Abstract: Thermally conductive compositions include from about 20 wt. % to about 80 wt. % of a polycarbonate polymer, from about 0.5 wt. % to about 30 wt. % of an impact modifier, and a thermal conductivity modifier. The thermal conductivity modifier includes from about 0.5 wt. % to about 10 wt. % of a high density polyethylene polymer, from about 0.5 wt. % to about 10 wt. % of a maleic anhydride type copolymer, or from about 0.01 wt. % to about 10 wt. % of an acid component. In some aspects the thermally conductive compositions have a notched Izod impact strength of at least about 30 J/m, a through-plane thermal conductivity of at least about 0.4 W/mK and/or an in-plane thermal conductivity of at least about 1.0 W/mK. Methods for making the compositions and articles formed according to the methods are also described.

Abstract: Thermally conductive compositions include from about 20 wt. % to about 80 wt. % of a polycarbonate polymer, from about 0.5 wt. % to about 30 wt. % of an impact modifier, and a thermal conductivity modifier. The thermal conductivity modifier includes from about 0.5 wt. % to about 10 wt. % of a high density polyethylene polymer, from about 0.5 wt. % to about 10 wt. % of a maleic anhydride type copolymer, or from about 0.01 wt. % to about 10 wt. % of an acid component. In some aspects the thermally conductive compositions have a notched Izod impact strength of at least about 30 J/m, a through-plane thermal conductivity of at least about 0.4 W/mK and/or an in-plane thermal conductivity of at least about 1.0 W/mK. Methods for making the compositions and articles formed according to the methods are also described.

Abstract: Filler-reinforced solid resin multilayered structures and methods of making the same. A method of forming a filler-re-inforced solid resin multilayered structure includes forming a layer stack including a first resin layer that is a monoextruded filler-reinforced resin layer and one or more second resin layers that are the same as or different than the first resin layer. The monoextruded filler-reinforced resin layer has a thickness of about 1 micron to less than about 1 mm. The method includes contacting the layer stack and a compression tool. The method includes compressing the layer stack with the compression tool, to laminate the layers of the layer stack and form the filler-reinforced solid resin multilayered structure.

Abstract: Glass filler-reinforced solid resins and methods of making the same. The method includes contacting a flowable resin composition and a tool. The flowable resin composition includes a flowable resin and glass filler. The method includes molding or forming the flowable resin composition with the tool. The method includes curing the flowable resin composition, to form the glass filler-reinforced solid resin. Substantially all the surface of the tool that contacts the flowable resin composition during the curing thereof has a surface roughness Ra of about 2 microns or less. A refractive index of the glass filler is within about 0.100 of a refractive index of a cured product of the flowable resin in the glass filler-reinforced solid resin.

Abstract: Filler-reinforced solid resin multilayered structures and methods of making the same. A filler-reinforced solid resin multilayered structure includes a laminated layer stack. The laminated layer stack includes an inner structure including a first resin layer that is a filler-reinforced resin layer including a cured product of a filler and a resin. The inner structure also includes a second resin layer including a cured product of a resin. The second resin layer is different than the first resin layer. The laminated layer stack also includes a border structure including at least one edge of the second resin layer extending past a corresponding edge of the first resin layer. The border structure is free of the first resin layer.

Abstract: Compositions containing a polycarbonate and a linear and cyclic phenyl containing siloxanes are disclosed. Specifically, a composition comprising: (a) a branched polycarbonate resin, (b) a flame retardant, (c) at least one linear phenyl containing siloxane and at least one cyclic phenyl containing siloxane, and (d) a linear polycarbonate resin when said branched polycarbonate is less than 100% based upon weight percent of total polycarbonate in said composition, wherein the amounts of said branched and linear polycarbonate resins, said linear siloxanes and cyclic siloxanes, and flame retardant are in amounts effective to provide a molded article from said composition with a UL94 V0 p(FTP) value of 0.90 or greater at a thickness of between 1 mm and 2.5 mm or at 2.5 mm or at 1.5 mm or at 1 mm is disclosed.

Abstract: A molded article, comprises: an insert comprising metal, glass, and combinations comprising at least one of the foregoing; a composition injection molded in a first shot on at least a portion of the insert forming a part; and a thermoplastic material injection molded on at least a portion of the part in a second shot of a double shot process. The composition comprises: a) an aromatic polycarbonate (PC) and poly(1,4-cyclohexane dimethylene 1,4-cyclohexanedicarboxylate) (PCCD), the weight ratio of PC to PCCD being in the range of 30 to 90 PC to 70 to 10 PCCD, b) glass fiber greater than or equal to 0.75 mm in length and the quantity of glass fiber from 1 to 50 wt. % of the composition, and c) the refractive index of the polycarbonate and PCCD closely matching the refractive index of the glass fiber and being in the range of from 1.540 to 1.570.

Abstract: An optically diffusive plastic can comprise 40 to 94.9 mass % of a polymer resin matrix; 5 to 50 mass % of a glass filler; and 0.1 to 10 mass % of a light diffusing component; wherein the difference between refractive index of the polymer resin matrix and refractive index of the glass filler is less than or equal to 0.02; wherein a 1 millimeter (mm) thick sample of the optically diffusive plastic comprises a DLD value of greater than or equal to 1 degree (°) as measured by goniophotometry; wherein the 1 mm thick sample comprises a total transmittance of greater than or equal to 40% for incident light having a wavelength of 360 nanometers (nm) to 750 nm in air; and wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23° C., of greater than or equal to 2,500 Megapascal (MPa).

