Abstract: A polyaspartate composition can include a reaction product of a diamine and an amine-reactive component. The amine reactive-component can include a diester and an acrylate combined at an equivalent ratio of diester equivalents to acrylate equivalents of from less than 0.9:greater than 0.1 to greater than 0.3:less than 0.7. The diamine and the amine-reactive component can be combined at an equivalent ratio of diamine equivalents to amine-reactive component equivalents of from 1:0.8 to 0.8:1.

Abstract: A polyaspartate composition is provided which comprises a reaction product of a diamine and a diester reacted at a ratio of diamine equivalents to diester equivalents of from 1:0.95 to 1:0.50. The polyaspartate compositions of the invention may be combined with polyisocyanates to produce polyurea compositions, e.g., coatings, adhesives, sealants, composites, castings, and films, which exhibit a faster cure time along with faster development time for physical properties such as hardness and tensile strength.

Abstract: A process of directly coating a metal substrate and curing the coating using radiation sources such as UV radiation having a wavelength of 200 nm and above. Furthermore, compositions of the invention can be used as a tie-coat for coatings that do not bond well directly to various metal substrates.

Abstract: Composition and process for low temperature curing of polyuretdione-polyol compositions in which the polyuretdione is prepared from a polyisocyanate with isocyanate groups and a polyol containing primary hydroxyl groups. The catalyst for the composition and process is an amine catalyst containing the group —N?C—N—, being aprotic, having a pKa greater than 20 and upon addition to the liquid coating composition causing a phase-change of the coating composition from liquid to solid at 25° C. and 1 atm. within one week.

Abstract: Methods of producing an elastomer are disclosed that include (I) applying a composition that includes a urethane (meth)acrylate to a substrate at a thickness of at least 10 mils; (II) exposing the composition ultraviolet radiation to produce a cured film; and (III) removing the film from the substrate. Related compositions are also disclosed.

Abstract: A process of directly coating a metal substrate and curing the coating using radiation sources such as UV radiation having a wavelength of 200 nm and above. Furthermore, compositions of the invention can be used as a tie-coat for coatings that do not bond well directly to various metal substrates.

Abstract: This invention relates to flexible cycloaliphatic diisocyanate trimers and a process for the preparation of these. These flexible products are allophanate-modified, partially trimerized cycloaliphatic diisocyanates and are characterized by a low Tg. More specifically, the Tg of the resultant product ranges from about ?30° C. to about 40° C., after the excess monomer has been removed from the product.

Abstract: A coating composition is provided. The composition comprises as component I, a) a polyaspartic acid ester comprising the reaction product of one more diamines, one or more difunctional acrylate-containing compounds and one or more maleic/fumaric acid esters; b) at least one moisture scavenger; c) at least one deaerator; d) at least one plasticizer; and e) optionally additives; and as component II, one or more polyisocyanates. Methods of making and applying the composition to a substrate are also provided. The coating is particularly suitable for use as a gel coat.

Abstract: Composition and process for low temperature curing of polyuretdione-polyol compositions in which the polyuretdione is prepared from a polyisocyanate with isocyanate groups and a polyol containing primary hydroxyl groups. The catalyst for the composition and process is an amine catalyst containing the group —N?C—N—, being aprotic, having a pKa greater than 20 and upon addition to the liquid coating composition causing a phase-change of the coating composition from liquid to solid at 25° C. and 1 atm. within one week.

Abstract: This invention relates to coating compositions and more particularly to highly productive coating compositions that quickly harden for sanding or buffing by incorporating therein a polyisocyanate adduct mixture into the coating composition as the crosslinking material. Such coatings are particularly useful for refinishing automobiles and trucks.

Abstract: A coating composition is provided. The composition comprises as component I, a) a polyaspartic acid ester comprising the reaction product of one more diamines, one or more difunctional acrylate-containing compounds and one or more maleic/fumaric acid esters; b) at least one moisture scavenger; c) at least one deaerator; d) at least one plasticizer; and e) optionally additives; and as component II, one or more polyisocyanates. Methods of making and applying the composition to a substrate are also provided. The coating is particularly suitable for use as a gel coat.

Abstract: A process of directly coating a metal substrate and curing the coating using radiation sources such as UV radiation having a wavelength of 200 nm and above. Furthermore, compositions of the invention can be used as a tie-coat for coatings that do not bond well directly to various metal substrates.

