Patents by Inventor Munirpallam Appadorai Subramanian

Munirpallam Appadorai Subramanian has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20100288967
    Abstract: The present invention provides an indium-doped Co4Sb12 skutterudite composition in which some Co on the cubic lattice structure may be replaced with one or more members of the group consisting of Fe, Ni, Ru, Rh, Pd, Ir and Pt; some Sb on the planar rings may be replaced by one or more members of the group consisting of Si, Ga, Ge and Sn; and a second dopant atom is selected from a member of the group consisting of Ca, Sc, Zn, Sr, Y, Pd, Ag, Cd, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. The composition is useful as a thermoelectric material. In preferred embodiments, the composition has a figure of merit greater than 1.0. The present invention also provides a process for the production of the composition, and thermoelectric devices using the composition.
    Type: Application
    Filed: May 24, 2010
    Publication date: November 18, 2010
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: MUNIRPALLAM APPADORAI SUBRAMANIAN, TAO HE, JAMES J. KRAJEWSKI
  • Patent number: 7745516
    Abstract: Water absorption resistant polyimide/epoxy-based compositions, like pastes (or solutions), are particularly useful to make electronic screen-printable materials and electronic components. A group of hydrophobic epoxies (and soluble polyimides) was discovered to be particularly resistant to moisture absorption. The polyimide/epoxy pastes made with these epoxies (and these polyimides) may optionally contain thermal crosslinking agents, adhesion promoting agents, blocked isocyanates, and other inorganic fillers. The polyimide/epoxy pastes of the present invention can have a glass transition temperature greater than 250° C., a water absorption factor of less than 2%, and a positive solubility measurement.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: June 29, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Thomas Eugene Dueber, John D. Summers, Brian C. Auman, Munirpallam Appadorai Subramanian, Nyrissa S. Rogado
  • Patent number: 7723607
    Abstract: The present invention provides an indium-doped Co4Sb12 skutterudite composition in which some Co on the cubic lattice structure may be replaced with one or more members of the group consisting of Fe, Ni, Ru, Rh, Pd, Ir and Pt; some Sb on the planar rings may be replaced by one or more members of the group consisting of Si, Ga, Ge and Sn; and a second dopant atom is selected from a member of the group consisting of Ca, Sc, Zn, Sr, Y, Pd, Ag, Cd, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. The composition is useful as a thermoelectric material. In preferred embodiments, the composition has a figure of merit greater than 1.0. The present invention also provides a process for the production of the composition, and thermoelectric devices using the composition.
    Type: Grant
    Filed: April 14, 2005
    Date of Patent: May 25, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Munirpallam Appadorai Subramanian, Tao He, James J. Krajewski
  • Patent number: 7504358
    Abstract: A crystalline alpha-chromium oxide where from about 0.05 atom % to about 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are substituted by nickel atoms, and optionally, additional chromium atoms in the alpha-chromium oxide lattice are substituted by trivalent cobalt atoms (provided that the total amount of the nickel atoms and the trivalent cobalt atoms in the alpha-chromium oxide lattice is no more than 6 atom %) is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline substituted alpha-chromium oxide.
    Type: Grant
    Filed: August 21, 2003
    Date of Patent: March 17, 2009
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Velliyur Nott Mallikarjuna Rao, H. David Rosenfeld, Allen C. Sievert, Shekhar Subramoney, Munirpallam Appadorai Subramanian
  • Patent number: 7477131
    Abstract: Provided are compositions containing 20 to 50% by volume of a nitride or carbide of a group IV metal, a polymer, and 1 to 9% by volume of an allotrope of carbon. The compositions are useful in manufacturing resistors with low temperature coefficients of resistivity.
    Type: Grant
    Filed: September 7, 2006
    Date of Patent: January 13, 2009
    Assignee: E.I. Du Pont De Nemours
    Inventors: Nyrissa S. Rogado, Munirpallam Appadorai Subramanian
  • Patent number: 7462217
    Abstract: The present invention relates to a process for the preparation of thermoelectric compositions of the formula InxCO4Sb12 (0<x<1), with a figure of merit greater than 1.0 and a composition made by that process.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: December 9, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Tao He, James J. Krajewski, Munirpallam Appadorai Subramanian
  • Patent number: 7371960
    Abstract: This invention provides novel thermoelectric compounds comprising: a) atomic percent Ytterbium b) between 50 and 74.999 atomic percent Aluminum c) between 0.001 and 25 atomic percent Manganese and a process for their preparation.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: May 13, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Tao He, James J. Krajewski, Munirpallam Appadorai Subramanian
  • Publication number: 20080061273
    Abstract: Provided are compositions containing 20 to 50% by volume of a nitride or carbide of a group IV metal, a polymer, and 1 to 9% by volume of an allotrope of carbon. The compositions are useful in manufacturing resistors with low temperature coefficients of resistivity.
