Patents by Inventor Naozumi SHIRAIWA
Naozumi SHIRAIWA has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230322981Abstract: An object of the present invention is to provide a cured product which is suitable as a material for a layer of low refractive index in a multilayer diffractive optical element, can exhibit a desired chromatic aberration reducing effect over a near-infrared wavelength region to a shortwave infrared wavelength region in a case of being used in the multilayer diffractive optical element, and can exhibit high transmittance in this wavelength range; a curable resin composition suitable for obtaining this cured product; and a diffractive optical element and a multilayer diffractive optical element including this cured product. Provided are a curable resin composition which includes oxide nanoparticles including indium and cerium, a monofunctional or higher functional (meth)acrylate compound, and a dispersant; a cured product formed of the curable resin composition; a diffractive optical element and a multilayer diffractive optical element; and oxide nanoparticles used in this composition.Type: ApplicationFiled: December 29, 2022Publication date: October 12, 2023Applicant: FUJIFILM CorporationInventors: Masahiro TAKATA, Masashi ONO, Naozumi SHIRAIWA
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Publication number: 20230212136Abstract: Provided are a curable resin composition including a near-ultraviolet light-absorbing organic compound, indium tin oxide particles, and a polymer having a constitutional unit represented by General Formula (P) and having an acidic group at one terminal, in which the near-ultraviolet light-absorbing organic compound is a compound that has a maximal value at 300 to 400 nm in an absorption spectrum in a wavelength region of 300 to 800 nm and does not substantially absorb light at a wavelength of 410 to 800 nm; a cured product formed of the curable resin composition; a diffractive optical element; and a multilayer diffractive optical element. ArP represents an aryl group and LP and RP1 represent a specific group.Type: ApplicationFiled: December 29, 2022Publication date: July 6, 2023Applicant: FUJIFILM CorporationInventors: Kosuke CHIBA, Naozumi SHIRAIWA, Takafumi NAKAYAMA, Naoyuki MOROOKA
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Publication number: 20230096868Abstract: A curable resin composition for a lens, including a coloring agent A having a maximal absorption at a wavelength of 520 to 620 nm, in which a wavelength dispersion WD of a cured product of the composition, which is calculated by the following expression (X), is 2.0×10?5 or more; a cured product formed of the curable resin composition for a lens; a diffractive optical element; and a multilayer diffractive optical element. WD=(nC?n(1129))/(1129?656)??Expression (X) In the expression, nC represents a refractive index at a wavelength of 656 nm and n(1129) represents a refractive index at a wavelength of 1129 nm.Type: ApplicationFiled: August 17, 2022Publication date: March 30, 2023Applicant: FUJIFILM CorporationInventors: Naozumi SHIRAIWA, Naoyuki MOROOKA, Daisuke SASAKI
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Publication number: 20220403245Abstract: Provided are a cured product of a curable composition including a compound represented by General Formula (1), in which a birefringence ?n at a wavelength of 587 nm is 0.00??n?0.01; an optical member; a lens; a compound represented by General Formula (1); a curable resin composition containing the compound; a cured product; a diffractive optical element; and a multilayer diffractive optical element. Pol1-Spa-L1-Ar-L2-Spb-Pol2??Genera Formula (1) Ar represents an aromatic ring group represented by a specific formula, L1 and L2 represent —O—, Spa and Spb represent a linking group having the shortest atom number of 11 or more and linking Pol and L, Pol1 and Pol2 represent a polymerizable group, and in Spa and Spb, a linking portion to L1 or L2 is —CH2— and a linking portion to Pol1 or Pol2 is a carbon atom.Type: ApplicationFiled: August 4, 2022Publication date: December 22, 2022Applicant: FUJIFILM CorporationInventors: Naozumi SHIRAIWA, Naoyuki MOROOKA
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Patent number: 11518916Abstract: According to the present invention, a lens adhesive including a compound represented by General Formula 1 is provided. Pol1-Sp1-L1-Ar-L2-Sp2-Pol2??(General Formula 1) In the formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. In the formula, Z1 and Z2 each represent a hydrogen atom, a methyl group, and the like; A1 and A2 each represent —S— and the like; X represents C(Rz)2 and the like (where Rz is a substituent, and two Rz's may form a ring); L1 and L2 each represent a single bond, —O—, —OC(?O)—, —OC(?O)O—, —OC(?O)NH—, and the like; Sp1 and Sp2 each represent a single bond or a linking group such as a linear alkylene group; Pol1 and Pol2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group. Using the lens adhesive, it is possible to provide a cemented lens that is unlikely to deteriorate due to light, and an imaging module having high durability.Type: GrantFiled: June 25, 2020Date of Patent: December 6, 2022Assignee: FUJIFILM CorporationInventors: Takafumi Nakayama, Naozumi Shiraiwa, Naoyuki Morooka
