Abstract: A method of generating oxygen including applying a potential of greater than 0 to 2.0 V to an electrochemical cell. The electrochemical cell is at least partially submerged in an aqueous solution, where on applying the potential the aqueous solution is oxidized thereby forming oxygen. The electrochemical cell includes an electrocatalyst; and a counter electrode. The electrocatalyst includes a nickel foam substrate; and a layer of particles of a FeNi alloy on the surface of the nickel foam substrate, where the particles of the FeNi alloy are in the form of nanosheets, where the nanosheets have average width of 1-5 ?m and an average length of 1-10 ?m, and where the nanosheets are vertically aligned to form a flower shape.

Abstract: A method of making an aluminum-cubic boron nitride (Al-cBN) composite includes mixing an aluminum powder and particles of cubic boron nitride (cBN) in a solvent and sonicating to form an Al-cBN mixture; drying the Al-cBN mixture to form a dried mixture powder; and sintering by pressing and heating the dried mixture powder to form the Al-cBN composite. The aluminum powder has an average particle size of 10 to 100 micrometers (?m). The cBN particles have an average particle size of from 10 to 100 ?m, and are uniformly dispersed throughout the Al-cBN composite.

Abstract: A method of generating oxygen including applying a potential of greater than 0 to 2.0 V to an electrochemical cell that is at least partially submerged in an aqueous solution such that on applying the potential the aqueous solution is oxidized thereby forming oxygen. The electrochemical cell includes an electrocatalyst and a counter electrode. The electrocatalyst includes a nickel foam substrate and a layer of particles of manganese oxide having a formula of MnxOy on a surface of the nickel foam substrate, where x is an integer from 1 to 7, and where y is an integer from 1 to 13. The particles of MnO have a spherical shape with an average diameter of 5-15 nanometers (nm) and are aggregated with an average aggregate size of 500-1,000 nm in the shape of a cauliflower.

Abstract: A method of generating oxygen including applying a potential of greater than 0 to 2.0V to an electrochemical cell, where the electrochemical cell is at least partially submerged in an aqueous solution, and where on applying the potential the aqueous solution is oxidized thereby forming oxygen. The electrochemical cell includes an electrocatalyst; and a counter electrode. The electrocatalyst includes a nickel foam substrate; and a layer of particles of FeNiOx on a surface of the nickel foam substrate, wherein x=3-4. The particles of FeNiOx have a nanorod shape with an average diameter of 100-500 nanometers (nm) and a length longer than 500 nm. The terminal end of the nanorod shape has a cap with a hemispherical shape having a diameter larger than the average diameter of the nanorod shape.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: A rapid method of synthesizing nanoflowers made of nanoflakes of nickel molybdate (NiMoO4) directly on nickel foam (NF) through an aerosol-assisted chemical vapor deposition (AACVD) process is disclosed. The nickel molybdate nanoflowers were grown on NF by varying the deposition time for 60 and 120 min at a fixed temperature of 480° C. and their efficiency was investigated as oxygen evolution reaction (OER) catalysts in 1 M KOH electrolyte. The NiMoO4 nanoflowers of NF obtained after 60 minutes of AACVD process showed OER performance with lowest overpotential of 320 mV to reach standard current density of 10 mA cm?2. The catalyst continuously performed the OER for 15 h, signifying its prominent stability under electrochemical conditions.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: A vanadium oxide-based electrode for electrochemical water splitting that includes a metallic substrate and a layer of particles of a vanadium oxide composite at least partially covering a surface of the metallic substrate. The particles of the vanadium oxide composite are in the form of nanobeads having an average particle size of 50 to 400 nm. A method of making the electrode.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: An electrocatalyst including a nickel foam (NF) substrate and a layer of metallic nickel particles on the nickel foam substrate. The metallic nickel particles are spherical and have an average diameter of 100-500 nanometers (nm). Further, the metallic nickel particles are aggregated with aggregates having an average size of 0.5 to 5 micrometers (?m).

Abstract: An electrocatalyst including an iron foam substrate and magnetite (Fe3O4). At least one layer of the Fe3O4 is deposited onto the iron foam substrate. At least one layer of the Fe3O4 on the iron foam substrate is continuous. At least one layer of the Fe3O4 on the iron foam substrate has a thickness of 0.01 micrometer (?m) to 50 ?m. The Fe3O4 is in a form of particles having a spherical shape with an average diameter of 0.01 to 2 ?m.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: A rapid method of synthesizing nanoflowers made of nanoflakes of nickel molybdate (NiMoO4) directly on nickel foam (NF) through an aerosol-assisted chemical vapor deposition (AACVD) process is disclosed. The nickel molybdate nanoflowers were grown on NF by varying the deposition time for 60 and 120 min at a fixed temperature of 480° C. and their efficiency was investigated as oxygen evolution reaction (OER) catalysts in 1 M KOH electrolyte. The NiMoO4 nanoflowers of NF obtained after 60 minutes of AACVD process showed OER performance with lowest overpotential of 320 mV to reach standard current density of 10 mA cm?2. The catalyst continuously performed the OER for 15 h, signifying its prominent stability under electrochemical conditions.

Abstract: An electrocatalyst and a method of preparing the electrocatalyst are described. The electrocatalyst includes a porous foam substrate; and a catalytically active layer comprising NiVOx nanostructures, the catalytically active layer being disposed on an exterior surface and an interior pore surface of the porous metal foam substrate; where “x” is in the range of 1 to 3. A method of using the electrocatalyst for water oxidation is also described.

Abstract: Catalytic materials useful, e.g., in water oxidation performing at low overpotential and/or stable for applications such as solar-to-fuel conversion systems may include nanoscale, nanoporous Pd-containing materials. Thin-film Pd electrocatalysts may be obtained via Aerosol-Assisted Chemical Vapor Deposition (AACVD) on conducting surfaces. XRD and XPS analyses show a phase pure crystalline metallic Pd deposit. Surface morphology study reveals a nanoparticulate highly porous nanostructure. Under electrochemical conditions, such Pd electrocatalysts may conduct water oxidation at onset potentials starting around 1.43 V against a reversible hydrogen electrode (? of 200 mV, Tafel slope of 40 mV/dec), and/or may achieve around 100 mA/cm2 current density at 1.63 V against a reversible hydrogen electrode, and may exhibits long-term stability in oxygen evolution. Method of making such electrocatalysts and their uses are also provided.

Abstract: A CoVOx composite electrode and method of making is described. The composite electrode comprises a substrate with an average 0.5-5 ?m thick layer of CoVOx having pores with average diameters of 2-200 nm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a cobalt complex, and a vanadium complex. The CoVOx composite electrode is capable of being used in an electrochemical cell for water oxidation.

Abstract: An aerosol-assisted chemical vapor-deposition (AACVD) method of making nickel sulfide (NiS) nanowires. The method includes depositing a nickel carbamate compound onto a conductive support by an AACVD technique to form nickel sulfide (NiS) nanowires on the conductive support, where the nanowires are present directly on a surface of the conductive support. The NiS electrode prepared by the process of the present disclosure showed excellent OER activity in 1.0 M KOH solution, with a low Tafel value (60 mV dec?1) and good OER stability. The NiS nanowires, as prepared, can be used in energy conversion devices such as batteries, fuel cells, and supercapacitors.