Patents by Inventor Munehito Funaya
Munehito Funaya has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230142911Abstract: To provide an olefin polymerization catalyst having high catalytic activity (polymerization activity), an olefin polymerization catalyst production method, and an olefin polymer production method using the olefin polymerization catalyst. An olefin polymerization catalyst comprising the following components [A], [B] and [C]: the component [A]: a metallocene complex having a specific indenyl structure, the component [B]: a solid component containing one or more selected from the group consisting of (b-1) a fine particulate carrier on which an ionic compound or Lewis acid which can convert the component [A] into a cation by reaction with the component [A], is supported, (b-2) solid acid fine particles, and (b-3) an ion-exchange layered compound, and the component [C]: a specific silylacetylene compound.Type: ApplicationFiled: March 23, 2021Publication date: May 11, 2023Applicant: JAPAN POLYPROPYLENE CORPORATIONInventors: Munehito FUNAYA, Ryota FUJITA
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Patent number: 10336838Abstract: [Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: GrantFiled: May 30, 2017Date of Patent: July 2, 2019Assignee: MITSUI CHEMICALS, INC.Inventors: Munehito Funaya, Atsushi Sakuma, Ikuko Ebisawa, Shinsuke Kinoshita, Akiko Matsumoto, Hirokazu Tanaka, Shinya Tanaka
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Patent number: 10336837Abstract: [Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: GrantFiled: May 30, 2017Date of Patent: July 2, 2019Assignee: MITSUI CHEMICALS, INC.Inventors: Munehito Funaya, Atsushi Sakuma, Ikuko Ebisawa, Shinsuke Kinoshita, Akiko Matsumoto, Hirokazu Tanaka, Shinya Tanaka
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Patent number: 9896526Abstract: [Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: GrantFiled: June 28, 2016Date of Patent: February 20, 2018Assignee: MITSUI CHEMICALS, INC.Inventors: Munehito Funaya, Atsushi Sakuma, Ikuko Ebisawa, Shinsuke Kinoshita, Akiko Matsumoto, Hirokazu Tanaka, Shinya Tanaka
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Publication number: 20170327610Abstract: [Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: ApplicationFiled: May 30, 2017Publication date: November 16, 2017Inventors: Munehito FUNAYA, Atsushi SAKUMA, Ikuko EBISAWA, Shinsuke KINOSHITA, Akiko MATSUMOTO, Hirokazu TANAKA, Shinya TANAKA
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Publication number: 20170327611Abstract: [Problem to be Solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to Problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: ApplicationFiled: May 30, 2017Publication date: November 16, 2017Inventors: Munehito FUNAYA, Atsushi SAKUMA, Ikuko EBISAWA, Shinsuke KINOSHITA, Akiko MATSUMOTO, Hirokazu TANAKA, Shinya TANAKA
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Patent number: 9796799Abstract: [Object] To provide transition metal compounds with excellent catalytic activity which can afford olefin polymers such as propylene polymers that have high stereoregularity and high molecular weight and may be easily crystallized into a ?-phase. [Solution] The transition metal compound is represented by General Formula [I] or is an enantiomer thereof: [in Formula [I], R1, R3, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15 and R16 are each independently a hydrogen atom, a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R2 is a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R4 is a hydrogen atom; any two substituents of the substituents R1 to R16 except R4 may be bonded to each other to form a ring; M is a Group IV transition metal; Q is a structure such as a halogen atom; and j is an integer of 1 to 4].Type: GrantFiled: June 28, 2016Date of Patent: October 24, 2017Assignee: MITSUI CHEMICALS, INC.Inventor: Munehito Funaya
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Publication number: 20160376385Abstract: [Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. Solution to problem The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: ApplicationFiled: June 28, 2016Publication date: December 29, 2016Inventors: Munehito FUNAYA, Atsushi SAKUMA, Ikuko EBISAWA, Shinsuke KINOSHITA, Akiko MATSUMOTO, Hirokazu TANAKA, Shinya TANAKA
