Patents by Inventor Naohiko Suemura
Naohiko Suemura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11961636Abstract: An insulating composition containing silica particles, a resin, and a curing agent, wherein: when an aqueous solution of the silica particles having an SiO2 concentration of 3.8% by mass is heated at 121° C. for 20 hours, the amount of Na ions eluted from the silica particles is 40 ppm/SiO2 or less, especially, wherein the amount of Na ions eluted from the silica particles after the heating may be 5-38 ppm/SiO2, and, the silica particles may contain a polyvalent metal oxide so the ratio by mole of a polyvalent metal M to Si is 0.001-0.02; the mass ratio of Na2O/SiO2 in the silica particles may be 700-1,300 ppm; and the silica particles may have, on the surfaces thereof, a layer having a thickness of 0.1-1.5 nm and an Na2O/SiO2 mass ratio of 10-400 ppm, and may have an average particle diameter of 5-40 nm.Type: GrantFiled: September 7, 2018Date of Patent: April 16, 2024Assignee: NISSAN CHEMICAL CORPORATIONInventors: Naohiko Suemura, Masatoshi Sugisawa
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Patent number: 11708273Abstract: A silica sol dispersed in a nitrogen-containing solvent and a silica-containing resin composition containing a nitrogen atom-containing polymer. A silica sol including silica particles containing aluminum atoms and having an average primary particle diameter of 5 to 100 nm, the silica particles being dispersed in a nitrogen-containing solvent, wherein the aluminum atoms are bonded to the surfaces of the silica particles in an amount in terms of Al2O3 of 800 to 10,000 ppm/SiO2. The silica particles are bonded to a silane compound or a hydrolysate of the silane compound. The nitrogen-containing solvent is an amide solvent. The nitrogen-containing solvent is dimethylacetamide, dimethylformamide, N-methylpyrrolidone, or N-ethylpyrrolidone. The insulating resin composition includes the silica sol and a nitrogen-containing polymer. The nitrogen-containing polymer is polyimide, polyamide, polyamic acid, polyamideimide, polyetherimide, or polyesterimide.Type: GrantFiled: November 4, 2021Date of Patent: July 25, 2023Assignee: NISSAN CHEMICAL CORPORATIONInventors: Kazuya Kuroiwa, Hikaru Onishi, Yuki Sugawara, Naohiko Suemura
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Publication number: 20230045117Abstract: A silica sol dispersed in a nitrogen-containing solvent and a silica-containing resin composition containing a nitrogen atom-containing polymer. A silica sol including silica particles containing aluminum atoms and having an average primary particle diameter of 5 to 100 nm, the silica particles being dispersed in a nitrogen-containing solvent, wherein the aluminum atoms are bonded to the surfaces of the silica particles in an amount in terms of Al2O3 of 800 to 10,000 ppm/SiO2. The silica particles are bonded to a silane compound or a hydrolysate of the silane compound. The nitrogen-containing solvent is an amide solvent. The nitrogen-containing solvent is dimethylacetamide, dimethylformamide, N-methylpyrrolidone, or N-ethylpyrrolidone. The insulating resin composition includes the silica sol and a nitrogen-containing polymer. The nitrogen-containing polymer is polyimide, polyamide, polyamic acid, polyamideimide, polyetherimide, or polyesterimide.Type: ApplicationFiled: November 4, 2021Publication date: February 9, 2023Applicant: NISSAN CHEMICAL CORPORATIONInventors: Kazuya KUROIWA, Hikaru ONISHI, Yuki SUGAWARA, Naohiko SUEMURA
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Patent number: 11549019Abstract: A sol of inorganic oxide particles is stably dispersed in a hydrophilic organic solvent containing a hydrocarbon such as a paraffinic hydrocarbon or a naphthenic hydrocarbon. The sol contains a dispersion medium containing an organic solvent containing a C6-18 paraffinic hydrocarbon, a C6-18 naphthenic hydrocarbon, or a mixture of these, a C4-8 alcohol having a carbon chain with a carbon-carbon bond in the molecule in an amount of 0.1 to 5% by mass in the entire dispersion medium, and inorganic oxide particles having an average particle diameter of 5 to 200 nm as measured by dynamic light scattering as a dispersoid, wherein the inorganic oxide particles contain a C1-3 alkyl group bonded to a silicon atom and a C4-18 alkyl group. The paraffinic hydrocarbon is a normal paraffinic hydrocarbon or an isoparaffinic hydrocarbon. The naphthenic hydrocarbon is a saturated aliphatic cyclic hydrocarbon substitutable with a C1-10 alkyl group.Type: GrantFiled: July 6, 2021Date of Patent: January 10, 2023Assignee: NISSAN CHEMICAL CORPORATIONInventors: Tomoya Maeta, Naohiko Suemura, Keiko Yoshitake