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Publication number: 20220298348Abstract: Provide are a curable resin composition containing ITO particles, in which a cured product obtained from the curable resin composition can exhibit high transmittance over a visible light to shortwave infrared wavelength region while maintaining a wavelength dependence of a desired refractive index; a cured product formed of the curable resin composition; and a diffractive optical element and a multilayer diffractive optical element. A curable resin composition includes particles which have a core-shell structure, in which a core portion is composed of indium tin oxide, a monofunctional or higher (meth)acrylate compound, and a dispersant; a cured product formed of the curable resin composition; and a diffractive optical element and a multilayer diffractive optical element.Type: ApplicationFiled: February 9, 2022Publication date: September 22, 2022Applicant: FUJIFILM CorporationInventors: Masahiro TAKATA, Masashi ONO, Naozumi SHIRAIWA
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Patent number: 11396613Abstract: The present invention provides a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence ?n (587 nm) is 0.00??n (587 nm)?0.01. Pol1-Sp1-L1-Ar-L2-Sp2-Pol2??(General Formula 1) In the formula, Ar represents a divalent group containing a ring structure selected from the group consisting of a quinoxaline ring and a quinazoline ring; L1 and L2 each represent a single bond, —O—, —OC(?O)—, —OC(?O)O—, —OC(?O)NH—, and the like; Sp1 and Sp2 each represent a single bond or a divalent linking group; Pol1 and Pol2 each represent a hydrogen atom or a polymerizable group; and the compound represented by General Formula 1 has at least one polymerizable group. The cured product of the present invention has a small Abbe number (?d) and a large partial dispersion ratio (?g, F), and is therefore useful for production of optical members.Type: GrantFiled: August 31, 2020Date of Patent: July 26, 2022Assignee: FUJIFILM CorporationInventors: Naozumi Shiraiwa, Naoyuki Morooka
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Patent number: 11377545Abstract: The present invention provides a curable resin composition including a bifunctional or more (meth)acrylate compound, indium tin oxide particles, and an acidic polymer, in which the acidic polymer has a moiety including a carboxyl group at a polymer skeleton of a (meth)acrylate compound and at any one of terminals of the polymer skeleton of a (meth)acrylate compound, and an acid value of the acidic polymer is 2.0 mgKOH/g or more and less than 100 mgKOH/g. The curable resin composition of the present invention provides a transparent cured product, hardly causes bubbles to be mixed in a case of applying the curable resin composition to a mold so as to form a lattice-shaped cured product, and also has a good peeled surface shape from the mold after curing. The present invention also provides a diffractive optical element including a surface having a diffraction grating shape and formed of the cured product of the curable resin composition.Type: GrantFiled: September 14, 2020Date of Patent: July 5, 2022Assignee: FUJIFILM CorporationInventors: Takayasu Nagai, Naozumi Shiraiwa, Takafumi Nakayama, Naoyuki Morooka, Masahiro Takata, Masanori Fujiwara
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Patent number: 11208596Abstract: The present invention is to provide an optical film having optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention is an optical film having at least an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound and a polymerization initiator, and an extrapolated glass transition starting temperature of the optically anisotropic layer is 70° C. or higher.Type: GrantFiled: May 11, 2020Date of Patent: December 28, 2021Assignee: FUJIFILM CorporationInventors: Takahiro Ohno, Makoto Ishiguro, Yoshiaki Hisakado, Hiroshi Sato, Keita Takahashi, Naozumi Shiraiwa, Taiji Katsumata, Hiroshi Matsuyama
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Publication number: 20210395418Abstract: The present invention provides a resin composition suitable for producing a diffractive optical element, the resin composition including an indium tin oxide particle and a near-ultraviolet light-absorbing organic compound having a maximum value of an absorbance at 340 nm to 400 nm in an absorption spectrum in a wavelength region of 300 nm to 780 nm and exhibiting substantially no light absorption at a wavelength of 410 to 800 nm.Type: ApplicationFiled: August 6, 2021Publication date: December 23, 2021Applicant: FUJIFILM CorporationInventors: Naozumi SHIRAIWA, Takayasu Nagai, Naoyuki Morooka
