Abstract: Sample bags having at least one multilayer wall are described. The multilayer wall may include an inner layer and a sealing layer. The sealing layer is outside of the inner layer and forms a seam around at least a portion of the sample bag. In certain embodiments, the inner layer comprises a patterned periphery. The patterned periphery extends into the seam to provide the inner layer with a mechanical stability. The inner layer may be a thin metal foil or a plastic film and the sealing layer may include a sealing surface of a thermoplastic, wherein the thermoplastic of each sealing layer may be fused to form a seal around the periphery of the sampling bag. The sample bag thereby an inner layer with a low permeable, low adsorption layer coupled with a second layer providing an effective seal results in a sample bag with improved sample gas stability.

Abstract: Sampling devices are used to obtain samples of fluids to be analyzed and to determine the composition of the fluid in the sampled environment. A sampling apparatus with an inflatable sample bag used to collect and store liquid, air, vapor, and or gas samples by drawing the sample into the bag through an inlet, a sorbent tube, cassette, and/or other collection media is described. The means for extracting the sample and moving it into the sample bag comprises means for expanding the volume of a sample bag and creating a vacuum or reduced pressure within the sample bag. The means for expanding the include separating walls of a sample bag by use of gravity, pneumatic pressure, a biasing force, hydraulic force, for example or increasing the volume of a sample bag retaining container by such forces. Such sampling apparatuses do not require use of a sampling pump.