Abstract: Disclosed is a method of preparing sodium-catalyzed iron-aluminum inorganic catalyst for catalyzing a hydrogenation reaction of carbon dioxide. The method of preparing sodium-catalyzed iron-aluminum inorganic catalyst includes: a first step of mixing a precipitant solution formed by dissolving a basic precipitant with a reaction solution formed by dissolving an iron (Fe) precursor material and an aluminum (Al) precursor material, thereby forming a suspension solution; a second step of aging the suspension solution; a third step of separating powder from the aged suspension solution; a fourth step of drying the separated powder and then performing a first heat treatment, thereby forming first catalyst powder; and a fifth step of adding and stirring the first catalyst powder and a sodium precursor material to water and evaporating the water and then performing a second heat treatment, thereby preparing a sodium-introduced iron-aluminum inorganic catalyst.