Abstract: The invention relates to a pulverulent composition comprising a powder based on at least one polyaryl ether ketone, said composition having at least a first endothermic peak and a second endothermic peak, the first endothermic peak having a peak temperature strictly greater than 280° C., and the second endothermic peak having a peak temperature equal to a value of 200° C. to 280° C.; the endothermic peaks are measured on a thermogram obtained by differential scanning calorimetry, according to the standard ISO 11357-3: 2018, on first heating, using a temperature ramp of 20° C./minute. The invention also relates to a method for the electromagnetic radiation-mediated layer-by-layer sintering construction of a three-dimensional object from the pulverulent composition, to a method for determining the minimum construction temperature to be used, and also to objects that may be manufactured via this construction process.

Abstract: A method and apparatus for heat treating powders of semi-crystalline or crystallizable polymers. The apparatus includes a heating device for heating the powder to a temperature that is less than the melting temperature of a highest melting crystalline form of the powder, a vessel containing the powder that is exposed to heat produced by the heating device, and a mechanism for moving the vessel to cause the powder within the vessel to move with respect to the vessel.

Abstract: Disclosed is a composition including at least one polymer, wherein the polymer is in the form of a powder, and wherein the polymer includes at least one thermoplastic polymer. The thermoplastic polymer is selected from at least one polyaryletherketone and/or a copolymer and/or a block-copolymer and/or a polymer blend thereof, wherein the composition has a melt volume rate (MVR) of at least 5 cm3/10 min and a process of manufacturing and a use thereof. Also disclosed are a process for the manufacture of a construction element and the construction element thereof.

Abstract: A method for producing a surface coated with a coating having an improved coalescence, the method including: providing a composition comprising from 99.6% to 99.99% by weight of at least one powder of at least one polyarylene ether ketone and 0.01 to 0.4% by weight of a hydrophilic flow agent, the hydrophilic flow agent being hydrophilic silica; depositing the composition onto a surface forming a coated surface; and baking the coated surface to form a film on the surface.

Abstract: A powder of a copolymer with polyamide blocks and polyether blocks. The invention concerns a composition comprising a powder of a copolymer with polyamide blocks and polyether blocks, the copolymer being in particle form with a pulverulent filler content of 0 to 10% by mass and the copolymer having a ratio by mass of the polyamide blocks to the polyether blocks of less than or equal to 0.7, the polyamide blocks having a number-average molar mass of less than or equal to 1000 g/mol; and the composition comprising a flow aid at a content of greater than or equal to 0.3% by mass. The invention also concerns the process for producing this composition, the use of the composition for constructing three-dimensional articles, and the three-dimensional articles manufactured from said composition.

Abstract: A method and apparatus for heat treating powders of semi-crystalline or crystallizable polymers. The apparatus includes a heating device for heating the powder to a temperature that is less than the melting temperature of a highest melting crystalline form of the powder, a vessel containing the powder that is exposed to heat produced by the heating device, and a mechanism for moving the vessel to cause the powder within the vessel to move with respect to the vessel.

Abstract: Process for densification of a poly(arylene ether ketone) (PAEK) powder or of a mixture of poly(arylene ether ketone) (PAEK) powders, the process being mixing the powder or the mixture of powders, in a mixer equipped with a rotary stirrer including at least one blade, for a period of between 30 minutes and 120 minutes, preferably of between 30 and 60 minutes, at a blade-tip speed of between 30 m/s and 70 m/s, preferably of between 40 and 50 m/s.

Abstract: A part including polyetherketoneketone, in which the polyetherketoneketone is at least partially crystalline and in which at least 50% by weight of the crystalline polyetherketoneketone is of form 1. Also a process for the manufacture of such a part, the process including the provision of polyetherketoneketone; the shaping of the polyetherketoneketone and the at least partial crystallization of the polyetherketoneketone in the form 1.

Abstract: A graft copolymer comprising: a core polymer comprising a crosslinked or non-crosslinked polysaccharide, a plurality of primary graft polymers covalently grafted to the core polymer, a plurality of secondary graft polymers covalently grafted to each primary graft polymer, an injectable dermal aesthetic formulation comprising such a graft copolymer and a method of preparing such a graft copolymer.

