Patents by Inventor Nobuhiko Akino

Nobuhiko Akino has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20210391542
    Abstract: A light emitting device having excellent light emission efficiency contains a cathode, a first organic layer containing a compound having a cross-linkable group and a phosphorescent transition metal complex, a second organic layer containing a crosslinked body of the same compound as the compound having a cross-linkable group, and an anode in this order. The ratio of the compound having a cross-linkable group contained in the first organic layer is 2 to 10% by mass with respect to the total mass of the first organic layer. The compound having a cross-linkable group may be a compound having at least one cross-linkable group selected from cross-linkable groups represented by the formula (XL-1) to the formula (XL-19).
    Type: Application
    Filed: December 19, 2019
    Publication date: December 16, 2021
    Inventors: Mio SHIRATORI, Nobuhiko AKINO, Daisuke FUKUSHIMA
  • Patent number: 11046655
    Abstract: A compound represented by the formula (1) is provided: wherein A1 represents an oxygen atom, a sulfur atom, —NR5— or —PR5—; at least one A1 is —NR5— or —PR5—; R1 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylsulfenyl group, a cycloalkylsulfenyl group, an arylsulfenyl group or a disubstituted amino group; R2 and R3 represent an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylsulfenyl group, a cycloalkylsulfenyl group, an arylsulfenyl group, a monovalent heterocyclic group, a halogen atom or a disubstituted amino group; R4 represents a hydrogen atom, —C(R6)3, —OR7, —N(R7)2 or —Si(R7)3; m represents an integer of 0 to 3; and n represents an integer of 0 to 4.
    Type: Grant
    Filed: March 21, 2017
    Date of Patent: June 29, 2021
    Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, CAMBRIDGE DISPLAY TECHNOLOGY LIMITED
    Inventors: Satoshi Kobayashi, Takayuki Iijima, Nobuhiko Akino, Sheena Zuberi
  • Patent number: 11005044
    Abstract: A light emitting device is provided which contains an anode, a cathode, and two organic layers disposed between the anode and the cathode. The first organic layer contains a phosphorescent material and the second organic layer contains a crosslinked body of a crosslinkable material and a phosphorescent material. The two phosphorescent materials contain the same phosphorescent compound represented by formula (1), and the crosslinkable material is a compound represented by formula (3): In formula (1), M represents a metal atom, n1 is ?1, n2 is ?0, E1 and E2 represent a carbon atom, L1 and L2 represent an aromatic heterocyclic ring, and A1-G1-A2 represents an anionic bidentate ligand. In formula (3), mB1 to mB3 represent an integer of ?0, Ar7 may represent an aromatic hydrocarbon group, LB1 may represent a divalent group, and X? may represent a crosslinkable group.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: May 11, 2021
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Toshiaki Sasada, Makoto Anryu, Nobuhiko Akino, Takakazu Saito
  • Patent number: 10711091
    Abstract: Provided is a light-emitting device including an anode, a light-emitting layer, an electron-transporting layer and a cathode. The electron-transporting layer contains at least one electron-transporting material whose LUMO level is ?3.0 eV or more and at least one dopant material selected from the group consisting of a heterocyclic compound whose SOMO level is ?2.2 to ?1.5 eV and a derivative thereof. The LUMO level of the electron-transporting material is smaller than the SOMO level of the heterocyclic compound.
    Type: Grant
    Filed: March 21, 2017
    Date of Patent: July 14, 2020
    Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, Cambridge Display Technology Limited
    Inventors: Takayuki Iijima, Satoshi Kobayashi, Masanobu Tanaka, Nobuhiko Akino, Sheena Zuberi
  • Publication number: 20200140394
    Abstract: A compound represented by the formula (1) is provided: wherein A1 represents an oxygen atom, a sulfur atom, —NR5— or —PR5—; at least one A1 is —NR5— or —PR5—; R1 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylsulfenyl group, a cycloalkylsulfenyl group, an arylsulfenyl group or a disubstituted amino group; R2 and R3 represent an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylsulfenyl group, a cycloalkylsulfenyl group, an arylsulfenyl group, a monovalent heterocyclic group, a halogen atom or a disubstituted amino group; R4 represents a hydrogen atom, —C(R6)3, —OR7, —N(R7)2 or —Si(R7)3; m represents an integer of 0 to 3; and n represents an integer of 0 to 4.
