Abstract: Novel hybrid luminescent ammunition (HLA) is provided. The HLA projectiles can include photoluminescent or triboluminescent material, or both. The photoluminescent and triboluminescent material can be placed at various locations on the projectile. In one configuration, the triboluminescent material that gives off light when the projectile impacts the target. In another configuration, a photoluminescent material provides a during flight and the triboluminescent material provides identification of target impact. In another configuration, the triboluminescent material is used to provide both the ballistic trace and the impact identification. Methods of making the HLA are also provided.