Patents by Inventor Mosha H. ZHAO
Mosha H. ZHAO has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11499031Abstract: A composition comprising the reaction product of a polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?vis) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C.; and within the range from 0.01 to 3 wt % of at least one organic peroxide, by weight of the polypropylene and organic peroxide. Such hyperbranched polypropylenes are useful in films, foamed articles, and thermoformed articles.Type: GrantFiled: December 4, 2019Date of Patent: November 15, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: George J. Pehlert, Mosha H. Zhao
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Patent number: 11414526Abstract: A method of melt blending a polypropylene and the melt blended polypropylene therefrom, comprising providing a base-polypropylene having a MFR of less than 15 g/10 min and a molecular weight distribution (Mw/Mn) within the range from 5 to 16, and comprising hindered phenol and phosphorous-type antioxidants, and within the range from 5 ppm to 4000 ppm of an alkyl radical scavenger relative to the total weight of the components to form a melt blended polypropylene; melt blending the melt blended polypropylene at a temperature of at least 210° C.; and isolating a melt blended, melt blended polypropylene.Type: GrantFiled: June 25, 2015Date of Patent: August 16, 2022Assignee: EXXONMOBIL CHEMICAL PATENTS INC.Inventors: George J. Pehlert, Mosha H. Zhao, Roswell E. King
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Publication number: 20220017730Abstract: The present disclosure provides polyolefin compositions and films and method for producing such films. The polyolefin composition contains about 40 wt % to about 95 wt % of a BOCD polyethylene and about 10 wt % to about 60 wt % of a polypropylene, by weight of the polyolefin composition. The polyolefin composition has a 1% secant flexural modulus MID of greater than 250 MPa and a 1% secant flexural modulus TD of greater than 300 MPa, as determined for a layer of the polyolefin composition having a thickness of about 50 ?m and a Dart Impact (Method A) of greater than 15 g/?m and an Elmendorf tear MI) of greater than 7 g/?m, as determined for a film containing the polyolefin composition and having a thickness of about 90 ?m.Type: ApplicationFiled: November 11, 2019Publication date: January 20, 2022Inventors: Sushanta DHAR ROY, Bradley A. KRAMER, Ying ZOU, Jasper HOLSBEEK, Stefan B. OHLSSON, Maciej M. PASNIEWSKI, Mosha H. ZHAO
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Patent number: 10787399Abstract: A process for producing phenylstyrene comprises contacting benzene with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation product comprising cyclohexylbenzene. At least part of the cyclohexylbenzene is then contacted with ethylbenzene in the presence of a transalkylation catalyst under conditions effective to produce a transalkylation product comprising cyclohexylethylbenzene and/or with ethylene in the presence of an alkylation catalyst under conditions effective to produce an alkylation product comprising cyclohexylethylbenzene. At least part of the cyclohexylethylbenzene is then contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation product comprising phenylstyrene.Type: GrantFiled: October 14, 2016Date of Patent: September 29, 2020Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michael Salciccioli, Alan A. Galuska, Ranjita Ghose, Doron Levin, Mosha H. Zhao
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Publication number: 20200109260Abstract: A composition comprising the reaction product of a polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?vis) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C.; and within the range from 0.01 to 3 wt % of at least one organic peroxide, by weight of the polypropylene and organic peroxide. Such hyperbranched polypropylenes are useful in films, foamed articles, and thermoformed articles.Type: ApplicationFiled: December 4, 2019Publication date: April 9, 2020Inventors: George J. Pehlert, Mosha H. Zhao
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Patent number: 10538645Abstract: A composition comprising the reaction product of a polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?vis) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C.; and within the range from 0.01 to 3 wt % of at least one organic peroxide, by weight of the polypropylene and organic peroxide. Such hyperbranched polypropylenes are useful in films, foamed articles, and thermoformed articles.Type: GrantFiled: January 21, 2016Date of Patent: January 21, 2020Assignee: ExxonMobil Chemical Patents Inc.Inventors: George J. Pehlert, Mosha H. Zhao