Abstract: This invention relates to flexible cycloaliphatic diisocyanate trimers and a process for the preparation of these. These flexible products are allophanate-modified, partially trimerized cycloaliphatic diisocyanates and are characterized by a low Tg. More specifically, the Tg of the resultant product ranges from about ?30° C. to about 40° C., after the excess monomer has been removed from the product.

Abstract: The present invention is directed to blocked biuret group-containing polyisocyanate compositions, wherein the blocking agent is of the formula: wherein R1, R2, R3 and R4 may be the same or different and represent a moiety selected from the group consisting of hydrogen, C1-C6-alkyl and C3-C6-cycloalkyl, R5 represents a moiety selected from the group consisting of C1-C10-alkyl and C3-C10-cycloalkyl, and B is a group according to one of the following structural formulas wherein each occurrence of R6, R7, and R8 may be the same or different and represent a moiety selected from the group consisting of C1-C6-alkyl and C3-C6-cycloalkyl and R9 is a moiety selected from the group consisting of hydrogen, C1-C6-alkyl and C3-C6-cycloalkyl.

Abstract: The invention relates to a process for reducing the monomeric aziridine content in a polyaziridine forming reaction mixture by adding to the polyaziridine forming reaction mixture an excess of a carbodiimide scavenger wherein the excess is based on the equivalent ratio of scavenger to monomeric aziridine, and to a product obtained by this process and to a coating composition containing the product obtained by the process.

Abstract: The invention relates to a process for reducing the monomeric aziridine content in a polyaziridine forming reaction mixture by adding to the polyaziridine forming reaction mixture an excess of a carbodiimide scavenger wherein the excess is based on the equivalent ratio of scavenger to monomeric aziridine, and to a product obtained by this process and to a coating composition containing the product obtained by the process.

Abstract: Biuret group-containing polyisocyanates are produced having an isocyanate functionality of at least 4 are prepared by reacting polyisocyanates having a functionality of at least 2.8 with water as the biuretizing agent. Most preferably water is used as the sole biuretizing agent. The preparation is useful as a curing agent in crosslinkable coating compositions. The coating composition can be used as an automotive clearcoat over a conventional pigmented basecoat, or as a basecoat or monocoat or even as a primer or sealer when a suitable amount of pigment is incorporated therein.

Abstract: The present invention relates to moisture-curable compositions containing a mixture of a) a polyisocyanate and b) a polyacrylate resin which has an alkoxysilane group content (calculated as Si, MW 28) of 0.2 to 4.5% by weight, based on the weight of the polyacrylate resin, and contains less than 0.2% by weight of hydroxy groups, based on the weight of the polyacrylate resin, wherein components a) and b) are present in amounts sufficient to provide an equivalent ratio of isocyanate groups to alkoxy groups, which are bound to Si, of 1.0:0.05 to 1.0:2.5. The present invention also relates to coatings, sealants and adhesives prepared from these compositions.

Abstract: The present invention relates to moisture-curable compounds whicha) have an isocyanate group content (calculated as NCO, MW 42) of 2 to 30% by weight and an alkoxysilane group content (calculated as Si, MW 28) of 0.2 to 4.5% by weight,b) optionally contain repeating ethylene oxide units andc) have an equivalent ratio of isocyanate groups to alkoxy groups of 1.0:0.05 to 1.0:2.5,wherein the preceding percentages are based on the weight of the moisture-curable compounds and wherein the alkoxysilane groups are incorporated as the reaction products ofi) a polyisocyanate component having a minimum average functionality of 2.0 and containing at least 50% by weight of polyisocyanate adducts, provided that when the moisture-curable compounds contain ethylene oxide units, the polyisocyanate component has a minimum average functionality of 2.

Abstract: The present invention relates to compounds having an isocyanate group content (calculated as NCO, MW 42) of 0.2 to 20% by weight and an alkoxysilane group content (calculated as Si, MW 28) of 0.2 to 4.5% by weight, wherein the preceding percentages are the weight of the compounds, and containing sufficient chemically incorporated hydrophilic groups to form a stable dispersion in water, wherein the alkoxysilane groups are incorporated as the reaction product ofi) a polyisocyanate component having a minimum average functionality of 2.4 and containing at least 50% by weight of polyisocyanate adducts andii) compounds containing secondary amino groups and alkoxysilane groups.The present invention is also directed to the use of these compounds in admixture with isocyanate-reactive resins in aqueous, two-component coating, adhesive and sealant compositions.