Abstract: The invention relates to an alkoxysilane polysulfide, of formula (I): (R3O)3-n(R1)nSi—CH2—(R2)CH—Z—Sx—Z—HC(R2)—CH2—Si(R1)n(OR3)3-n??(I), in which: R1, which are identical or different, each represent a monovalent hydrocarbon group having from 1 to 18 carbon atoms; R2, which are identical or different, each represent a monovalent hydrocarbon group having from 1 to 4 carbon atoms; R3, which are identical or different, each represent a monovalent hydrocarbon group having from 1 to 12 carbon atoms, preferably from 1 to 6 carbon atoms; Z, which are identical or different, each represent a divalent hydrocarbon bonding group comprising from 1 to 16 carbon atoms; x is an integral or fractional number greater than or equal to 2; and n is an integer equal to 0, 1 or 2.

Abstract: An elastomeric composition is based on at least a diene elastomer, an inorganic filler as reinforcing filler and a monohydroxysilane polysulfide as coupling agent of formula (I): (HO)(R1)2Si—CH2—(R2)CH—Z—Sx—Z—HC(R2)—CH2—Si(R1)2(OH) (I), in which: each R1 represents a monovalent hydrocarbon group having from 1 to 18 carbon atoms and can be the same or different from one another; each R2 represents a monovalent hydrocarbon group having from 1 to 4 carbon atoms and can be the same or different from one another; each Z represents a divalent hydrocarbon bonding group comprising from 1 to 16 carbon atoms can be the same or different from one another; and x is an integral or fractional number greater than or equal to 2.

Abstract: The invention relates to an alkoxysilane polysulfide, of formula (I): (R3O)3-n(R1)nSi—CH2—(R2)CH—Z—Sx—Z—HC(R2)—CH2—Si(R1)n(OR3)3-n??(I), in which: R1, which are identical or different, each represent a monovalent hydrocarbon group having from 1 to 18 carbon atoms; R2, which are identical or different, each represent a monovalent hydrocarbon group having from 1 to 4 carbon atoms; R3, which are identical or different, each represent a monovalent hydrocarbon group having from 1 to 12 carbon atoms, preferably from 1 to 6 carbon atoms; Z, which are identical or different, each represent a divalent hydrocarbon bonding group comprising from 1 to 16 carbon atoms; x is an integral or fractional number greater than or equal to 2; and n is an integer equal to 0, 1 or 2.

Abstract: A process for the synthesis of a diene copolymer comprising at least two blocks, at least one of the blocks being composed of a diene elastomer, characterized in that it comprises a stage of 1,3-dipolar reaction of two polymers defined as being: a) a diene elastomer bearing an alkyne functional group at one or each of its chain ends, and b) a polymer bearing at least one azide functional group. This process of synthesis can be adjusted, whatever the nature of the monomers necessary to form each of the blocks of the copolymer. Each block can be synthesized with an appropriate chemistry, independently of the other block.

Abstract: An elastomeric composition is based on at least a diene elastomer, an inorganic filler as reinforcing filler and a monohydroxysilane polysulfide as coupling agent of formula (I): (HO)(R1)2Si—CH2—(R2)CH—Z—Sx—Z—HC(R2)—CH2—Si(R1)2(OH) (I), in which: each R1 represents a monovalent hydrocarbon group having from 1 to 18 carbon atoms and can be the same or different from one another; each R2 represents a monovalent hydrocarbon group having from 1 to 4 carbon atoms and can be the same or different from one another; each Z represents a divalent hydrocarbon bonding group comprising from 1 to 16 carbon atoms can be the same or different from one another; and x is an integral or fractional number greater than or equal to 2.

Abstract: A heavy-duty vehicle tire comprising a tread consisting of a crosslinked rubber composition comprising a reinforcing filler of siliceous type and a synthetic polyisoprene modified by grafting with a compound comprising at least one group Q, and at least one group A, which are joined to one another by at least one and preferably one “spacer” group Sp, in which: Q comprises a dipole containing at least one and preferably one nitrogen atom, A comprises an associative group comprising at least one nitrogen atom, Sp is an atom or group of atoms forming a bond between Q and A. The heavy-duty vehicle tire according to the invention has a satisfactorily improved rolling resistance/wear resistance compromise.

Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by a silanol group, the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.

Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler and a 1,3-dipolar compound bearing an imidazole functional group. Such a composition exhibits an improved compromise in certain properties such as stiffness in the cured state and hysteresis.

Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolyzed to give silanol, bearing a tertiary amine functional group and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.

Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolyzed to give silanol, bearing an epoxide function and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine function.

Abstract: A rubber composition comprises a reinforcing filler and a diene elastomer bearing imidazole functional groups along the chain which are randomly distributed along the chain. Such a composition exhibits an improved compromise in certain properties such as stiffness in the cured state and hysteresis.

Abstract: A rubber composition for the manufacture of tires is based on one or more diene elastomers, one or more reinforcing fillers, and a vulcanization system. The vulcanization system includes one or more thiazole compounds chosen from compounds having the following formula (I): Certain specific thiazole derivatives are described.

Abstract: A rubber composition for manufacturing tyres includes one or more diene elastomers, one or more reinforcing fillers, and a vulcanization system. The vulcanization system includes one or more thiazoline compounds chosen from compounds of formula I and compounds of formula II: Certain specific thiazoline derivatives are described.

Abstract: A process for the synthesis of a diene copolymer comprising at least two blocks, at least one of the blocks being composed of a diene elastomer, characterized in that it comprises a stage of 1,3-dipolar reaction of two polymers defined as being: a) a diene elastomer bearing an alkyne functional group at one or each of its chain ends, and b) a polymer bearing at least one azide functional group. This process of synthesis can be adjusted, whatever the nature of the monomers necessary to form each of the blocks of the copolymer. Each block can be synthesized with an appropriate chemistry, independently of the other block.

Abstract: The present invention relates to a process for the preparation of a random copolymer based on diene monomers and on cyclic carbosilane monomers. This process is characterized in that it comprises a stage of copolymerization, in the presence of an anionic initiator in a reaction medium comprising a polar solvent, of at least one diene monomer and of a cyclic carbosilane monomer corresponding to the Formula I: in which: R1 and R2, which are identical or different, are each a C1-C5 alkyl, C6-C14 aryl or C7-C11 alkylaromatic group; R3 and R4, which are identical or different, are each a hydrogen atom or a C1-C5 alkyl, C6-C14 aryl or C7-C11 alkylaromatic group; and x is an integer with a value ranging from 2 to 5 and is preferably 3.

Abstract: A process for the radical grafting of a graft to a diene elastomer, comprising the following stages: a. dissolving, with stirring, at least one diene elastomer and at least one thiol derivative as graft in a solvent comprising a mixture of at least one polar solvent and at least one nonpolar solvent, b. heating the homogeneous reaction mixture obtained in the preceding stage to the temperature of the grafting reaction, and c. once the temperature of the grafting reaction has been reached, adding the radical initiator in order to bring about the grafting of the graft to the units of the elastomer comprising unsaturations. This radical grafting process makes it possible to achieve high grafting yields which can reach 100%.

Abstract: An anionic polymerization initiator of formula: in which: Met, which can be borne by the ortho, meta or para position, denotes an alkali metal, R1 and R2, and also R3 and R4, which can be borne by the ortho, meta or para position, denote a hydrogen atom or an alkyl, cycloalkyl, aryl or arylalkyl group, and R5 denotes an alkyl, cycloalkyl, aryl or arylalkyl group or a protective group for the alkyne functional group. The use of such a polymerization initiator makes possible the synthesis of a diene elastomer bearing, at one or each of its chain ends, a group comprising an alkyne functional group with a high degree of functionalization.

Abstract: The present invention relates to a modified polymer obtained by grafting a compound comprising at least one group Q, and at least one group A bonded together by at least, and preferably, one “spacer” group Sp in which: Q comprises an azo-carbonyl group capable of being grafted onto the polymer chain by an “ene reaction”, A comprises an associative group comprising at least one nitrogen atom, Sp is an atom or a group of atoms forming a bond between Q and A.

Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, bearing an epoxide function and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine function.

Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler and a 1,3-dipolar compound bearing an imidazole functional group. Such a composition exhibits an improved compromise in certain properties such as stiffness in the cured state and hysteresis.