoto, Hiroshi Fujimoto
  • Patent number: 5276179
    Abstract: The sulfonamide derivative according to the present invention is expressed by a general formula: ##STR1## (where R.sub.11 represents an alkyl group having 5 or less carbon atoms; Each of L.sub.11, L.sub.12 and L.sub.13 represents an alkylene group; Each of M.sub.11 and M.sub.12 represents a hydrogen atom or a cation.)This compound is suitable for the applications such as photographic processing solution, for chelate titration or analytical reagent for medical treatment or for medical drugs as a metallic ion shielding agent.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: January 4, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Morio Yagihara
  • Patent number: 5273859
    Abstract: A method for forming an image is disclosed. The method comprises the step of developing an imagewise exposed silver halide photographic material which contains a redox compound, with a developer which contains a silver halide developing agent and at least 0.1 mol/l of a sulfite and has a pH of 9 to 12, wherein the redox compound contains a redox group which is a hydrazine derivative which is capable of releasing a development inhibitor as a result of oxidation with the oxidized developer, and wherein after said oxidation, at least a portion of the development inhibitor is released into a developer where it reacts with a developer component and changes into a compound having little inhibiting effect. A silver halide photographic material used in that method is also disclosed.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: December 28, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Hisashi Okamura, Morio Yagihara
  • Patent number: 5250402
    Abstract: A photographic processing composition for processing a silver halide photographic light-sensitive material. The composition contains at least one metal chelating compound formed from a metal salt of Fe(III) and a monoamine compound or salt thereof represented by formula (I-a') or (I-b'): ##STR1## wherein R represents a substituent; Q represents a group of non-metal atoms necessary to form a heterocyclic ring; X and Y each represents a carbon atom or a nitrogen atom; L.sub.1 ' and L.sub.2 ' each represents an alkylene group; M.sub.1, M.sub.2, M.sub.3 each represents a hydrogen atom or a cation; and u represents 0, 1, 2, 3, or 4.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: October 5, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Tadashi Inaba, Morio Yagihara
  • Patent number: 5250401
    Abstract: Disclosed is a method for processing a silver halide color photographic material, which comprises the steps of:image-wise exposing a silver halide color photographic material,color developing the image-wise exposed silver halide photographic material, andprocessing the color developed silver halide photographic material, in the presence of a processing composition containing a metal chelating compound formed by a compound represented by following formula (I) and a salt of a metal belonging to group Ib, IIb, IIIb,IVb, Vb, VIb, VIIb, or VIII of the Periodic Table: ##STR1## wherein Z represents a heterocyclic group; L represents a divalent linkage group; R.sub.11 and R.sub.12 each represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; and n represents 0 or 1. Also disclosed is the processing composition used in the above method.
    Type: Grant
    Filed: July 30, 1991
    Date of Patent: October 5, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Morio Yagihara, Tadashi Inaba, Hiroyuki Seki
  • Patent number: 5240823
    Abstract: A developer composition comprising a dihydroxybenzene developing agent, a sulfite ion, and an antisludging agent is diluted with water to prepare a developer for the development of photographic silver halide photosensitive material. The components of the composition are divided into a plurality of parts such that the antisludging agent and the dihydroxybenzene developing agent are added to separate parts which are kept apart during storage until they were combined to form the developer.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: August 31, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Takashi Toyoda, Morio Yagihara, Hiroshi Kawamoto