Abstract: The present invention relates to radically curable compositions, comprising (A) silver nanoplatelets, (B) one reactive diluent comprising 1 to 4 (meth)acrylate groups; (C) one, or more urethane (meth)acrylates (C), which are obtainable by reaction of the following components: (a) at least one isocyanate having two isocyanate groups, (b) at least one polyalkylene oxide polyether having at least 2 hydroxyl groups, (c) at least one hydroxy-functional (meth)acrylate having one hydroxyl group and one (meth)acrylate group, (d) at least one compound having at least one isocyanate reactive group and at least one acid function, (e) if component (d) is present, optionally at least one basic compound which is present for neutralization or partial neutralization of the acid groups of component (d), (f) optionally at least one monoalcohol having one hydroxy function, and (g) optionally at least one compound having at least one primary and/or secondary amino group; (D) one, or more photonitiators; printing inks containi

Abstract: The present invention relates to compositions, comprising (A) platelet-shaped transition metal particles, wherein the number mean diameter of the platelet-shaped transition metal particles, present in the composition, is in the range of from 15 nm to 1000 nm, the transition metal is selected from silver, copper, gold and palladium, especially silver and copper, very especially silver; (B) one, or more reactive diluents (B); (C) one, or more oligomers (C); (D) one, or more photoinitiators (D); (E) at least a surfactant (E), which is a block copolymer, comprising at least a block A and a block B, wherein a) the block A comprises a1) monomer units (A1) derived from a compound selected from alkyl (meth)acrylates, alkyl (meth)acrylamides, or any mixture thereof, and a2) monomer units (A2) derived from a hydroxy group, or ether group containing alkyl (meth)acrylate; b) the block B comprises monomer units (B) derived from a compound selected from fluorinated (meth)acrylic esters of formula H2C?CR46(C(O)ORF-

Abstract: The present invention provides a UV-Vis radiation curable security ink for producing a security feature for securing value documents, wherein said security feature exhibits a blue color upon viewing in transmitted light and a metallic yellow color upon viewing in incident light. The UV-Vis radiation curable security ink comprises a cationically curable or a hybrid curable ink vehicle, and silver nanoplatelets bearing a surface stabilizing agent of general formula (I) wherein the residue RA is a C2-C4alkyl group substituted with a hydroxy group; the residue RB is selected from a C1-C4 alkyl group, and a C2-C4alkyl group substituted with a hydroxy group; and Cat+ is a cation selected from the group consisting of Na+, K+, Cs+ and Rb+.

Abstract: The present invention provides a process for manufacturing a security feature for securing a value document, wherein said security feature exhibits a blue color upon viewing in transmitted light and a metallic yellow color upon viewing in Incident light. The manufacturing process comprises the following steps: a) printing a specific UV-Vis radiation curable ink on a transparent or partially transparent region of a substrate of a value document; b) heating the ink layer obtained at step a) at a temperature of about 55° C. to about 100° C. for at least one second so that the ink layer exhibits a metallic yellow color upon viewing in incident light; and c) UV-Vis curing the ink layer obtained at step b) to form the security feature.

Abstract: The present invention relates to security, or decorative elements, comprising a transparent, or translucent substrate, which may contain indicia or other visible features in or on its surface, and on at least part of the substrate surface, a first layer, comprising transition metal particles having an average diameter of from 5 nm to 500 nm and a binder, on at least part of the first layer a second layer, comprising an organic material and having a refractive index of from 1.2 to 2.3 and having a thickness of from 20 to 1000 nm, wherein the transition metal is silver, copper, gold and palladium, wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 20:1 to 1:2 in case the binder is a polymeric binder, or wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 5:1 to 1:15 in case the binder is an UV curable binder.

Abstract: The present invention provides a UV-Vis radiation curable security ink for producing a security feature for securing value documents, wherein said security feature exhibits a blue color upon viewing in transmitted light and a metallic yellow color upon viewing in incident light. The UV-Vis radiation curable security ink comprises a cationically curable or a hybrid curable ink vehicle, and silver nanoplatelets bearing a surface stabilizing agent of general formula (I) wherein the residue RA is a C2-C4alkyl group substituted with a hydroxy group; the residue RB is selected from a C1-C4alkyl group, and a C2-C4alkyl group substituted with a hydroxy group; and Cat+ is an ammonium cation of general formula +NH2RCRD, wherein the residue RC is a C2-C4alkyl group substituted with a hydroxy group; and the residue RD is selected from a C1-C4alkyl group, and a C2-C4alkyl group substituted with a hydroxy group.