    Type: Application
    Filed: March 21, 2017
    Publication date: May 7, 2020
    Applicants: Sumitomo Chemical Company, Limited, Cambridge Display Technology Limited
    Inventors: Satoshi KOBAYASHI, Takayuki IIJIMA, Nobuhiko AKINO, Sheena ZUBERI
  • Patent number: 10529934
    Abstract: Provided is a metal complex which is excellent in quantum yield and full width at half maximum of a light emission spectrum. The metal complex is represented by the following formula (1): wherein M represents an iridium atom or the like, n1 represents 1 to 3, n2 represents 0 to 2, X1 to X8 represent a carbon atom or the like, R1 to R8 represent a hydrogen atom or the like, one of Xa and Xb is a single bond, and the other is a group represented by —CR11R12—CR13R14—, R11 to R14 represent an alkyl group or the like, ring A represents a heteroaromatic ring, and A1-G1-A2 represents an anionic bidentate ligand.
    Type: Grant
    Filed: September 9, 2015
    Date of Patent: January 7, 2020
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takakazu Saito, Yusuke Ishii, Kazuei Ohuchi, Nobuhiko Akino, Rui Ishikawa
  • Patent number: 10431760
    Abstract: A light emitting device excellent in luminance life includes an anode, a cathode, a first organic layer (containing at least one phosphorescent compound) disposed between the anode and cathode and a second organic layer (containing at least one phosphorescent compound and a crosslinked body) disposed between the anode and first organic layer. At least one phosphorescent compound contained in the first and second organic layers is the same phosphorescent compound and is represented by the formula (1): wherein M may be an iridium atom, n1 represents an integer of 1 or more, n2 may be 0 or more, E1 and E2 may be a carbon atom, ring L1 represents an aromatic heterocyclic ring, ring L2 may be an aromatic hydrocarbon ring, A1-G1-A2 represents an anionic bidentate ligand, and at least one of rings L1 and L2 has an aryl group, a monovalent heterocyclic group or a substituted amino group.
    Type: Grant
    Filed: May 22, 2015
    Date of Patent: October 1, 2019
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Makoto Anryu, Nobuhiko Akino
  • Publication number: 20190185500
    Abstract: A metal complex represented by formula (1) is provided. In formula (1), X represents a nitrogen atom or a group represented by ?C(RX)—; R1 represents an alkyl group having 4 or more carbon atoms; R2 represents an alkyl, cycloalkyl, alkoxy, cycloalkoxy, aryl, aryloxy, monovalent heterocyclic, or substituted amino group or a halogen atom; rings A and B each independently represent an aromatic hydrocarbon ring or an aromatic heterocyclic ring; M represents a rhodium, palladium, iridium, or platinum atom; n1 represents an integer of 1 or more, n2 represents an integer of 0 or more, and n1+n2 is 2 or 3; A1-G1-A2 represents an anionic bidentate ligand; A1 and A2 each independently represent a carbon atom, an oxygen atom, or a nitrogen atom; and G1 represents a single bond or an atomic group constituting a bidentate ligand together with A1 and A2.
    Type: Application
    Filed: March 30, 2017
    Publication date: June 20, 2019
    Inventors: Mayu YOSHIOKA, Taichi ABE, Toshiaki SASADA, Kohei ASADA, Nobuhiko AKINO
  • Publication number: 20190048131
    Abstract: Provided is a light-emitting device including an anode, a light-emitting layer, an electron-transporting layer and a cathode. The electron-transporting layer contains at least one electron-transporting material whose LUMO level is ?3.0 eV or more and at least one dopant material selected from the group consisting of a heterocyclic compound whose SOMO level is ?2.2 to ?1.5 eV and a derivative thereof. The LUMO level of the electron-transporting material is smaller than the SOMO level of the heterocyclic compound.
    Type: Application
    Filed: March 21, 2017
    Publication date: February 14, 2019
    Inventors: Takayuki IIJIMA, Satoshi KOBAYASHI, Masanobu TANAKA, Nobuhiko AKINO, Sheena ZUBERI
  • Patent number: 10128449
    Abstract: A metal complex represented by the following formula (1) is provided. In formula (1), M represents an iridium atom or a platinum atom; n1 represents 1, 2 or 3. n2 represents 0, 1 or 2; E1 to E4 represent a nitrogen atom or a carbon atom; R1 to R10 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryl group, an aryloxy group, a monovalent heterocyclic group or a halogen atom; Xa and Xb represent a direct bond, an oxygen atom, a sulfur atom, —C(?O)—, —CRXa2— or —NRXa—; A1-G1-A2 represents an anionic bidentate ligand; and G1 represents an atomic group constituting a bidentate ligand together with A1 and A2.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: November 13, 2018
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takakazu Saito, Yusuke Ishii, Kazuei Ohuchi, Kohei Asada, Nobuhiko Akino
  • Publication number: 20180240978
    Abstract: A light emitting device is provided which contains an anode, a cathode, and two organic layers disposed between the anode and the cathode. The first organic layer contains a phosphorescent material and the second organic layer contains a crosslinked body of a crosslinkable material and a phosphorescent material. The two phosphorescent materials contain the same phosphorescent compound represented by formula (1), and the crosslinkable material is a compound represented by formula (3): In formula (1), M represents a metal atom, n1 is ?1, n2 is ?0, E1 and E2 represent a carbon atom, L1 and L2 represent an aromatic heterocyclic ring, and A1-G1-A2 represents an anionic bidentate ligand. In formula (3), mB1 to mB3 represent an integer of ?0, Ar7 may represent an aromatic hydrocarbon group, LB1 may represent a divalent group, and X? may represent a crosslinkable group.
