Abstract: This invention relates to methods to prepare and compositions pertaining to branched ethylene-propylene copolymers that include at least 50% ethylene content by weight as determined by FTIR; a g?vis of less than 0.95; a Mw of 125,000 to 300,000; a methylene sequence length of 6 or greater as determined by 13C NMR, wherein the percentage of sequences of the length of 6 or greater is more than 32%; and can have greater than 50% vinyl chain end functionality.

Abstract: The present invention is related to adhesive compositions and their applications. In particular, the adhesive compositions described herein comprise a propylene-based polymer and an ethylene-based polymer with varying comonomer content.

Abstract: This invention relates to methods to prepare and compositions pertaining to branched ethylene-propylene copolymers that include at least 50% ethylene content by weight as determined by FTIR; a g?vis of less than 0.95; a Mw of 125,000 to 300,000; a methylene sequence length of 6 or greater as determined by 13C NMR, wherein the percentage of sequences of the length of 6 or greater is more than 32%; and can have greater than 50% vinyl chain end functionality.

Abstract: This invention relates to methods to prepare and compositions pertaining to branched ethylene-propylene copolymers that include at least 50% ethylene content by weight as determined by FTIR; a g?vis of less than 0.95; a Mw of 125,000 to 300,000; a methylene sequence length of 6 or greater as determined by 13C NMR, wherein the percentage of sequences of the length of 6 or greater is more than 32%; and can have greater than 50% vinyl chain end functionality.

Abstract: This invention relates to methods to prepare and compositions pertaining to branched ethylene-propylene copolymers that include at least 50% ethylene content by weight as determined by FTIR; a g?vis of less than 0.95; a MW of 150,000 to 250,000; a methylene sequence length of 6 or greater as determined by 13C NMR, wherein the percentage of sequences of the length of 6 or greater is more than 32%; and can have greater than 50% vinyl chain end functionality.

Abstract: This invention relates to methods to prepare and compositions pertaining to branched ethylene-propylene copolymers that include at least 50% ethylene content by weight as determined by FTIR; a g?vis of less than 0.95; a Mw of 125,000 to 300,000; a methylene sequence length of 6 or greater as determined by 13C NMR, wherein the percentage of sequences of the length of 6 or greater is more than 32%; and can have greater than 50% vinyl chain end functionality.

Abstract: This invention relates to a reaction product obtained by contacting a polymer comprising units derived from dicyclopentadiene with a vinyl terminated macromonomer, a vinyl monomer or a vinylene monomer, in the presence of a metathesis catalyst, where the vinyl monomer or vinylene monomer is represented by the formula: wherein each X is, independently, —CO2R, —CONR1R2, CN, a C1 to a C20 alkyl group; R is a C1 to a C20 alkyl group or an aromatic group; each R1 and R2 is, independently, a hydrogen, a C1 to a C20 alkyl group, or an aromatic group; each R5 is, independently, a hydrogen atom or a C1 to a C40 alkyl group; each Ar is, independently, an aromatic group; and each n is, independently, from 0 to about 40.

Abstract: A highly branched polyolefin having olefin derived units; wherein the highly branched polyolefin has: (i) a branching index, g?(vis), of less than about 0.9; (ii) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C.; (iii) a gel content of less than or equal to about 10%; and (iv) a melting point of less than about 135° C.; wherein the highly branched polyolefin is obtained by contacting one or more polyolefins with a free radical generator. The highly branched polyolefin may also comprise a modifying polymer, wherein the modifying polymer may be the similar or dissimilar to the polyolefin. Methods of producing these highly branched polyolefins and blends of these highly branched polyolefins are also disclosed.

Abstract: The present invention is related to adhesive compositions and their applications. In particular, the adhesive compositions described herein comprise a propylene-based polymer and an ethylene-based polymer with varying comonomer content.

Abstract: Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity.