Abstract: The present invention provides a UV-Vis radiation curable security ink for producing a security feature for securing value documents, wherein said security feature exhibits a blue color upon viewing in transmitted light and a metallic yellow color upon viewing in incident light. The UV-Vis radiation curable security ink comprises a cationically curable or a hybrid curable ink vehicle, and silver nanoplatelets bearing a surface stabilizing agent of general formula (I) wherein the residue RA is a C2-C4alkyl group substituted with a hydroxy group; the residue RB is selected from a C1-C4 alkyl group, and a C2-C4alkyl group substituted with a hydroxy group; and Cat+ is a cation selected from the group consisting of Na+, K+, Cs+ and Rb+.

Abstract: The present invention relates to coating compositions, comprising i) single or mixed metal oxide nanoparticles, wherein the volume average diameter (Dv50) of the metal oxide nanoparticles is in the range of 1 to 20 nm; the nanoparticles comprise at least one volatile surface-modifying compound selected from alcohols, ?-diketones, or salts thereof; carboxylic acids and ?-ketoesters and Ge mixtures thereof, wherein the total amount of volatile surface-modifying compounds is at least 5% by weight, preferably at least 10% by weight based on the amount of metal oxide nano-particles, and ii) a solvent, coatings obtained therefrom and the use of the comositions for coating surface relief micro- and nanostructures (e.g. holograms), manufacturing of optical waveguides, solar panels, light outcoupling layers for display and lighting devices and anti-reflection coatings.

Abstract: The present invention relates to compositions, comprising platelet-shaped transition metal particles, wherein the number mean diameter of the platelet-shaped transition metal particles, present in the composition, is in the range of 15 nm to 1000 nm and the number mean thickness of the platelet-shaped transition metal particles, present in the composition, is in the range of 2 to 40 nm, the transition metal is selected from silver, copper, gold and palladium and the platelet-shaped transition metal particles bear a surface modifying agent of formula A-(CHR9)r—R10 (V), wherein if r is 1, A is a C1-C25alkyl group substituted with one, or more fluorine atoms; a C2-C25alkenyl substituted with one, or more fluorine atoms; a C2-C25alkynyl group substituted with one, or more fluorine atoms; a C3-C20cycloalkyl group substituted with one, or more fluorine atoms; or a C6-C24aryl group substituted with one, or more fluorine atoms, CF3 or —O—CF3 groups; if r is 0, A is a C6-C24aryl group substituted with one, or more flu

Abstract: The present invention provides a process for manufacturing a security feature for securing a value document, wherein said security feature exhibits a blue color upon viewing in transmitted light and a metallic yellow color upon viewing in Incident light. The manufacturing process comprises the following steps: a) printing a specific UV-Vis radiation curable ink on a transparent or partially transparent region of a substrate of a value document; b) heating the ink layer obtained at step a) at a temperature of about 55° C. to about 100° C. for at least one second so that the ink layer exhibits a metallic yellow color upon viewing in incident light; and c) UV-Vis curing the ink layer obtained at step b) to form the security feature.

Abstract: The present invention relates to a process for the preparation of thin silver nano-particles containing layers, which are produced directly on a substrate as part of a coating or printing process. The layers can show different colours in transmittance and reflectance. The invention further relates to decorative and security elements. When the layers are applied over a security element, such as a hologram, the obtained products may show different colours in reflection and transmission, an extremely bright optically variable image (OVD image). Depending on the thickness of the layer a more or less intensive metallic aspect appears.

Abstract: The present invention relates to metal oxide nanoparticles, a method for their production, a coating, or printing composition, comprising the metal oxide nanoparticles and the use of the composition for coating of surface relief micro- and nanostructures (e.g. holograms), manufacturing of optical waveguides, solar panels, light outcoupling layers for display and lighting devices and anti-reflection coatings. Holograms are bright and visible from any angle, when coated, or printed with the composition, comprising the metal oxide nanoparticles.