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Patent number: 11078180Abstract: According to the present invention, a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence ?n (587 nm) is 0.00??n (587 nm)?0.01, is provided, and this cured product is suitable for manufacturing an optical member. Pol1-Sp1-L1-Ar-L2-Sp2-Pol2??(General Formula 1) In formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. In formula, Z1 and Z2 each represent a hydrogen atom, a methyl group, and the like; A1 and A2 each represent —S— and the like; X represents C(Rz)2 and the like (where Rz is a substituent, and two Rz's may form a ring); L1 and L2 each represent a single bond, —O—, —OC(?O)—, —OC(?O)O—, —OC(?O)NH—, and the like; Sp1 and Sp2 each represent a single bond or a divalent linking group; Pol1 and Pol2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group.Type: GrantFiled: February 27, 2020Date of Patent: August 3, 2021Assignee: FUJIFILM CorporationInventors: Naoyuki Morooka, Naozumi Shiraiwa
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Publication number: 20210017315Abstract: The present invention provides a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence ?n (587 nm) is 0.00??n (587 nm)?0.01. Pol1-Sp1-L1-Ar-L2-Sp2-Pol2??(General Formula 1) In the formula, Ar represents a divalent group containing a ring structure selected from the group consisting of a quinoxaline ring and a quinazoline ring; L1 and L2 each represent a single bond, —O—, —OC(?O)—, —OC(?O)O—, —OC(?O)NH—, and the like; Sp1 and Sp2 each represent a single bond or a divalent linking group; Pol1 and Pol2 each represent a hydrogen atom or a polymerizable group; and the compound represented by General Formula 1 has at least one polymerizable group. The cured product of the present invention has a small Abbe number (?d) and a large partial dispersion ratio (?g, F), and is therefore useful for production of optical members.Type: ApplicationFiled: August 31, 2020Publication date: January 21, 2021Applicant: FUJIFILM CorporationInventors: Naozumi Shiraiwa, Naoyuki Morooka
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Publication number: 20200407546Abstract: The present invention provides a curable resin composition including a bifunctional or more (meth)acrylate compound, indium tin oxide particles, and an acidic polymer, in which the acidic polymer has a moiety including a carboxyl group at a polymer skeleton of a (meth)acrylate compound and at any one of terminals of the polymer skeleton of a (meth)acrylate compound, and an acid value of the acidic polymer is 2.0 mgKOH/g or more and less than 100 mgKOH/g. The curable resin composition of the present invention provides a transparent cured product, hardly causes bubbles to be mixed in a case of applying the curable resin composition to a mold so as to form a lattice-shaped cured product, and also has a good peeled surface shape from the mold after curing. The present invention also provides a diffractive optical element including a surface having a diffraction grating shape and formed of the cured product of the curable resin composition.Type: ApplicationFiled: September 14, 2020Publication date: December 31, 2020Applicant: FUJIFILM CorporationInventors: Takayasu NAGAI, Naozumi SHIRAIWA, Takafumi NAKAYAMA, Naoyuki MOROOKA, Masahiro TAKATA, Masanori FUJIWARA
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Publication number: 20200325367Abstract: According to the present invention, a lens adhesive including a compound represented by General Formula 1 is provided. Pol1-Sp1-L1-Ar-L2-Sp2-Pol2??(General Formula 1) In the formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. In the formula, Z1 and Z2 each represent a hydrogen atom, a methyl group, and the like; A1 and A2 each represent —S— and the like; X represents C(Rz)2 and the like (where Rz is a substituent, and two Rz's may form a ring); L1 and L2 each represent a single bond, —O—, —OC(?O)—, —OC(?O)O—, —OC(?O)NH—, and the like; Sp1 and Sp2 each represent a single bond or a linking group such as a linear alkylene group; Pol1 and Pol2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group. Using the lens adhesive, it is possible to provide a cemented lens that is unlikely to deteriorate due to light, and an imaging module having high durability.Type: ApplicationFiled: June 25, 2020Publication date: October 15, 2020Applicant: FUJIFILM CorporationInventors: Takafumi NAKAYAMA, Naozumi SHIRAIWA, Naoyuki MOROOKA