Abstract: Highly branched compositions including: (i) from about 96 wt % to about 99.9 wt % metallocene catalyzed ethylene propylene diene derived units; and (ii) from about 0.1 wt % to about 4 wt % multifunctional monomer derived units, wherein the highly branched composition has: (a) a Mooney viscosity ML (1+4) at 125° C. of about 30 to 100 MU, (b) a Mooney relaxation area MLRA of about 100 to about 1000, (c) a branching index, g?(vis) of less than about 0.9, (d) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C., and (e) a degree of shear thinning greater than about 0.95, measured at 190° C., are disclosed herein. Homogeneous blends including this composition are also described. Processes to make the highly branched composition and the homogeneous blend are also described herein.

Abstract: This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.

Abstract: This invention relates to a reaction product obtained by contacting a polymer comprising units derived from dicyclopentadiene with a vinyl terminated macromonomer, a vinyl monomer or a vinylene monomer, in the presence of a metathesis catalyst, where the vinyl monomer or vinylene monomer is represented by the formula: wherein each X is, independently, —CO2R, —CONR1R2, CN, a C1 to a C20 alkyl group; R is a C1 to a C20 alkyl group or an aromatic group; each R1 and R2 is, independently, a hydrogen, a C1 to a C20 alkyl group, or an aromatic group; each R5 is, independently, a hydrogen atom or a C1 to a C40 alkyl group; each Ar is, independently, an aromatic group; and each n is, independently, from 0 to about 40.

Abstract: A highly branched polyolefin having olefin derived units; wherein the highly branched polyolefin has: (i) a branching index, g?(vis), of less than about 0.9; (ii) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C.; (iii) a gel content of less than or equal to about 10%; and (iv) a melting point of less than about 135° C.; wherein the highly branched polyolefin is obtained by contacting one or more polyolefins with a free radical generator. The highly branched polyolefin may also comprise a modifying polymer, wherein the modifying polymer may be the similar or dissimilar to the polyolefin. Methods of producing these highly branched polyolefins and blends of these highly branched polyolefins are also disclosed.

Abstract: Highly branched compositions including: (i) from about 96 wt % to about 99.9 wt % metallocene catalyzed ethylene propylene diene derived units; and (ii) from about 0.1 wt % to about 4 wt % multifunctional monomer derived units, wherein the highly branched composition has: (a) a Mooney viscosity ML (1+4) at 125° C. of about 30 to 100 MU, (b) a Mooney relaxation area MLRA of about 100 to about 1000, (c) a branching index, g?(vis) of less than about 0.9, (d) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C., and (e) a degree of shear thinning greater than about 0.95, measured at 190° C., are disclosed herein. Homogeneous blends including this composition are also described. Processes to make the highly branched composition and the homogeneous blend are also described herein.

Abstract: This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.

Abstract: This invention relates to a film comprising a blend composition comprising: 1) a linear ethylene containing polymer, such as a LLDPE, a HDPE or the like; and at least 1 weight percent of an in-reactor polymer blend comprising: (a) a first ethylene containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol; and (b) a second ethylene containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.

Abstract: This invention relates to a film or sheet and a process to make a film or sheet having a thickness of 0.5 to 35 mils comprising a blend composition comprising: a) 4 to 50 wt % of one or more polypropylene-based TPO(s); and b) 30 to 80 wt % of one or more ethylene plastomer(s); and c) 0.5 to 35 wt % of one or more non-functionalized plasticizer(s) having a kinematic viscosity at 100° C. of 4 to 300 cSt, a pour point of ?20° C. or less, and a flash point of 200° C. or more; and d) 0 to 69.5 wt % of one or more filler(s); and wherein the blend composition is calendered into a film or sheet.

Abstract: This invention relates to a blend composition comprising: 1) a linear ethylene containing polymer, such as a LLDPE, a HDPE or the like; and at least 1 weight percent of an in-reactor polymer blend comprising: (a) a first ethylene containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol; and (b) a second ethylene containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.

Abstract: The present invention is directed to polymer blend compositions for use as viscosity modifiers comprising at least two ethylene-based copolymer components. The viscosity modifiers described herein comprise a first ethylene-based copolymer having an ethylene content of from about 44 to about 52 wt % and/or a heat of fusion of from about 0 to about 15 J/g and a second ethylene-based copolymer having an ethylene content of from about 68 to about 75 wt % and/or a heat of fusion of from about 40 to about 65 J/g. The invention is also directed to lubricant compositions comprising a lubricating basestock and a polymer blend of the invention.