Patents by Inventor Motoshige Sumino

Motoshige Sumino has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6924323
    Abstract: A compound shown by the general formula [1] (wherein R1, R2 and R3 are each independently an aromatic hydrocarbon residual group, Yn? is an anion derived from a carboxylic acid having 3 or more carbon atoms with substituted fluorine atoms, and n is 1 or 2, provided that R1, R2 and R3 each is not a phenyl group having substituents at an ortho and/or a meta position), and a composition consisting of the compound and a diazodisulfone compound are disclosed. Use of the compound or the compound as an acid generator for resists produces the effects of improving the profiles of ultra-fine patterns or diminishing sidewall irregularities in ultra-fine patterns. The compound is also useful as a cationic photopolymerization initiator.
    Type: Grant
    Filed: June 27, 2001
    Date of Patent: August 2, 2005
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Masami Ishihara, Motoshige Sumino, Kazuhito Fukasawa, Naoki Katano, Shigeaki Imazeki
  • Patent number: 6723483
    Abstract: A triphenyl sulfonium salt compound shown by the general formula [1] or [3]. (wherein R1 and R2 are each independently a hydrogen atom or a lower alkyl group, provided that at least one of R1 and R2 are a lower alkyl group, R3s are each independently an alkyl group, n is an integer of 0 to 3, i is an integer of 1 to 3, j is an integer of 0 to 2, provided that i+j=3, Y− is an anion derived from a sulfonic acid shown by the general formula [2] R4—SO3H  [2] [wherein R4 is an alkyl group or an aryl group which may have as a substituent an alkyl group]). (wherein X is a phenyl group which has a substituent at an ortho- and/or a meta-position, m is an integer of 1 to 3, q is an integer of 0 to 2, provided that m+q=3, p is 1 or 2 and Zp− is an anion derived from a carboxylic acid).
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: April 20, 2004
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Keiji Oono, Kazuhito Fukasawa, Kazunori Sakamoto, Fumiyoshi Urano, Motoshige Sumino, Shigeaki Imazeki
  • Publication number: 20040033434
    Abstract: A compound shown by the general formula [1] 1
    Type: Application
    Filed: January 14, 2003
    Publication date: February 19, 2004
    Inventors: Masami Ishihara, Motoshige Sumino, Kazuhito Fukasawa, Naoki Katano, Shigeaki Imazeki
  • Patent number: 6476240
    Abstract: This invention relates to a monomer shown by the general formula [1] (wherein X′ is a cyclic hydrocarbon residue containing polymerizable double bond(s), which may have a substituent, Z is a spacer or a direct bond and R is a substituted alkyl or alkenyl group having one or two protected hydroxyl groups as substituent) and a polymer containing a segment derived from the above monomer. The said polymer is useful for a resist composition, etc. utilized in the production of semiconductor elements, etc. and the said monomer is useful as a starting material for the polymer, and a resist composition using the said polymer can remarkably advantageously be used as a resist material for ArF excimer laser beams which has been considered to be a valuable technology for exposure belonging to the coming generation.
    Type: Grant
    Filed: October 16, 2001
    Date of Patent: November 5, 2002
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventor: Motoshige Sumino
  • Publication number: 20020042531
    Abstract: This invention relates to a monomer shown by the general formula [1] 1
    Type: Application
    Filed: October 16, 2001
    Publication date: April 11, 2002
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventor: Motoshige Sumino
  • Patent number: 6335143
    Abstract: A resist composition comprising an alkali-soluble polymer, a special cross-linking agent containing one or more oxirane rings and at least one of —O—, —CO—,—COO— and —OCO— groups in the molecule, a photoacid generator, and a solvent can form a film having high transmittance for deep UV light such as ArF excimer laser beams and high etching resistance as well as high resolution, and thus suitable for forming a negative working pattern.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: January 1, 2002
    Assignees: Wako Pure Chemical Industries Ltd., Matsushita Electronics Corporation
    Inventors: Motoshige Sumino, Hirotoshi Fujie, Akiko Katsuyama, Masayuki Endo
  • Patent number: 6331602
    Abstract: This invention relates to a monomer shown by the general formula [1] (wherein X′ is a cyclic hydrocarbon residue containing polymerizable double bond(s), which may have a substituent, Z is a spacer or a direct bond and R is a substituted alkyl or alkenyl group having one or two protected hydroxyl groups as substituent) and a polymer containing a segment derived from the above monomer. The said polymer is useful for a resist composition, etc. utilized in the production of semiconductor elements, etc. and the said monomer is useful as a starting material for the polymer, and a resist composition using the said polymer can remarkably advantageously be used as a resist material for ArF excimer laser beams which has been considered to be a valuable technology for exposure belonging to the coming generation.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: December 18, 2001