    Type: Application
    Filed: September 30, 2016
    Publication date: August 23, 2018
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Toshiaki SASADA, Makoto ANRYU, Nobuhiko AKINO, Takakazu SAITO
  • Patent number: 9976078
    Abstract: This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Ze of the main repeating minimum unit of the polymer falls within the following range: 0<Ze?2.00 (1) wherein the electronic conjunction chain coefficient Ze is defined as a slope obtained by linear approximation of function Tm=Tm (1/ne) by the least square method wherein ne represents the number of conjugated electrons contained in repeating minimum units; and Tm represents, for m-mer obtained by bonding repeating minimum units, the lowest triplet excitation energy in each m-mer when the number m is varied from 1 to 3 by one by one. Here in the number of conjugated electrons, only the conjugated electrons present in the main chain of the repeating minimum units are taken into consideration, provided that, when there are a plurality of main repeating minimum units, the minimum Ze is used.
    Type: Grant
    Filed: March 9, 2016
    Date of Patent: May 22, 2018
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Nobuhiko Akino, Chizu Sekine, Satoshi Mikami, Tomoya Nakatani
  • Publication number: 20170256726
    Abstract: Provided is a metal complex which is excellent in quantum yield and full width at half maximum of a light emission spectrum. The metal complex is represented by the following formula (1): wherein M represents an iridium atom or the like, n1 represents 1 to 3, n2 represents 0 to 2, X1 to X8 represent a carbon atom or the like, R1 to R8 represent a hydrogen atom or the like, one of Xa and Xb is a single bond, and the other is a group represented by —CR11R12—CR13R14—, R11 to R14 represent an alkyl group or the like, ring A represents a heteroaromatic ring, and A1-G1-A2 represents an anionic bidentate ligand.
    Type: Application
    Filed: September 9, 2015
    Publication date: September 7, 2017
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Takakazu SAITO, Yusuke ISHII, Kazuei OHUCHI, Nobuhiko AKINO, Rui ISHIKAWA
  • Patent number: 9735374
    Abstract: A metal complex exhibits blue light emission of high color purity and has a color purity of small temperature dependence, particularly in the blue region. Specifically, the metal complex is represented by Formula (1a): wherein M is a metal atom; R0 is a divalent linking group; each j independently represents 0 or 1; RP1, RP2, RP3, RP4 and RP6 each independently represents a hydrogen atom or the like; RP5 represents a halogen atom or the like; m is an integer of from 1 to 3, n is an integer of from 0 to 2, and m+n is 2 or 3; and the portion represented by Formula (2): represents a bidentate ligand; wherein Rx and Ry are an atom bonding to the metal atom M, and each independently represents a carbon atom, an oxygen atom or a nitrogen atom.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: August 15, 2017
    Assignees: SUMITOMO CHEMICAL COMPANY, LIMITED, NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Nobuhiko Akino, Taichi Abe, Hideo Konno, Shigeru Shimada, Kazuhiko Sato
  • Patent number: 9705097
    Abstract: A highly stable metal complex useful for the manufacture of a light-emitting device has an excellent lifetime property, particularly in a blue region, specifically a metal complex represented by Formula (1): wherein M is a metal atom; each R0 independently represents a divalent linking group; i and j each independently represent 0 or 1; RP1, RP2, RP3, RP4, RP5 and RP6 each independently represent a hydrogen atom and the like, with a proviso that at least one of RP1, RP2, RP3, RP4, RP5 and RP6 is a dendron; m is an integer of from 1 to 3, n is an integer of from 0 to 2, and m+n is 2 or 3; and the portion represented by Formula (2): represents a bidentate ligand; wherein Rx and Ry are an atom bonding to the metal atom M, and each independently represents a carbon atom and the like.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: July 11, 2017
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobuhiko Akino, Taichi Abe, Hideo Konno, Shigeru Shimada, Kazuhiko Sato
  • Publication number: 20170194584
    Abstract: A light emitting device excellent in luminance life includes an anode, a cathode, a first organic layer (containing at least one phosphorescent compound) disposed between the anode and cathode and a second organic layer (containing at least one phosphorescent compound and a crosslinked body) disposed between the anode and first organic layer. At least one phosphorescent compound contained in the first and second organic layers is the same phosphorescent compound and is represented by the formula (1): wherein M may be an iridium atom, n1 represents an integer of 1 or more, n2 may be 0 or more, E1 and E2 may be a carbon atom, ring L1 represents an aromatic heterocyclic ring, ring L2 may be an aromatic hydrocarbon ring, A1-G1-A2 represents an anionic bidentate ligand, and at least one of rings L1 and L2 has an aryl group, a monovalent heterocyclic group or a substituted amino group.
