Abstract: Electrolyte formulations for energy storage devices are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Electrolyte formulations as described herein are electrolyte compositions comprising two or more components such as solvents, co-solvents, salts and/or additives. In some embodiments, three or more, four or more, five or more, six or more, seven or more, or eight or more components are included in the electrolyte composition.

Abstract: A nanowire energy storage device such as a nanowire battery or a capacitor having a cathode comprising a plurality of nanowires and an anode comprising a plurality of nanowires interlaced with the plurality of nanowires of the cathode, and embedded in a PMMA gel electrolyte.

Abstract: A nanowire energy storage device such as a nanowire battery or a capacitor having a cathode comprising a plurality of nanowires and an anode comprising a plurality of nanowires interlaced with the plurality of nanowires of the cathode, and embedded in a PMMA gel electrolyte.

Abstract: A method and system for copper coated anode active material may include providing a metal current collector; an active material layer on the current collector, the active material layer comprising at least 50% silicon by weight, a pyrolyzed carbon source; and a layer of metal on the active material layer that increases conductivity of the layer. The surface may be opposite to a surface of the active material layer that is coupled to the current collector. The layer of metal may comprise copper. The silicon may comprise particles ranging in size from 2 to 50 ?m. The metal layer may comprise islands of metal on the silicon particles. The islands of metal may have a thickness of 100 nm or less. The islands of metal may be less than 50 ?m across. A conductivity of the anode active material layer and layer of metal may be less than 2×10?5 ?-cm.

Abstract: A method and system for copper coated anode active material may include providing a metal current collector; an active material layer on the current collector, the active material layer comprising at least 50% silicon by weight, a pyrolyzed carbon source; and a layer of metal on the active material layer that increases conductivity of the layer. The surface may be opposite to a surface of the active material layer that is coupled to the current collector. The layer of metal may comprise copper. The silicon may comprise particles ranging in size from 2 to 50 ?m. The metal layer may comprise islands of metal on the silicon particles. The islands of metal may have a thickness of 100 nm or less. The islands of metal may be less than 50 ?m across. A conductivity of the anode active material layer and layer of metal may be less than 2×10?5 ?-cm.

Abstract: Systems and methods provide for safety of silicon dominant anodes in a battery. The battery may include an anode comprising an anode active material layer on a metal current collector, where the anode active material layer comprises pyrolyzed binder, conductive additives, and 50% or more silicon by weight. The battery may further include a separator, an electrolyte, a cathode, and a solid electrolyte interface between the anode active material layer and the electrolyte, and has a thermal runaway temperature of greater than 260° C. The conductive additives may comprise between 1% and 40% of the active material layer. The anode active material layer may comprise between 20% to 95% silicon. The separator may comprise ceramic-coated polyolefin or polymer-coated polyolefin. The electrolyte may comprise Lithium hexafluorophosphate (LiPF6) and/or lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in one or more electrolyte solvents. The metal current collector may comprise copper.

Abstract: Silicon-dominate battery electrodes, battery cells utilizing the silicon-dominate battery electrodes, and methods of manufacturing are disclosed. Such a battery cell includes a cathode, a separator, an electrolyte, and an anode. The anode comprises a current collector and active material on the current collector. The active material layer includes at least 50% silicon. A ratio of the electrolyte to Ah is over 2 g/Ah.

Abstract: Electrolyte compositions for energy storage devices comprising fluorinated esters/carbonates/aromatic compounds and multiple additive combinations are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte composition comprising one or more of fluorinated ester/carbonate/aromatic compound solvents/co-solvents and multiple additive combinations.

Abstract: A nanowire energy storage device such as a nanowire battery or a capacitor having a cathode comprising a plurality of nanowires and an anode comprising a plurality of nanowires interlaced with the plurality of nanowires of the cathode, and embedded in a PMMA gel electrolyte.

Abstract: A nanowire energy storage device such as a nanowire battery or a capacitor having a cathode comprising a plurality of nanowires and an anode comprising a plurality of nanowires interlaced with the plurality of nanowires of the cathode, and embedded in a PMMA gel electrolyte.

Abstract: A nanowire energy storage device such as a nanowire battery or a capacitor having a cathode comprising a plurality of nanowires and an anode comprising a plurality of nanowires interlaced with the plurality of nanowires of the cathode, and embedded in a PMMA gel electrolyte.