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Patent number: 10472437Abstract: Disclosed is an article comprising polymers and copolymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted versions thereof, and blends thereof, the polymer or copolymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C. The polymers are desirably processed in the melted state at a temperature of at least 150° C. to impart orientation and extensional strain hardening.Type: GrantFiled: November 9, 2017Date of Patent: November 12, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Carlos R. Lopez-Barron, Mark K. Davis, Alan A. Galuska, Yong Yang, Mosha H. Zhao
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Patent number: 10457789Abstract: A process to form a polypropylene composition comprising combining at a temperature within a range from 190° C. to 320° C. a polypropylene resin and within the range from 0.01 wt % to 3 wt % of at least one organic peroxide, by weight of the polypropylene composition and within a range from 100 to 4000 ppm each of phosphorous- and hindered phenol antioxidants; the polypropylene resin comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C. The resulting polypropylene composition comprises at least 50 mol % propylene and has a peak extensional viscosity of greater than 500 kPa·s at a strain rate of 0.01 sec?1 (190° C.) and a melt strength of at least 40 determined using an extensional rheometer at 190°.Type: GrantFiled: February 17, 2016Date of Patent: October 29, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mosha H. Zhao, George J. Pehlert
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Patent number: 10442879Abstract: An impact copolymer comprising a polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (MwMALLS/Mn) greater than 10, a branching index (g?) of less than 0.97, and a melt strength greater than 40 cN, and an elastomer. Also disclosed is a method of making an impact copolymer composition comprising melt-blending the components, sequentially or simultaneously a polypropylene resin comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C.; and within the range from 0.01 to 3 wt % of at least one organic peroxide; and an elastomer.Type: GrantFiled: March 23, 2016Date of Patent: October 15, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jan Kalfus, Abdul M. Jangda, Mosha H. Zhao
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Patent number: 10435359Abstract: Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.Type: GrantFiled: August 9, 2017Date of Patent: October 8, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Tracie L. Owens, Virginia M. Reiner, Mosha H. Zhao, Jingwen Zhang, Beatrice M. Gooding, James R. Bielenberg
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Patent number: 10351520Abstract: Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.Type: GrantFiled: August 9, 2017Date of Patent: July 16, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mosha H. Zhao, Virginia M. Reiner, Jingwen Zhang, Tracie L. Owens
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Patent number: 10351521Abstract: Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.Type: GrantFiled: August 9, 2017Date of Patent: July 16, 2019Assignee: ExxonMobil Chemical Patents Inc.Inventors: Virginia M. Reiner, Jingwen Zhang, Tracie L. Owens, Mosha H. Zhao
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Publication number: 20180305512Abstract: Strain-induced articles such as foamed, blow molded, or thermoformed articles comprising styrenic copolymers such as poly(vinylbiphenyl-co-styrene) having improved strain hardening and extensional viscosity for foaming and other applications, having a weight average molecular weight (Mw) of at least 100 kg/mole, comprising within the range from 5 to 80 wt % styrene derived units, and a process to form such styrenic copolymers, the process comprising combining styrene, a second aryl-containing monomer such as 4-vinylbiphenyl, and an initiator.Type: ApplicationFiled: April 5, 2018Publication date: October 25, 2018Inventors: Carlos R. Lopez-Barron, Mosha H. Zhao, Alan A. Galuska, Mark K. Davis
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Publication number: 20180258011Abstract: A process for producing phenylstyrene comprises contacting benzene with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation product comprising cyclohexylbenzene. At least part of the cyclohexylbenzene is then contacted with ethylbenzene in the presence of a transalkylation catalyst under conditions effective to produce a transalkylation product comprising cyclohexylethylbenzene and/or with ethylene in the presence of an alkylation catalyst under conditions effective to produce an alkylation product comprising cyclohexylethylbenzene. At least part of the cyclohexylethylbenzene is then contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation product comprising phenylstyrene.Type: ApplicationFiled: October 14, 2016Publication date: September 13, 2018Inventors: Michael Salciccioli, Alan A. Galuska, Ranjita Ghose, Dorin Levin, Mosha H. Zhao
