Abstract: Catalyst-inhibitor system for the polymerization of poly(ethylene terephthalate) having excellent properties for fabrication of fibers and films. The catalyst-inhibitor system comprises a combination of organic or inorganic salts of manganese and cobalt; titanium alkoxides; an antimony compound; and a phosphate ester. This invention also is directed to an improved method of preparing synthetic linear polyesters utilizing the new catalyst-inhibitor system.

Abstract: Catalyst-inhibitor systems for the polymerization of poly(ethylene terephthalate) having excellent properties for fabrication of fibers and films. The catalyst-inhibitor systems comprise a combination of organic or inorganic salts of manganese and cobalt; titanium alkoxides; organic salts of alkali metals or alkaline earth metals; and a phosphate ester. This invention also is directed to an improved method of preparing synthetic linear polyesters utilizing the new catalyst-inhibitor systems.

Abstract: method for treating pellets of a polyester polymer, such as a polyester polymer of poly(ethylene terephthalate), having at least some non-crystalline portions to prevent sticking when heated above the glass transition temperature. The method comprises mixing with pellets of the polyester polymer an amount of about 0.25% to about 5% by weight of crystalline fines which are less than 40 mesh in size, and preferably less than 140 mesh in size, of the same type polymer prior to or while the pellets are being subjected to temperatures above the glass transition temperature. The crystalline fines may also be mixed with pellets of amorphous polyester polymer. Other examples of polymers with which this treatment will also be effective are poly(tetramethylene terephthalate); poly(1,4-cyclohexanedimethylene terephthalate); poly(1,4-cyclohexanedimethylene terephthalate) modified with isophthalic acid; and a copolymer of 3:1 terephthalic:adipic acids and 3:1 ethylene:tetramethylene glycols.