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Patent number: 10782567Abstract: An object of the present invention is to provide an optical film having an optically-anisotropic layer having excellent durability, a polarizing plate and an image display device in which the optical film is used, a polymerizable compound used in the optical film, and a method for manufacturing a 1,4-cyclohexanedicarboxylic acid monoaryl ester. The optical film of the present invention is an optical film having at least an optically-anisotropic layer, in which the optically-anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a polymerizable compound which has a specific structure, a liquid crystal compound which has a specific structure, and a polymerization initiator.Type: GrantFiled: May 21, 2018Date of Patent: September 22, 2020Assignee: FUJIFILM CorporationInventors: Keita Takahashi, Hiroshi Matsuyama, Naozumi Shiraiwa, Taiji Katsumata, Yuuta Fujino, Hiroshi Sato, Kiyoshi Takeuchi, Hiroyuki Hagio, Aiko Yoshida, Hiroaki Nakatsugawa
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Publication number: 20200270524Abstract: The present invention is to provide an optical film having optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention is an optical film having at least an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound and a polymerization initiator, and an extrapolated glass transition starting temperature of the optically anisotropic layer is 70° C. or higher.Type: ApplicationFiled: May 11, 2020Publication date: August 27, 2020Applicant: FUJIFILM CorporationInventors: Takahiro OHNO, Makoto ISHIGURO, Yoshiaki HISAKADO, Hiroshi SATO, Keita TAKAHASHI, Naozumi SHIRAIWA, Taiji KATSUMATA, Hiroshi MATSUYAMA
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Publication number: 20200199095Abstract: According to the present invention, a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence ?n (587 nm) is 0.00??n (587 nm)?0.01, is provided, and this cured product is suitable for manufacturing an optical member. Pol1-Sp1-L1-Ar-L2-Sp2-Pol2??(General Formula 1) In formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. In formula, Z1 and Z2 each represent a hydrogen atom, a methyl group, and the like; A1 and A2 each represent —S— and the like; X represents C(Rz)2 and the like (where Rz is a substituent, and two Rz's may form a ring); L1 and L2 each represent a single bond, —O—, —OC(?O)—, —OC(?O)O—, —OC(?O)NH—, and the like; Sp1 and Sp2 each represent a single bond or a divalent linking group; Pol1 and Pol2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group.Type: ApplicationFiled: February 27, 2020Publication date: June 25, 2020Applicant: FUJIFILM CorporationInventors: Naoyuki MOROOKA, Naozumi SHIRAIWA
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Patent number: 10689575Abstract: The present invention is to provide an optical film having optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention is an optical film having at least an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound and a polymerization initiator, and an extrapolated glass transition starting temperature of the optically anisotropic layer is 70° C. or higher.Type: GrantFiled: November 29, 2017Date of Patent: June 23, 2020Assignee: FUJIFILM CorporationInventors: Takahiro Ohno, Makoto Ishiguro, Yoshiaki Hisakado, Hiroshi Sato, Keita Takahashi, Naozumi Shiraiwa, Taiji Katsumata, Hiroshi Matsuyama
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Publication number: 20190023986Abstract: An object of the present invention is to provide an optical film having an optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. This optical film of the present invention is an optical film at least having an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound, a predetermined mesogen compound, and a polymerization initiator, an I/O value of the liquid crystal compound is more than 0.56, and an I/O value of the mesogen compound is 0.56 or less.Type: ApplicationFiled: September 26, 2018Publication date: January 24, 2019Applicant: FUJIFILM CorporationInventors: Shinichi YOSHINARI, Hiroshi SATO, Shinnosuke SAKAI, Keita TAKAHASHI, Naozumi SHIRAIWA, Hiroshi MATSUYAMA
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Publication number: 20180348417Abstract: An object of the present invention is to provide an optical film having an optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention includes an optically anisotropic layer, an overcoat layer, and a pressure sensitive adhesive layer in this order, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a liquid crystal compound having a polymerizable group and a polymerization initiator, the overcoat layer is a layer obtained by curing a polyfunctional polymerizable monomer having two or more polymerizable groups, and a molecular weight per polymerizable group in the polyfunctional polymerizable monomer is 140 or less.Type: ApplicationFiled: August 2, 2018Publication date: December 6, 2018Applicant: FUJIFILM CorporationInventors: Naozumi SHIRAIWA, Keita TAKAHASHI, Hiroshi SATO