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Publication number: 20220332589Abstract: A sol of inorganic oxide particles is stably dispersed in a hydrophilic organic solvent containing a hydrocarbon such as a paraffinic hydrocarbon or a naphthenic hydrocarbon. The sol contains a dispersion medium containing an organic solvent containing a C6-18 paraffinic hydrocarbon, a C6-18 naphthenic hydrocarbon, or a mixture of these, a C4-8 alcohol having a carbon chain with a carbon-carbon bond in the molecule in an amount of 0.1 to 5% by mass in the entire dispersion medium, and inorganic oxide particles having an average particle diameter of 5 to 200 nm as measured by dynamic light scattering as a dispersoid, wherein the inorganic oxide particles contain a C1-3 alkyl group bonded to a silicon atom and a C4-18 alkyl group. The paraffinic hydrocarbon is a normal paraffinic hydrocarbon or an isoparaffinic hydrocarbon. The naphthenic hydrocarbon is a saturated aliphatic cyclic hydrocarbon substitutable with a C1-10 alkyl group.Type: ApplicationFiled: July 6, 2021Publication date: October 20, 2022Applicant: NISSAN CHEMICAL CORPORATIONInventors: Tomoya MAETA, Naohiko SUEMURA, Keiko YOSHITAKE
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Publication number: 20220033268Abstract: Provided is an inorganic oxide dispersion (sol) in which inorganic oxide particles are dispersed in silicone oil.Type: ApplicationFiled: February 13, 2020Publication date: February 3, 2022Applicant: NISSAN CHEMICAL CORPORATIONInventors: Naohiko SUEMURA, Tomoya MAETA
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Patent number: 11177050Abstract: A method for preventing occurrence of creeping electrical discharge at a resin surface, the method being characterized by including dispersing nanosized inorganic fine particles in a resin, thereby preventing occurrence of creeping electrical discharge at the surface of a cured product of the resin.Type: GrantFiled: June 28, 2017Date of Patent: November 16, 2021Assignees: NISSAN CHEMICAL CORPORATION, KYUSHU INSTITUTE OF TECHNOLOGYInventors: Naohiko Suemura, Tomohisa Ishida, Masahiro Kozako, Masayuki Hikita, Kyunghoon Jang, Takao Akahoshi
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Patent number: 11168201Abstract: A silica-blended resin varnish contains a silica sol with a high dispersibility that is dispersed in a ketone organic solvent, in a nitrogen atom-containing polymer. The particles have an average size of 5 to 100 nm and have a carbon-carbon unsaturated bond-containing organic group and an alkoxy group bonded to surfaces thereof. The carbon-carbon unsaturated bond-containing organic group is bonded at 0.5 to 2.0 groups per unit area (nm2) of the particle surfaces. The alkoxy group is bonded at 0.1 to 2.0 groups per unit area (nm2) of the particle surfaces. The molar ratio of {(the carbon-carbon unsaturated bond-containing organic group)/(the alkoxy group)} is 0.5 to 5.0. The carbon-carbon unsaturated bond-containing organic group may be a phenyl group-containing organic group or a (meth)acryloyl group-containing organic group.Type: GrantFiled: May 13, 2020Date of Patent: November 9, 2021Assignee: NISSAN CHEMICAL CORPORATIONInventors: Kazuya Kuroiwa, Naohiko Suemura, Masatoshi Sugisawa
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Publication number: 20210309834Abstract: A silica-blended resin varnish contains a silica sol with a high dispersibility that is dispersed in a ketone organic solvent, in a nitrogen atom-containing polymer. The particles have an average size of 5 to 100 nm and have a carbon-carbon unsaturated bond-containing organic group and an alkoxy group bonded to surfaces thereof. The carbon-carbon unsaturated bond-containing organic group is bonded at 0.5 to 2.0 groups per unit area (nm2) of the particle surfaces. The alkoxy group is bonded at 0.1 to 2.0 groups per unit area (nm2) of the particle surfaces. The molar ratio of {(the carbon-carbon unsaturated bond-containing organic group)/(the alkoxy group)} is 0.5 to 5.0. The carbon-carbon unsaturated bond-containing organic group may be a phenyl group-containing organic group or a (meth)acryloyl group-containing organic group.Type: ApplicationFiled: May 13, 2020Publication date: October 7, 2021Applicant: NISSAN CHEMICAL CORPORATIONInventors: Kazuya KUROIWA, Naohiko SUEMURA, Masatoshi SUGISAWA
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Publication number: 20200286644Abstract: An insulating composition containing silica particles, a resin, and a curing agent, wherein: when an aqueous solution of the silica particles having an SiO2 concentration of 3.8% by mass is heated at 121° C. for 20 hours, the amount of Na ions eluted from the silica particles is 40 ppm/SiO2 or less, especially, wherein the amount of Na ions eluted from the silica particles after the heating may be 5-38 ppm/SiO2, and, the silica particles may contain a polyvalent metal oxide so the ratio by mole of a polyvalent metal M to Si is 0.001-0.02; the mass ratio of Na2O/SiO2 in the silica particles may be 700-1,300 ppm; and the silica particles may have, on the surfaces thereof, a layer having a thickness of 0.1-1.5 nm and an Na2O/SiO2 mass ratio of 10-400 ppm, and may have an average particle diameter of 5-40 nm.Type: ApplicationFiled: September 7, 2018Publication date: September 10, 2020Applicant: NISSAN CHEMICAL CORPORATIONInventors: Naohiko SUEMURA, Masatoshi SUGISAWA