    Type: Application
    Filed: May 22, 2015
    Publication date: July 6, 2017
    Inventors: Makoto ANRYU, Nobuhiko AKINO
  • Patent number: 9691983
    Abstract: It is an object of the present invention to provide a composition using a polymer compound, which is useful for manufacturing a blue phosphorescent light-emitting device excellent in luminous efficiency. The present invention provides a composition including: a polymer compound substantially consisting of a constitutional unit selected from a constitutional unit represented by Formula (1)-1 below, a constitutional unit represented by Formula (1)-2 below, a constitutional unit represented by Formula (2)-1 below, a constitutional unit represented by Formula (2)-2 below, and a constitutional unit derived from a phosphorescent light-emitting compound having a light-emitting spectrum peak at smaller than 480 nm and the polymer compound containing at least both of the constitutional unit represented by Formula (1)-1 and the constitutional unit represented by Formula (1)-2; and a phosphorescent light-emitting compound having a light-emitting spectrum peak at smaller than 480 nm.
    Type: Grant
    Filed: July 13, 2011
    Date of Patent: June 27, 2017
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Masayuki Soga, Osamu Goto, Kazuei Ohuchi, Nobuhiko Akino
  • Publication number: 20160329508
    Abstract: A metal complex represented by the following formula (1) is provided. In formula (1), M represents an iridium atom or a platinum atom; n1 represents 1, 2 or 3. n2 represents 0, 1 or 2; E1 to E4 represent a nitrogen atom or a carbon atom; R1 to R10 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryl group, an aryloxy group, a monovalent heterocyclic group or a halogen atom; Xa and Xb represent a direct bond, an oxygen atom, a sulfur atom, —C(?O)—, —CRXa2— or —NRXa—; A1-G1-A2 represents an anionic bidentate ligand; and G1 represents an atomic group constituting a bidentate ligand together with A1 and A2.
    Type: Application
    Filed: December 18, 2014
    Publication date: November 10, 2016
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Takakazu SAITO, Yusuke ISHII, Kazuei OHUCHI, Kohei ASADA, Nobuhiko AKINO
  • Publication number: 20160186051
    Abstract: This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Ze of the main repeating minimum unit of the polymer falls within the following range: 0<Ze?2.00 (1) wherein the electronic conjunction chain coefficient Ze is defined as a slope obtained by linear approximation of function Tm=Tm (1/ne) by the least square method wherein ne represents the number of conjugated electrons contained in repeating minimum units; and Tm represents, for m-mer obtained by bonding repeating minimum units, the lowest triplet excitation energy in each m-mer when the number m is varied from 1 to 3 by one by one. Here in the number of conjugated electrons, only the conjugated electrons present in the main chain of the repeating minimum units are taken into consideration, provided that, when there are a plurality of main repeating minimum units, the minimum Ze is used.
    Type: Application
    Filed: March 9, 2016
    Publication date: June 30, 2016
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Nobuhiko AKINO, Chizu SEKINE, Satoshi MIKAMI, Tomoya NAKATANI
  • Patent number: 9315723
    Abstract: This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Ze of the main repeating minimum unit of the polymer falls within the following range: 0<Ze?2.00 (1) wherein the electronic conjunction chain coefficient Ze is defined as a slope obtained by linear approximation of function Tm=Tm(1/ne) by the least square method wherein ne represents the number of conjugated electrons contained in repeating minimum units; and Tm represents, for m-mer obtained by bonding repeating minimum units, the lowest triplet excitation energy in each m-mer when the number m is varied from 1 to 3 by one by one. Here in the number of conjugated electrons, only the conjugated electrons present in the main chain of the repeating minimum units are taken into consideration, provided that, when there are a plurality of main repeating minimum units, the minimum Ze is used.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: April 19, 2016
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Nobuhiko Akino, Chizu Sekine, Satoshi Mikami, Tomoya Nakatani