Abstract: Structured automotive catalysts which comprise a plurality of different catalytically active coatings arranged above one another on a support body and whose coatings contain transition metals and porous support materials are well known. Structured automotive catalysts of this type which do not belong to the group of three-way catalysts, in particular, frequently display large selectivity losses after thermal aging processes which can be attributed to the thermally induced migration of transition metal atoms from one layer into the neighboring coating. The introduction of a diffusion barrier which slows or prevents the thermally induced migration of transition metal atoms from one catalytically active layer into the other increases the thermal aging stability of such catalysts significantly.

Abstract: Structured automotive catalysts which comprise a plurality of different catalytically active coatings arranged above one another on a support body and whose coatings contain transition metals and porous support materials are well known. Structured automotive catalysts of this type which do not belong to the group of three-way catalysts, in particular, frequently display large selectivity losses after thermal aging processes which can be attributed to the thermally induced migration of transition metal atoms from one layer into the neighbouring coating.

Abstract: This invention provides a method of regenerating a diesel particulate filter in an exhaust-gas purification system of a diesel engine using lambda variation. During regeneration on demand, the ratio of air to fuel for the corresponding operating point of the diesel engine is adjusted so as to achieve the substantially highest possible exhaust-gas temperature. For this purpose, the ratio of air to fuel (lambda value) is preferably kept at a minimum and substantially constant over the major part of the load range so that the engine is operated at full load during the regeneration phases.