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventor: Motoshige Sumino
  • Patent number: 6160068
    Abstract: This invention relates to a monomer shown by the general formula [1] ##STR1## (wherein X' is a cyclic hydrocarbon residue containing polymerizable double bond(s), which may have a substituent, Z is a spacer or a direct bond and R is a substituted alkyl or alkenyl group having one or two protected hydroxyl groups as substituent) and a polymer containing a segment derived from the above monomer.The said polymer is useful for a resist composition, etc. utilized in the production of semiconductor elements, etc. and the said monomer is useful as a starting material for the polymer, and a resist composition using the said polymer can remarkably advantageously be used as a resist material for ArF excimer laser beams which has been considered to be a valuable technology for exposure belonging to the coming generation.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: December 12, 2000
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventor: Motoshige Sumino
  • Patent number: 6143472
    Abstract: This invention relates to a resist composition comprising a polymer containing, as a constituent unit, a monomer unit shown by the general formula [1a] ##STR1## (wherein X is a polycyclic hydrocarbon residue which may have a substituent, Z is a spacer or a direct bond, and R is a substituted alkyl or alkenyl group having one or two protected hydroxyl groups as substituent), a photosensitive compound which can generate an acid upon exposure to light and a solvent which can dissolve the polymer and the photosensitive compound, and a method for formation of a pattern using the said resist composition.The said resist composition shows high sensitivity and high resolution ability in which a polymer having high transmittance against deep-ultraviolet lights having a wavelength of 220 nm or less, particularly ArF excimer laser beams.
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: November 7, 2000
    Assignees: Wako Pure Chemical Industries, Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Motoshige Sumino, Akiko Katsuyama
  • Patent number: 5973094
    Abstract: To provide a polymer comprising as a structural unit a monomer unit containing a hydroxy group or other hydrophilic radical and other functional group in the molecule which is useful in medical, cosmetic and electric industries.A polymer comprising as a structural unit a monomer unit shown by the general formfula [1] ##STR1## (wherein R.sup.1 and R.sup.2 are, independently, a hydrogen atom or a halogen atom, R.sup.3 is a hydrophilic radical and R.sup.4 is a cyano group or a carboxyl group which may he esterified).
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: October 26, 1999
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Fumiyoshi Urano, Motoshige Sumino, Tsuneaki Maesawa
  • Patent number: 5856521
    Abstract: A monomer of the formula: ##STR1## wherein R5, R6 and R7 are independently hydrogen, alkyl, cyano, alkyloxycarbonyl or carbamoyl; Z is a spacer or a direct link; and R is hydroxyalkyl having a protected terminal hydroxy, can produce a polymer useful for producting a resist composition.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: January 5, 1999
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Motoshige Sumino, Kazuhito Fukasawa
  • Patent number: 5463075
    Abstract: Novel and improved simple process for preparing a 1,2-pyrazolidine-4-yl-disulfide compound represented by the following formula: ##STR1## wherein R.sup.1 and R.sup.2 are, independently each other, a hydrogen atom or an amino-protecting group.This compound may be prepared by reacting a compound of the formula: ##STR2## wherein R.sup.3 is an acid anion residue group, and R.sup.1 and R.sup.2 have the same meanings as above, with a disulfide compound selected from the group consisting of an alkali metal disulfide, an alkali earth metal disulfide, an ammonium disulfide and a tri-alkylammonium disulfide.
    Type: Grant
    Filed: September 6, 1994
    Date of Patent: October 31, 1995
    Assignee: WAKO Pure Chemical Industries, Ltd.
    Inventors: Motoshige Sumino, Tsutomu Tani, Atsunori Sano
  • Patent number: 5254688
    Abstract: A pyrido[1,2-a]pyrimidine derivative which is useful as an antiallergic agent can be produced from a 2-aminopyridine derivative or a hydrazoic acid salt thereof by a one-pot and substantially one-step process.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: October 19, 1993
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Atsunori Sano, Motoshige Sumino, Masami Ishihara, Kazuo Maruhashi