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Publication number: 20160304640Abstract: [Object] To provide transition metal compounds with excellent catalytic activity which can afford olefin polymers such as propylene polymers that have high stereoregularity and high molecular weight and may be easily crystallized into ?-phase. [Solution] The transition metal compound is represented by General Formula [I] or is an enantiomer thereof: [in Formula [I], R1, R3, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15 and R16 are each independently a hydrogen atom, a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R2 is a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R4 is a hydrogen atom; any two substituents of the substituents R1 to R16 except R4 may be bonded to each other to form a ring; M is a Group IV transition metal; Q is a structure such as a halogen atom; and j is an integer of 1 to 4].Type: ApplicationFiled: June 28, 2016Publication date: October 20, 2016Inventor: Munehito FUNAYA
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Patent number: 9458261Abstract: [Object] To provide transition metal compounds with excellent catalytic activity which can afford olefin polymers such as propylene polymers that have high stereoregularity and high molecular weight and may be easily crystallized into a ?-phase. [Solution] The transition metal compound is represented by General Formula [I] or is enantiomer thereof: [in Formula [I], R1, R3, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15 and R16 are each independently a hydrogen atom, a hydrocarbon group, a heteroatom-containing hydrocarbon group, or a silicon-containing group; R2 is a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R4 is a hydrogen atom; any two substituents of the substituents R1 to R16 except R4 may be bonded to each other to form a ring; M is a Group IV transition metal; Q is a structure such as a halogen atom; and j is an integer of 1 to 4].Type: GrantFiled: September 24, 2013Date of Patent: October 4, 2016Assignee: MITSUI CHEMICALS, INC.Inventor: Munehito Funaya
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Patent number: 9458257Abstract: There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: GrantFiled: September 24, 2013Date of Patent: October 4, 2016Assignee: MITSUI CHEMICALS, INC.Inventors: Munehito Funaya, Atsushi Sakuma, Ikuko Ebisawa, Shinsuke Kinoshita, Akiko Matsumoto, Hirokazu Tanaka, Shinya Tanaka
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Publication number: 20150252123Abstract: [Object] To provide transition metal compounds with excellent catalytic activity which can afford olefin polymers such as propylene polymers that have high stereoregularity and high molecular weight and may be easily crystallized into a ?-phase. [Solution] The transition metal compound is represented by General Formula [I] or is enantiomer thereof: [in Formula [I], R1, R3, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15 and R16 are each independently a hydrogen atom, a hydrocarbon group, a heteroatom-containing hydrocarbon group, or a silicon-containing group; R2 is a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; is a hydrogen atom; any two substituents of the substituents R1 to R16 except R4 may be bonded to each other to form a ring; M is a Group IV transition metal; Q is a structure such as a halogen atom; and j is an integer of 1 to 4].Type: ApplicationFiled: September 24, 2013Publication date: September 10, 2015Inventor: Munehito Funaya
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Publication number: 20150239996Abstract: [Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and ?-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and ?-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R1, R3 and R5 to R16 are each independently a hydrogen atom, a hydrocarbon group or the like; R2 is a hydrocarbon group or the like; R4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].Type: ApplicationFiled: September 24, 2013Publication date: August 27, 2015Inventors: Munehito Funaya, Atsushi Sakuma, Ikuko Ebisawa, Shinsuke Kinoshita, Akiko Matsumoto, Hirokazu Tanaka, Shinya Tanaka
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Patent number: 8409480Abstract: [Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp ??(1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound.Type: GrantFiled: December 2, 2008Date of Patent: April 2, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Atsushi Sakuma, Munehito Funaya
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Publication number: 20120049391Abstract: [Problem] To provide a preparation process by which an organic alkali metal compound is obtained in a high yield and a process for preparing an organic transition metal compound using the organic alkali metal compound. [Means to solve the problem] A process for preparing an organic alkali metal compound, which is characterized by adding a compound represented by the following formula (2) in the reaction of an active proton-containing compound represented by the following formula (1) with an alkali metal compound. RHp??(1) In the formula (1), R is a hydrocarbon group or an amino group and may contain a halogen atom, a silicon atom, an oxygen atom or a nitrogen atom, H is an active proton, and p is the number of hydrogen atoms abstracted in the reaction with the alkali metal compound.Type: ApplicationFiled: December 2, 2008Publication date: March 1, 2012Inventors: Atsushi Sakuma, Munehito Funaya