Abstract: An optically diffusive plastic can comprise 40 to 94.9 mass % of a polymer resin matrix; 5 to 50 mass % of a glass filler; and 0.1 to 10 mass % of a light diffusing component; wherein the difference between refractive index of the polymer resin matrix and refractive index of the glass filler is less than or equal to 0.02; wherein a 1 millimeter (mm) thick sample of the optically diffusive plastic comprises a DLD value of greater than or equal to 1 degree (°) as measured by goniophotometry; wherein the 1 mm thick sample comprises a total transmittance of greater than or equal to 40% for incident light having a wavelength of 360 nanometers (nm) to 750 nm in air; and wherein a 3.2 mm thick sample of the optically diffusive plastic comprises a flexural modulus, measured at 23° C., of greater than or equal to 2,500 Megapascal (MPa).

Abstract: Disclosed herein is a flame retardant composition comprising a polycarbonate composition, glass fibers, and a flame retardant that comprises a phenoxyphosphazene compound. Disclosed herein too are methods for manufacturing a flame retardant composition that comprises blending a polycarbonate composition, glass fibers and a flame retardant that comprises a phenoxyphosphazene compound.

Abstract: The present disclosure relates to blended thermoplastic compositions comprising at least one polycarbonate component, at least one reinforcing filler, at least one phosphorus-containing flame retardant component. The resulting thermoplastic composition can be used in the manufacture of articles requiring materials with improved flame retardancy and optical properties such as light transmittance, while retaining required modulus and impact properties.

Abstract: According to an embodiment, a molded article, comprises: an insert comprising metal, glass, and combinations comprising at least one of the foregoing; a composition injection molded in a first shot on at least a portion of the insert forming a part; and a thermoplastic material injection molded on at least a portion of the part in a second shot of a double shot process, wherein the thermoplastic material of the second shot adheres to at least a portion of the composition of the first shot; and the molded article is configured to be attached to an electronic device. The composition comprises: a) an aromatic polycarbonate (PC) and poly(1,4-cyclohexane dimethylene 1,4-cyclohexanedicarboxcylate) (PCCD), the weight ratio of PC to PCCD being in the range of 30 to 90 PC to 70 to 10 PCCD, b) glass fiber greater than or equal to 0.75 mm in length and the quantity of glass fiber from 1 to 50 wt.

Abstract: Disclosed herein is a flame retardant composition comprising a polycarbonate composition, glass fibers, and a flame retardant that comprises a phenoxyphosphazene compound. Disclosed herein too are methods for manufacturing a flame retardant composition that comprises blending a polycarbonate composition, glass fibers and a flame retardant that comprises a phenoxyphosphazene compound.

Abstract: Compositions containing a polycarbonate and a linear and cyclic phenyl containing siloxanes are disclosed. Specifically, a composition comprising: (a) a branched polycarbonate resin, (b) a flame retardant, (c) at least one linear phenyl containing siloxane and at least one cyclic phenyl containing siloxane, and (d) a linear polycarbonate resin when said branched polycarbonate is less than 100% based upon weight percent of total polycarbonate in said composition, wherein the amounts of said branched and linear polycarbonate resins, said linear siloxanes and cyclic siloxanes, and flame retardant are in amounts effective to provide a molded article from said composition with a UL94 V0 p(FTP) value of 0.90 or greater at a thickness of between 1 mm and 2.5 mm or at 2.5 mm or at 1.5 mm or at 1 mm is disclosed.

Abstract: According to an embodiment, disclosed is a method for making a molded article. The method comprises: locating an insert comprising metal, glass, or combination comprising at least one of the foregoing, in a tooling of a double shot injection molding apparatus; and injection molding, in a first shot on at least a portion of the insert to form a part, a composition. The composition comprises: a) an aromatic polycarbonate (PC) and poly(1,4-cyclohexane dimethylene 1,4-cyclohexanedicarboxcylate) (PCCD), the weight ratio of PC to PCCD being in the range of 30 to 90 PC to 70 to 10 PCCD, b) glass fiber greater than or equal to 0.75 mm in length and the quantity of glass fiber from 1 to 50 wt. % of the composition, and c) the refractive index of the polycarbonate and PCCD closely matching the refractive index of the glass fiber and being in the range of from 1.540 to 1.570. The method further comprises injection molding a thermoplastic material on at least a portion of the part in a second shot.

Abstract: According to an embodiment, disclosed is a method for making a molded article. The method comprises: locating an insert comprising metal, glass, or combination comprising at least one of the foregoing, in a tooling of a double shot injection molding apparatus; and injection molding, in a first shot on at least a portion of the insert to form a part, a composition. The composition comprises: a) an aromatic polycarbonate (PC) and poly(1,4-cyclohexane dimethylene 1,4-cyclohexanedicarboxcylate) (PCCD), the weight ratio of PC to PCCD being in the range of 30 to 90 PC to 70 to 10 PCCD, b) glass fiber greater than or equal to 0.75 mm in length and the quantity of glass fiber from 1 to 50 wt. % of the composition, and c) the refractive index of the polycarbonate and PCCD closely matching the refractive index of the glass fiber and being in the range of from 1.540 to 1.570. The method further comprises injection molding a thermoplastic material on at least a portion of the part in a second shot.