Abstract: Geothermal brine is passed through a zone containing a packing metal so as to reduce its tendency to deposit iron/silica scale, reduce corrosivity of the brine, and/or remove and recover metals from the brine. The method polishes the geothermal brine by contacting the brine with a packing metal higher in the electromotive series than silver for a time sufficient for a precious metals to precipitate onto the packing at brine temperature and pH conditions which inhibit iron-rich silica scale. Most preferably, the contacting is accomplished near an injection well at the end of a heat extraction process and the packing comprises coiled zinc-galvanized steel chicken wire mesh packed in a sufficient density to also act as a filter for suspended particles. Alternatively, contacting is also accomplished near the production well. Dissolving the packing in a suitable acid leaves a precious metal-rich residue behind for subsequent recovery.

Abstract: Geothermal brine is passed through a zone containing a packing metal so as to reduce its tendency to deposit iron/silica scale, reduce corrosivity of the brine, and/or remove and recover metals from the brine. The method polished the geothermal brine by contacting the brine with a packing metal higher in the electromotive series than silver for a time sufficient for a precious metals to precipitate onto the packing at brine temperature and pH conditions which inhibit iron-rich silica scale. Most preferably, the contacting is accomplished near an injection well at the end of a heat extraction process and the packing comprises coiled zinc-galvanized steel chicken wire mesh packed in a sufficient density to also act as a filter for suspended particles. Alternatively, contacting is also accomplished near the production well. Dissolving the packing in a suitable acid leaves a precious metal-rich residue behind for subsequent recovery.

Abstract: A method is provided for selectively treating flocculated heavy metal contaminated iron-based sludges from an industrial waste water treatment process. The method removes the heavy metal contaminants with a minimum loss of the iron therein. The method comprises dissolving the sludge in hydrochloric acid to produce a ferric chloride solution. The solution is filtered to remove precipitated heavy metal salts, such as lead chloride. The filtrate containing the remaining heavy metal chlorides and ferric chloride is then cooled or otherwise treated to remove additional heavy metal chlorides. The remaining ferric chloride based solution is then reduced (exposed to iron powder) to a ferrous chloride solution and heavy metals. After filtration of any additional precipitated heavy metals, the ferrous chloride solution is ready for recycling.

Abstract: Chlorine is removed from a gas stream by contacting the stream with a pulverized, oxidized bastnasite ore in the presence of water. The invention is particularly applicable to the processing of bastnasite ore for the recovery of rare earth compounds wherein there is produced a waste gas stream containing chlorine.

Abstract: A method for removing and recovering toxic heavy metal contaminants from an iron-bearing sludge is provided. The method comprises one or more cycles of a two step, controlled chloride leach comprising a first non-acidic chloride leaching solution and a second acidic chloride leaching solution, wherein said toxic heavy metals are separated from said sludge and said iron-bearing sludge is a substantially non-hazardous material.

Abstract: A method is provided for producing electric power from hot, pressurized geothermal brine containing dissolved toxic elements without significant precipitation of toxic solids. When sludge produced by the process is washed, non-toxic solids are produced which can be disposed of or utilized in an environmentally acceptable manner. The method includes removing geothermal brine from an underground aquifer, separating non-condensable gases therefrom, and handling the non-condensable gases separately from the processing of the non-condensable gas-free brine to prevent reactions therebetween. An air-free flashed brine handling system is established to prevent contact of air with the flashed brine, and all brine contacted with air is injected into the geothermal brine aquifer through a separate, corrosion-protected injection well. Steam derived from the brine is used to produce electric power, the steam being condensed in the process. The steam condensate is air-cooled, and is used in the steam condensation process.

Abstract: A method is provided for producing power from geothermal brine comprising dissolved toxic elements without significant precipitation of toxic solids. When sludge produced by the process is washed, non-toxic solids are produced which can be disposed or utilized in an environmentally acceptable manner. The method includes removing geothermal brine, separating non-condensable gases therefrom, and handling the non-condensable gases separate from the processing of the non-condensable gas-free brine to prevent reaction therebetween. An air-free flashed brine handling system is established to prevent contact of air with the flashed brine, and all brine contacted with air including condensate from steam turbines producing electrical power is injected into the aquifer from which the geothermal brine was extracted through the use of separate injection wells.

Abstract: A process is provided for reducing the total concentration of heavy metals, notably lead, copper and zinc, naturally occurring in silica-rich sludge precipitated from geothermal brine in a brine handling system such as a geothermal brine electric generating plant. The process includes washing the sludge with hot water to displace any brine entrapped in the sludge, dewatering the washed sludge and leaching the silicious solids residue with hydrochloric acid having a concentration of between about 2 and about 9 weight percent and an acid-to-sludge weight ratio between about 0.10 and about 0.33. The acid-sludge mixture is heated to a temperature of at least about 50.degree. and the leaching time is at least about one hour. The leaching solution is separated from the leached sludge and the solids residue are washed with water. Preferably the water used in both washing steps is condensate of steam derived from the geothermal brine. Effluent from the process is preferably combined with the brine for reinjection.

Abstract: A method for recovering lead from lead chloride through aqueous electrolysis wherein the lead chloride is directly reduced to metallic lead on the cathode. The electrolyte may comprise liquor from the leaching of galena concentrates, which liquor includes ferrous chloride that is subsequently converted to ferric chloride during electrolysis and recycled for additional leaching.