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Patent number: 7879960Abstract: A high molecular weight propylene polymer exhibiting high stereoregularity (isotactic) and high position selectivity can be effectively produced by polymerizing at least one monomer selected from propylene, ?-olefins and polyenes in the presence of a catalyst for olefin polymerization comprising: (A) a bridged metallocene compound represented by the General Formula [I] given in claims (diphenylmethylene(3-tert-butyl-5-ethyl-cyclopentadienyl)(fluorenyl)zirconium dichloride, etc.); and (B) one or more compound(s) selected from (b-1) an organoaluminumoxy compound (b-2) a compound which reacts with the bridged metallocene compound (A) to form an ion pair, and (b-3) an organoaluminum compound.Type: GrantFiled: August 29, 2005Date of Patent: February 1, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Munehito Funaya, Naritoshi Hirota, Mayumi Hiwara, Yasushi Tohi, Koji Kawai, Ryoji Mori, Masahiko Okamoto, Shigenobu Ikenaga, Hiromasa Marubayashi
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Patent number: 7834204Abstract: Provided is a transition metal compound represented by the general formula [III]: wherein R23, R24, R25, R26, R27, and R28 are each independently selected from hydrogen, a hydrocarbon group, a silicon-containing group, a sulfur-containing group, an oxygen-containing group, a nitrogen-containing group, and a halogen-containing group, adjacent substituents of R23 to R28 are optionally bonded to each other to form a ring, M is a Group 4 transition metal, Y is carbon atom, Q is selected from halogen, a hydrocarbon group, an anionic ligand and a neutral ligand capable of coordinating with a lone electron pair, which is selected in the same combination or different combination, j is an integer of 1 to 4, and Z is a fluorenylidene group comprising a fluorene derivative formula [I] or formula [II]Type: GrantFiled: May 24, 2006Date of Patent: November 16, 2010Assignee: Mitsui Chemicals, Inc.Inventors: Munehito Funaya, Koji Endo, Naritoshi Hirota, Yuichi Yamamura, Koji Kawai
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Patent number: 7803888Abstract: A novel olefin-based polymer has excellent thermal resistance, as well as excellent balance among various properties. The olefin-based polymer is an olefin-based polymer comprising 50 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties: i) the diad isotacticity is 70% or greater, ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5, and iii) the intrinsic viscosity [?] is 0.5 (dl/g) or greater.Type: GrantFiled: June 9, 2005Date of Patent: September 28, 2010Assignee: Mitsui Chemicals, Inc.Inventors: Nobuo Kawahara, Shinichi Kojoh, Shingo Matsuo, Hideyuki Kaneko, Tomoaki Matsugi, Norio Kashiwa, Munehito Funaya, Naritoshi Hirota, Tooru Tanaka, Toshiyuki Hirose, Nobuhisa Mikawa, Kouichi Kizu, Keiji Okada
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Publication number: 20100190941Abstract: Provided is a transition metal compound novel and useful as a catalyst component for olefin polymerization, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing an olefin polymer using the catalyst for polymerization. The transition metal is characterized by being represented by the following general formula [I]: wherein, R3 is hydrogen, R2 is selected from a hydrocarbon group or a silicon-containing group, R1 and R4 are selected from a hydrocarbon group having 2 to 20 carbon atoms and a silicon-containing group, each of R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14, which is selected from hydrogen, a hydrocarbon group and a silicon-containing group, may be same or different from each other, and adjacent groups from R5 to R14 may be bonded to each other to form a ring.Type: ApplicationFiled: April 2, 2010Publication date: July 29, 2010Inventors: Munehito Funaya, Naritoshi Hirota, Yuichi Yamamura, Koji Kawai
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Patent number: 7678934Abstract: A transition metal compound represented by the following formula (2a):Type: GrantFiled: August 4, 2008Date of Patent: March 16, 2010Assignee: Mitsui Chemicals, Inc.Inventors: Naritoshi Hirota, Hiromu Kaneyoshi, Munehito Funaya, Koji Kawai, Nobuo Kawahara