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Publication number: 20190148031Abstract: A method for preventing occurrence of creeping electrical discharge at a resin surface, the method being characterized by including dispersing nanosized inorganic fine particles in a resin, thereby preventing occurrence of creeping electrical discharge at the surface of a cured product of the resin.Type: ApplicationFiled: June 28, 2017Publication date: May 16, 2019Applicants: NISSAN CHEMICAL CORPORATION, KYUSHU INSTITUTE OF TECHNOLOGYInventors: Naohiko SUEMURA, Tomohisa ISHIDA, Masahiro KOZAKO, Masayuki HIKITA, Kyunghoon JANG, Takao AKAHOSHI
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Patent number: 10239758Abstract: A silica sol which has excellent moisture absorption resistance and stability as well as high purity and which does not cause coloring of a solvent or a resin to which the silica sol has been applied. The silica sol contains high-purity silica particles, water and/or a liquid organic medium serving as a dispersion medium, and an organic base compound, the silica particles being dispersed in the dispersion medium, wherein the silica particles satisfy the following requirements (a) to (c): (a) the silica particles have a specific surface area, as determined through a nitrogen absorption method, of 20 to 500 m2/g; (b) the silica particles have a moisture absorption amount per specific surface area thereof of 0.5 mg/m2 or less; and (c) the organic base compound is not substantially contained in the inside thereof.Type: GrantFiled: June 5, 2014Date of Patent: March 26, 2019Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Keiko Yoshitake, Naohiko Suemura, Megumi Shimada, Ichitaro Kikunaga
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Patent number: 9969867Abstract: The silica sol of the invention contains silica particles having a mean primary particle size of 20 to 100 nm and which has a silica particle size/mean primary particle size ratio, determined through dynamic light scattering, of 3.0 or less, wherein the silica particles are surface-treated with an organic silane compound and have an ?-ray emission rate of 0.005 counts/cm2·hr or less and a moisture absorption coefficient, determined after allowing the silica particles to stand for 48 hours at 23° C. and a relative humidity of 50 RH %, of 0.5 mass % or lower.Type: GrantFiled: May 14, 2014Date of Patent: May 15, 2018Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Naohiko Suemura, Megumi Shimada, Ichitaro Kikunaga
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Patent number: 9527749Abstract: There is provided colloidal silica particles comprising at least one polyvalent metal element M selected from a group consisting of iron, aluminum, zinc, zirconium, titanium, tin, and lead in an average content of 0.001 to 0.02 in terms of an M/Si molar ratio, and having an average primary particle diameter of 5 to 40 nm, wherein the content of the polyvalent metal element M present in an outermost layer of the colloidal particles is 0 to 0.003 atom per square nanometer (nm2) of a surface area of the colloidal particles; and a silica sol that the colloidal silica particles are dispersed in an organic solvent, a silica sol that the colloidal silica particles are dispersed in a polymerizable compound, and a silica sol that the colloidal silica particles are dispersed in a dicarboxylic anhydride.Type: GrantFiled: January 29, 2016Date of Patent: December 27, 2016Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Naohiko Suemura, Keiko Yoshitake, Toshiaki Takeyama
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Patent number: 9376322Abstract: There is provided colloidal silica particles comprising at least one polyvalent metal element M selected from a group consisting of iron, aluminum, zinc, zirconium, titanium, tin, and lead in an average content of 0.001 to 0.02 in terms of an M/Si molar ratio, and having an average primary particle diameter of 5 to 40 nm, wherein the content of the polyvalent metal element M present in an outermost layer of the colloidal particles is 0 to 0.003 atom per square nanometer (nm2) of a surface area of the colloidal particles; and a silica sol that the colloidal silica particles are dispersed in an organic solvent, a silica sol that the colloidal silica particles are dispersed in a polymerizable compound, and a silica sol that the colloidal silica particles are dispersed in a dicarboxylic anhydride.Type: GrantFiled: September 11, 2015Date of Patent: June 28, 2016Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Naohiko Suemura, Keiko Yoshitake, Toshiaki Takeyama