Abstract: The present invention relates to compositions, comprising silver nanoplatelets, wherein the number mean diameter of the silver nanoplatelets, present in the composition, is in the range of 50 to 150 nm with standard deviation being less than 60% and the number mean thickness of the silver nanoplatelets, present in the composition, is in the range of 5 to 30 nm with standard deviation being less than 50%, wherein the mean aspect ratio of the silver nanoplatelets is higher than 2.0 and the highest wavelength absorption maximum of the population of all silver nanoplatelets in the composition being within the range of 560 to 800 nm. A coating, comprising the composition, shows a blue color in transmission and a metallic yellow color in reflection.

Abstract: The present invention relates to security, or decorative elements, comprising a transparent, or translucent substrate, which may contain indicia or other visible features in or on its surface, and on at least part of the substrate surface, a first layer, comprising transition metal particles having an average diameter of from 5 nm to 500 nm and a binder, on at least part of the first layer a second layer, comprising an organic material and having a refractive index of from 1.2 to 2.3 and having a thickness of from 20 to 1000 nm, wherein the transition metal is silver, copper, gold and palladium, wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 20:1 to 1:2 in case the binder is a polymeric binder, or wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 5:1 to 1:15 in case the binder is an UV curable binder.

Abstract: The present invention relates to security elements, comprising (a) a substrate, (b) on at least part of the substrate surface a metal layer, (c) optionally on at least part of the metal layer a dielectric layer, (d) on at least part of the metal layer, or the dielectric layer, a layer obtained by overcoating the metal layer, or the dielectric layer with a composition, comprising (i) silver nanoparticles, (ii) a solvent, (iii) (surface) stabilizing agent(s) and (iv) optionally a binder, and (e) a protective layer on top of layer (d). The maximum absorption wavelength of the silver nanoparticles in layer (d) is controlled by the amount of (surface) stabilizing agent(s) and optionally binder relative to the amount of silver nanoparticles to be preferably in the range of 700 to 1600 nm.

Abstract: The present invention relates to compositions, comprising silver nanoplatelets, wherein the mean diameter of the silver nanoplatelets, present in the composition, is in the range of 20 to 70 nm with standard deviation being less than 50% and the mean thickness of the silver nanoplatelets, present in the composition, is in the range of 5 to 30 nm with standard deviation being less than 50%, wherein the mean aspect ratio of the silver nanoplatelets is higher than 1.5, a process for its production, printing inks containing the compositions and their use in security products. The highest wavelength absorption maximum of the population of all silver nanoplatelets in the composition being within the range of 450 to 550 nm. A coating, comprising the composition, shows a red, or magenta color in transmission and a greenish-metallic color in reflection.

Abstract: The present invention relates to a process for the preparation of thin silver nanoparticle layers, which are produced directly on a substrate as part of a coating or printing process. The layers show different colours in transmittance and reflectance. The layers do not show the typical conductivity of metallic layers, since the particles are essentially discrete particles which are not sintered. The invention further relates to decorative and security elements. When the layers are applied over a security element, such as a hologram, the obtained products show also different colours in reflection and transmission, an extremely bright optically variable image (OVD image) and high purity and contrast. Depending on the thickness of the layer a more or less intensive metallic aspect appears.

Abstract: The invention relates to a process for producing a patterned transparent conductive film comprising areas with lower conductivity and areas with higher conductivity, comprising following steps: (a) applying an ink comprising electrically conductive nanoobjects with or without a binder on a substrate, forming a first layer, wherein the amount of conductive nanoobjects is such that the first layer has a low conductivity after drying; (b) drying of the first layer; (c) applying an ink comprising a metallo-organic complex in a predetermined pattern on the first layer; (d) decomposing of the ink applied in step (c), thereby forming a pattern having a higher conductivity on the first layer.

Abstract: The present invention relates to a process for the preparation of thin silver nano-particles containing layers, which are produced directly on a substrate as part of a coating or printing process. The layers can show different colours in transmittance and reflectance. The invention further relates to decorative and security elements. When the layers are applied over a security element, such as a hologram, the obtained products may show different colours in reflection and transmission, an extremely bright optically variable image (OVD image). Depending on the thickness of the layer a more or less intensive metallic aspect appears.

Abstract: The present invention relates to complex security elements based on liquid crystal coatings which are subsequently coated with specific metallic nano-shaped metal particles, a method for their manufacture, in particular on a glass, paper or on a plastic substrate and a security product obtainable using the security element. The security element may contain additionally an embossed surface relief microstructure, especially an optically variable image (an optically variable device, OVD), such as a hologram. A further aspect of the invention is the use of such a security element for the prevention of counterfeit or reproduction of a document of value.