Abstract: A polymerization process to copolymerize hydrophobic ethylenically unsaturated C4-C28 olefins with polar monomers such as acrylates utilizing a polymeric support resin to stabilize the polymerization product in an aqueous media is described. The copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.

Abstract: A product and processes comprising urethane polymer and at least one copolymer from a hydrophobic ethylenically unsaturated C4-C30 olefins copolymerized with polar monomers such as acrylates. One process optionally utilizes an acid source to modify/catalyze the reactivity of the polar monomer and/or radically activated repeat unit from the polar monomer to promote incorporation of the ethylenically unsaturated olefin. Other processes vary depending on which polymer if formed and/or dispersed first. The hybrid copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.

Abstract: A polymerization process to copolymerize hydrophobic ethylenically unsaturated C4-C30. J olefins with polar monomers such as acrylates is described. The process utilizes an acid source to modify/catalyze the reactivity of the polar monomer and/or radically activated repeat unit from the polar monomer to promote incorporation of the ethylenically unsaturated olefin. The copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.

Abstract: The present invention discloses films, papers, and fabrics (both woven and non-woven) that are more receptive to inks or dyes. These ink/dye receptive products are made by coating the surface of the film, paper, or fabric with certain acrylate polymers. These ink/dye receptive films, papers and fabrics have the ability to then be used in making laminated and coated products. The subject invention more specifically discloses an ink/dye receptive film which is comprised of a base film which is coated with an acrylate polymer, comprised of 1 weight percent to 20 weight percent repeat units of at least one unsaturated aliphatic olefin monomer containing from 4 to 30 carbon atoms.

Abstract: A polymerization process to copolymerize hydrophobic ethylenically unsaturated C4-C28 olefins with polar monomers such as acrylates utilizing a polymeric support resin to stabilize the polymerization product in an aqueous media is described. The copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.

Abstract: A product and processes comprising urethane polymer and at least one copolymer from a hydrophobic ethylenically unsaturated C4-C30 olefins copolymerized with polar monomers such as acrylates. One process optionally utilizes an acid source to modify/catalyze the reactivity of the polar monomer and/or radically activated repeat unit from the polar monomer to promote incorporation of the ethylenically unsaturated olefin. Other processes vary depending on which polymer if formed and/or dispersed first. The hybrid copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylate coatings, wood, etc.

Abstract: A polymerization process to copolymerize hydrophobic ethylenically unsaturated C4-C30. J olefins with polar monomers such as acrylates is described. The process utilizes an acid source to modify/catalyze the reactivity of the polar monomer and/or radically activated repeat unit from the polar monomer to promote incorporation of the ethylenically unsaturated olefin. The copolymer shows excellent adhesion to a variety of polymeric and/or polar substrates such as polyolefins, acrylatc coatings, wood, etc.

Abstract: A controlled free-radical polymerization process for forming end-functionalized polymers is disclosed, particularly by degenerative iodine transfer. The end-functionalized polymers are characterized by a polydispersity less than 2.5 and a predetermined molecular weight. The end-functionalized polymers are useful as reactive intermediates in condensation polymerization, chain polymerization and heterogeneous polymerization reactions.

Abstract: A controlled free-radical polymerization process for forming end-functionalized polymers is disclosed, particularly by degenerative iodine transfer. The end-functionalized polymers are characterized by a polydispersity less than 2.5 and a predetermined molecular weight. The end-functionalized polymers are useful as reactive intermediates in condensation polymerization, chain polymerization and heterogeneous polymerization reactions.

Abstract: A one-part, substantially formaldehyde-free, self-curing interpolymer comprising repeating units derived from a) about 4 to about 30 percent by weight of at least one functional monomer selected from olefinically unsaturated monomer containing a nucleophile group; b) about 4 to about 40 percent by weight of an olefinically unsaturated dicarboxylic acid; c) about 1 to about 60 percent by weight of (meth)acrylonitrile; d) about 0 to about 80 percent by weight of at least one monomer selected from the group consisting of (meth)acrylic acid ester of an alcohol containing 1 to 30 carbon atoms; and e) about 0 to about 80 percent by weight of at least one monomer selected from the group consisting of styrene, vinyl acetate, and vinyl halides, wherein at least one of monomers d) and e) are present in an amount of from about 0.1 percent by weight, for use as a fiber binder, such as for coating non-woven glass mats, or as a saturant for fiber substrates such as paper.

Abstract: A one-part, substantially formaldehyde-free, self-curing interpolymer comprising repeating units derived from a) about 4 to about 30 percent by weight of at least one functional monomer selected from olefinically unsaturated monomer containing a nucleophile group: b) about 4 to about 40 percent by weight of an olefinically unsaturated dicarboxylic acid; c) about 1 to about 60 percent by weight of (meth)acrylonitrile; d) about 0 to about 80 percent by weight of at least one monomer selected from the group consisting of (meth)acrylic acid ester of an alcohol containing 1 to 30 carbon atoms; and e) about 0 to about 80 percent by weight of at least one monomer selected from the group consisting of styrene, vinyl acetate, and vinyl halides, wherein at least one of monomers d) and e) are present in an amount of from about 0.1 percent by weight, for use as a fiber binder, such as for coating non-woven glass mats, or as a saturant for fiber substrates such as paper.

Abstract: Polyvinyl halide resin absent allylic halogen is disclosed. Another polyvinyl halide resin absent allylic halogen, allylic branching and unsaturation is also disclosed. The compositions of this invention are prepared by contacting any polyvinyl halide resin with a hydrogen-substituting compound that has a selective affinity for the allylic halogens.

Abstract: Thermal stability of vinyl halide polymers is enhanced by the use of dienophiles such as N-alkyl maleimides, and bis compounds thereof, disclosed herein. The maleimides and bis compounds thereof produce synergistic results in terms of thermal stability of vinyl halide polymers when used in conjunction with conventional metal-containing thermal stabilizers. Environmental concerns are abated and certain other advantages are realized if the maleimides disclosed herein are used in conjunction with conventional nonmetallic thermal stabilizers to stabilize vinyl halide polymers against heat deterioration. Bis compounds of the N-alkyl maleimides disclosed herein, when used as thermal stabilizers for vinyl halide polymers, promote crosslinking without degrading the vinyl halide polymer.