    Type: Application
    Filed: September 7, 2006
    Publication date: March 13, 2008
    Inventors: Nyrissa S. Rogado, Munirpallam Appadorai Subramanian
  • Patent number: 7314842
    Abstract: This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1-xLnxTi1-xMxO3 wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLaxTi1-xFexO3 wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLaxTi1-x/4-3a/4Ala(x-a)/4O3 wherein denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.
    Type: Grant
    Filed: July 21, 2006
    Date of Patent: January 1, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Dong Li, Munirpallam Appadorai Subramanian
  • Patent number: 7217678
    Abstract: A crystalline alpha-chromium oxide where from about 0.05 atom % to about 6 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by trivalent cobalt (Co+3) atoms is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline cobalt-substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline cobalt-substituted alpha-chromium oxide. The method involves (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble cobalt salt and a soluble trivalent chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a cobalt concentration of from about 0.
    Type: Grant
    Filed: August 21, 2003
    Date of Patent: May 15, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Velliyur Nott Mallikarjuna Rao, H. David Rosenfeld, Allen C. Sievert, Shekhar Subramoney, Munirpallam Appadorai Subramanian
  • Patent number: 7094721
    Abstract: This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1?xLnxTi1?xMxO3 wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1?ySry)1?xLaxTi1?xFexO3 wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1?ySry)1?xLaxTi1?x/4?3a/4Ala}(x?a)/4O3 wherein } denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.
    Type: Grant
    Filed: March 24, 2005
    Date of Patent: August 22, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Dong Li, Munirpallam Appadorai Subramanian
  • Patent number: 6916755
    Abstract: This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1-xLnxTi1-xMxO3 wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLaxTi1-xFex O3 wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLax Ti1-x/4 3a/4Ala(x-a)/4O3 wherein denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.
    Type: Grant
    Filed: May 2, 2001
    Date of Patent: July 12, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Dong Li, Munirpallam Appadorai Subramanian
  • Patent number: 6906375
    Abstract: This invention provides compositions of the formula EuCu3M4O12 wherein M is Ge, Ti, Sn or mixtures thereof. These compositions have high dielectric constant and low loss over a frequency range of from 1 kHz to 1 MHz.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: June 14, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Munirpallam Appadorai Subramanian
  • Patent number: 6855670
    Abstract: Compositions having the nominal formula BiaSrbCacCu3Ox wherein a is from about 1 to 3, b is from about ? to 4, c is from about {fraction (3/16)} to 2, x=(1.5 a+b+c+y) where y is from about 2 to 5, with the proviso that “b+c” is from about {fraction (3/2)} to 5, containing a metal oxide phase of the formula Bi2Sr3?zCazCu2O8+w wherein z is from about 0.1 to 0.9 w is greater than zero but less than 1, are superconducting. Processes for manufacturing such compositions and for using them are disclosed.
    Type: Grant
    Filed: May 24, 1990
    Date of Patent: February 15, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jagannatha Gopalakrishnan, Arthur William Sleight, Munirpallam Appadorai Subramanian
  • Publication number: 20040196619
    Abstract: This invention provides compositions of the formula EuCu3M4O12 wherein M is Ge, Ti, Sn or mixtures thereof. These compositions have high dielectric constant and low loss over a frequency range of from 1 kHz to 1 MHz.
    Type: Application
    Filed: November 18, 2003
    Publication date: October 7, 2004
    Inventor: Munirpallam Appadorai Subramanian
  • Publication number: 20040119054
    Abstract: This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1−xLnxTi1−xMxO3 wherein when Ln is La, M is Fe or Cr, when Ln is Sm,M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1−ySry)1−xLaxTi1−xFex O3 wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1−ySry)1−xLax Ti1−x/4−3a/4Ala(x−a)/4O3 wherein denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a.
    Type: Application
    Filed: October 21, 2002
    Publication date: June 24, 2004
    Inventors: Dong Li, Munirpallam Appadorai Subramanian
  • Patent number: 5965284
    Abstract: Scandium-substituted thallium manganese pyrochlore compounds having increased magnetoresistance compared to unsubstituted compounds are disclosed. Such compounds are suitable for use in magnetic read heads and provide the choice of resistivity range.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: October 12, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Munirpallam Appadorai Subramanian
  • Patent number: 5853688
    Abstract: A crystalline lead-containing oxyfluoride of the formula PbMO.sub.2 F wherein M is selected from the group consisting of Ga, Sc, In, Lu, Yb, Tm, Er and Tl.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: December 29, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Munirpallam Appadorai Subramanian