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Publication number: 20160145110Abstract: There is provided colloidal silica particles comprising at least one polyvalent metal element M selected from a group consisting of iron, aluminum, zinc, zirconium, titanium, tin, and lead in an average content of 0.001 to 0.02 in terms of an M/Si molar ratio, and having an average primary particle diameter of 5 to 40 nm, wherein the content of the polyvalent metal element M present in an outermost layer of the colloidal particles is 0 to 0.003 atom per square nanometer (nm2) of a surface area of the colloidal particles; and a silica sol that the colloidal silica particles are dispersed in an organic solvent, a silica sol that the colloidal silica particles are dispersed in a polymerizable compound, and a silica sol that the colloidal silica particles are dispersed in a dicarboxylic anhydride.Type: ApplicationFiled: January 29, 2016Publication date: May 26, 2016Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Naohiko SUEMURA, Keiko YOSHITAKE, Toshiaki TAKEYAMA
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Publication number: 20160130152Abstract: A silica sol which has excellent moisture absorption resistance and stability as well as high purity and which does not cause coloring of a solvent or a resin to which the silica sol has been applied. The silica sol contains high-purity silica particles, water and/or a liquid organic medium serving as a dispersion medium, and an organic base compound, the silica particles being dispersed in the dispersion medium, wherein the silica particles satisfy the following requirements (a) to (c): (a) the silica particles have a specific surface area, as determined through a nitrogen absorption method, of 20 to 500 m2/g; (b) the silica particles have a moisture absorption amount per specific surface area thereof of 0.5 mg/m2 or less; and (c) the organic base compound is not substantially contained in the inside thereof.Type: ApplicationFiled: June 5, 2014Publication date: May 12, 2016Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Keiko YOSHITAKE, Naohiko SUEMURA, Megumi SHIMADA, Ichitaro KIKUNAGA
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Patent number: 9284197Abstract: There is provided colloidal silica particles comprising at least one polyvalent metal element M selected from a group consisting of iron, aluminum, zinc, zirconium, titanium, tin, and lead in an average content of 0.001 to 0.02 in terms of an M/Si molar ratio, and having an average primary particle diameter of 5 to 40 nm, wherein the content of the polyvalent metal element M present in an outermost layer of the colloidal particles is 0 to 0.003 atom per square nanometer (nm2) of a surface area of the colloidal particles; and a silica sol that the colloidal silica particles are dispersed in an organic solvent, a silica sol that the colloidal silica particles are dispersed in a polymerizable compound, and a silica sol that the colloidal silica particles are dispersed in a dicarboxylic anhydride.Type: GrantFiled: February 12, 2009Date of Patent: March 15, 2016Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Naohiko Suemura, Keiko Yoshitake, Toshiaki Takeyama
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Publication number: 20160068664Abstract: The silica sol of the invention contains silica particles having a mean primary particle size of 20 to 100 nm and which has a silica particle size/mean primary particle size ratio, determined through dynamic light scattering, of 3.0 or less, wherein the silica particles are surface-treated with an organic silane compound and have an ?-ray emission rate of 0.005 counts/cm2·hr or less and a moisture absorption coefficient, determined after allowing the silica particles to stand for 48 hours at 23° C. and a relative humidity of 50 RH %, of 0.5 mass % or lower.Type: ApplicationFiled: May 14, 2014Publication date: March 10, 2016Inventors: Naohiko SUEMURA, Megumi SHIMADA, Ichitaro KIKUNAGA
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Publication number: 20150376018Abstract: There is provided colloidal silica particles comprising at least one polyvalent metal element M selected from a group consisting of iron, aluminum, zinc, zirconium, titanium, tin, and lead in an average content of 0.001 to 0.02 in terms of an M/Si molar ratio, and having an average primary particle diameter of 5 to 40 nm, wherein the content of the polyvalent metal element M present in an outermost layer of the colloidal particles is 0 to 0.003 atom per square nanometer (nm2) of a surface area of the colloidal particles; and a silica sol that the colloidal silica particles are dispersed in an organic solvent, a silica sol that the colloidal silica particles are dispersed in a polymerizable compound, and a silica sol that the colloidal silica particles are dispersed in a dicarboxylic anhydride.Type: ApplicationFiled: September 11, 2015Publication date: December 31, 2015Inventors: Naohiko SUEMURA, Keiko YOSHITAKE, Toshiaki TAKEYAMA