Abstract: A graft copolymer comprising: a core polymer comprising a crosslinked or non-crosslinked polysaccharide, a plurality of primary graft polymers covalently grafted to the core polymer, a plurality of secondary graft polymers covalently grafted to each primary graft polymer, an injectable dermal aesthetic formulation comprising such a graft copolymer and a method of preparing such a graft copolymer.

Abstract: A method for producing an object by melting a polymer powder in a powder sintering device. For example, a method for producing an object by melting a polymer powder in a powder sintering device under a laser beam, implementing a rheological analysis of the polymers, in order to determine the conditions for producing the object by melting polymer powders.

Abstract: A powder composition of polyarylene ether ketone ketones allowing an excellent castability/coalescence balance suitable for laser sintering. A composition including between 99.6 and 99.99% by weight of at least one powder of at least one polyarylene ether ketone and 0.01 to 0.4% by weight of a hydrophilic flow agent. This hydrophilic flow agent is characterized by an increase in mass (quantity of water absorbed) of more than 0.5% after 5 days of conditioning at a relative humidity of 95%. This increase in mass of the flow agent is determined by means of a Karl Fischer measurement after desorption of the water by a 5-minute treatment at 170° C. This composition is suitable for laser sintering. In particular, it gives the powder an excellent castability/coalescence balance.

Abstract: The invention relates to a process for the heat treatment of poly(arylene ether ketone ketone) powder suitable for laser sintering, and also to the powders resulting from this process.

Abstract: The present invention relates to a composition comprising at least one poly(arylene ether ketone) powder suitable for laser sintering and also to the process which makes it possible to obtain it, minimizing the amount by weight of remaining non-sintered powder after production of the part by sintering.

Abstract: The invention concerns a composition comprising a first polyamide, a second polyamide, different from the first polyamide, and 0.1 to 5% by weight of carbonaceous nanofillers, in which: a) the first polyamide comprises a unit derived from the condensation of meta-xylylene diamine or from a mixture of meta-xylylene diamine and para-xylylene diamine with sebacic acid, said first polyamide having a melting temperature Tf1; and b) the second polyamide has a melting temperature Tf2 higher than or equal to Tf1?40° C. The invention also relates to a method for producing said composition and the use thereof for producing various items.

Abstract: A method for producing an object by melting a polymer powder in a powder sintering device. For example, a method for producing an object by melting a polymer powder in a powder sintering device under a laser beam, implementing a rheological analysis of the polymers, in order to determine the conditions for producing the object by melting polymer powders.

Abstract: Process for densification of a poly(arylene ether ketone) (PAEK) powder or of a mixture of poly(arylene ether ketone) (PAEK) powders, the process being mixing the powder or the mixture of powders, in a mixer equipped with a rotary stirrer including at least one blade, for a period of between 30 minutes and 120 minutes, preferably of between 30 and 60 minutes, at a blade-tip speed of between 30 m/s and 70 m/s, preferably of between 40 and 50 m/s.

Abstract: A powder composition of polyarylene ether ketone ketones allowing an excellent castability/coalescence balance suitable for laser sintering. The present invention concerns a composition comprising between 99.6 and 99.99% by weight of at least one powder of at least one polyarylene ether ketone and 0.01 to 0.4% by weight of a hydrophilic flow agent. This hydrophilic flow agent is characterised by an increase in mass (quantity of water absorbed) of more than 0.5% after 5 days of conditioning at a relative humidity of 95%. This increase in mass of the flow agent is determined by means of a Karl Fischer measurement after desorption of the water by a 5-minute treatment at 170° C. This composition is suitable for laser sintering. In particular, it gives the powder an excellent castability/coalescence balance.

Abstract: The invention concerns a composition comprising a first polyamide, a second polyamide, different from the first polyamide, and 0.1 to 5% by weight of carbonaceous nanofillers, in which: a) the first polyamide comprises a unit derived from the condensation of meta-xylylene diamine or from a mixture of meta-xylylene diamine and para-xylylene diamine with sebacic acid, said first polyamide having a melting temperature Tf1; and b) the second polyamide has a melting temperature Tf2 higher than or equal to Tf1?40° C. The invention also relates to a method for producing said composition and the use thereof for producing various items.

Abstract: The invention relates to a process for the heat treatment of poly(arylene ether ketone ketone) powder suitable for laser sintering, and also to the powders resulting from this process.