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Publication number: 20180244883Abstract: A process to form a polypropylene composition comprising combining at a temperature within a range from 190° C. to 320° C. a polypropylene resin and within the range from 0.01 wt % to 3 wt % of at least one organic peroxide, by weight of the polypropylene composition and within a range from 100 to 4000 ppm each of phosphorous- and hindered phenol antioxidants; the polypropylene resin comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C. The resulting polypropylene composition comprises at least 50 mol % propylene and has a peak extensional viscosity of greater than 500 kPa·s at a strain rate of 0.01 sec?1 (190° C.) and a melt strength of at least 40 determined using an extensional rheometer at 190°.Type: ApplicationFiled: February 17, 2016Publication date: August 30, 2018Inventors: Mosha H. Zhao, George J. Pehlert
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Publication number: 20180155471Abstract: Disclosed is an article comprising polymers and copolymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted versions thereof, and blends thereof, the polymer or copolymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C. The polymers are desirably processed in the melted state at a temperature of at least 150° C. to impart orientation and extensional strain hardening.Type: ApplicationFiled: November 9, 2017Publication date: June 7, 2018Inventors: Carlos R. Lopez-Barron, Mark K. Davis, Alan A. Galuska, Yong Yang, Mosha H. Zhao
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Publication number: 20180094089Abstract: An impact copolymer comprising a polypropylene comprising at least 50 mol % propylene, and having a molecular weight distribution (MwMALLS/Mn) greater than 10, a branching index (g?) of less than 0.97, and a melt strength greater than 40 cN, and an elastomer. Also disclosed is a method of making an impact copolymer composition comprising melt-blending the components, sequentially or simultaneously a polypropylene resin comprising at least 50 mol % propylene, and having a molecular weight distribution (Mw/Mn) greater than 6, a branching index (g?) of at least 0.97, and a melt strength greater than 10 cN determined using an extensional rheometer at 190° C.; and within the range from 0.01 to 3 wt % of at least one organic peroxide; and an elastomer.Type: ApplicationFiled: March 23, 2016Publication date: April 5, 2018Inventors: Jan Kalfus, Abdul M. Jangda, Mosha H. Zhao
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Publication number: 20180057453Abstract: Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.Type: ApplicationFiled: August 9, 2017Publication date: March 1, 2018Inventors: Virginia M. Reiner, Jingwen Zhang, Tracie L. Owens, Mosha H. Zhao
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Publication number: 20180057451Abstract: Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.Type: ApplicationFiled: August 9, 2017Publication date: March 1, 2018Inventors: Tracie L. Owens, Virginia M. Reiner, Mosha H. Zhao, Jingwen Zhang, Beatrice M. Gooding, James R. Bielenberg
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Publication number: 20180057452Abstract: Provided herein are various methods for forming alkylaromatic sulfonate compositions and blended alkylaromatic sulfonate compositions, and such compositions themselves. The methods of various embodiments include obtaining a C8-C30 hydrocarbon mixture, optionally treating the mixture to concentrate the mixture in sulfonatable aromatics, and sulfonating the mixture to form the alkylaromatic sulfonates. The mixture or treated mixture may be blended with linear alkyl benzene (LAB) compositions and sulfonated, and/or the alkylaryl sulfonates may be blended with linear alkylbenzene sulfonate (LAS) compositions, to form the blended alkylaromatic sulfonates of some embodiments. These compositions and processes for making them may be tailored to serve a variety of end uses, such as detergents in cleaning solutions or for enhanced oil recovery operations, and/or as low foaming and/or hydrotropic additives in detergent formulations, and the like.Type: ApplicationFiled: August 9, 2017Publication date: March 1, 2018Inventors: Mosha H. Zhao, Virginia M. Reiner, Jingwen Zhang, Tracie L. Owens