Abstract: An electrode for a photovoltaic device such as a dye sensitized solar cell includes a uniform layer of ZnO nanorods formed on a transparent conductive substrate and a natural dye, such as pigments from a natural source like coffee, on the ZnO nanorods. A dye sensitized solar cell formed from the electrode as a working electrode and a carbon-based counter electrode, such as a carbon soot layer on a transparent conductive substrate. The electrode and dye sensitized solar cell are formed by a simple, cost effective, environmentally friendly and easily scalable method.