Patents by Inventor Nobuhiko Tsuda
Nobuhiko Tsuda has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10093775Abstract: The present invention aims to provide an aqueous dispersion that contains particles of a fluoropolymer at high concentrations and has a less variable pH, and in which aggregates are less likely to be generated even after the aqueous dispersion has been stored for a long time. The present invention relates to an aqueous dispersion, including: particles of a fluoropolymer having an average primary particle size of 0.1 to 0.5 ?m in an amount of 50 to 70% by mass; a nonionic surfactant in an amount of 2 to 10% by mass based on the amount of the fluoropolymer; and ammonium lauryl sulfate in an amount of 0.0001 to 1% by mass based on the amount of the fluoropolymer, wherein an amount of a fluorine-containing anionic surfactant is less than 10 ppm.Type: GrantFiled: October 21, 2016Date of Patent: October 9, 2018Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Nobuhiko Tsuda, Hiromichi Momose, Toshirou Miura
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Patent number: 10047175Abstract: The present invention provides an aqueous dispersion of a low-molecular-weight polytetrafluoroethylene (PTFE), which contains an easily removable surfactant, and has a good dispersion stability. Specifically, the present invention provides an aqueous dispersion of a low-molecular-weight PTFE comprising tetrafluoroethylene (TFE) units, or TFE units and modifying monomer units which are copolymerizable with the TFE units, wherein the aqueous dispersion contains from 70 to 9,000 ppm, based on the aqueous dispersion, of a fluorine-containing compound of the formula (1) below: X—(CF2)m—Y??(1) where X is H or F; m is an integer from 3 to 5; and Y is —SO3M, —SO4M, —SO3R, —SO4R, —COOM, —PO3M2 or —PO4M2, M being H, NH4 or an alkali metal, and R being an alkyl group having 1 to 12 carbons, and the low-molecular-weight PTFE has an average primary particle size of from 100 to 350 nm.Type: GrantFiled: March 12, 2015Date of Patent: August 14, 2018Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Taku Yamanaka, Nobuhiko Tsuda, Masayuki Tsuji, Yasuhiko Sawada
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Patent number: 9624353Abstract: A nonionic surfactant composition including: a nonionic surfactant that contains a molecule having a C10-C22 alkyl group and/or alkenyl group as a hydrophobic group, a polyoxyalkylene chain as a hydrophilic group, no aromatic ring, no C9-C14 alkyl group derived from an alcohol that is produced from a higher olefin derived from a mixture of propylene and butene through an oxo process, and no C13 alkyl group derived from an alcohol that is produced from a higher olefin derived from a propylene tetramer through an oxo process. The nonionic surfactant has a hydrodynamic radius of 5.0 to 8.0 nm at 40° C. in an aqueous solution in which a nonionic surfactant concentration is 0.1 kg/L in the nonionic surfactant composition, the radius being measured by a dynamic light scattering method.Type: GrantFiled: March 27, 2013Date of Patent: April 18, 2017Assignees: DAIKIN INDUSTRIES, LTD., DAI-ICHI KOGYO SEIYAKU CO., LTD., OSAKA UNIVERSITYInventors: Nobuhiko Tsuda, Atsuko Tanaka, Kenji Adachi, Nahoko Izaki, Masayuki Hashimoto, Takahiro Sato
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Patent number: 9580590Abstract: The present invention aims to provide a novel method for producing an aqueous dispersion containing non-melt-processable polytetrafluoroethylene particles. The present invention relates to a method for producing an aqueous dispersion containing non-melt-processable polytetrafluoroethylene particles, the method including polymerizing tetrafluoroethylene in an aqueous medium in the presence of perfluoro hexanoic acid or its salt.Type: GrantFiled: August 27, 2012Date of Patent: February 28, 2017Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Takahiro Taira, Taku Yamanaka, Yoshinori Nanba, Atsuko Tanaka, Makoto Ono, Nobuhiko Tsuda, Taketo Kato
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Publication number: 20170037195Abstract: The present invention aims to provide an aqueous dispersion that contains particles of a fluoropolymer at high concentrations and has a less variable pH, and in which aggregates are less likely to be generated even after the aqueous dispersion has been stored for a long time. The present invention relates to an aqueous dispersion, including: particles of a fluoropolymer having an average primary particle size of 0.1 to 0.5 ?m in an amount of 50 to 70% by mass; a nonionic surfactant in an amount of 2 to 10% by mass based on the amount of the fluoropolymer; and ammonium lauryl sulfate in an amount of 0.0001 to 1% by mass based on the amount of the fluoropolymer, wherein an amount of a fluorine-containing anionic surfactant is less than 10 ppm.Type: ApplicationFiled: October 21, 2016Publication date: February 9, 2017Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Nobuhiko TSUDA, Hiromichi MOMOSE, Toshirou MIURA
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Publication number: 20150329701Abstract: A nonionic surfactant composition including: a nonionic surfactant that contains a molecule having a C10-C22 alkyl group and/or alkenyl group as a hydrophobic group, a polyoxyalkylene chain as a hydrophilic group, no aromatic ring, no C9-C14 alkyl group derived from an alcohol that is produced from a higher olefin derived from a mixture of propylene and butene through an oxo process, and no C13 alkyl group derived from an alcohol that is produced from a higher olefin derived from a propylene tetramer through an oxo process. The nonionic surfactant has a hydrodynamic radius of 5.0 to 8.0 nm at 40° C. in an aqueous solution in which a nonionic surfactant concentration is 0.1 kg/L in the nonionic surfactant composition, the radius being measured by a dynamic light scattering method.Type: ApplicationFiled: March 27, 2013Publication date: November 19, 2015Applicants: DAIKIN INDUSTRIES, LTD., OSAKA UNIVERSITY, DAI-ICHI KOGYO SEIYAKU CO., LTD.Inventors: Nobuhiko TSUDA, Atsuko TANAKA, Kenji ADACHI, Nahoko IZAKI, Masayuki HASHIMOTO, Takahiro SATO
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Patent number: 9109095Abstract: The present invention provides an organosol composition that is stable even in the case that the PTFE particle content is high. The present invention relates to an organosol composition of PTFE particles, comprising PTFE particles (A), a polymer (B), and an organic solvent (S), wherein (1) the polymer (B) is soluble in the organic solvent (S), (2) the amount of the PTFE particles (A) is not lower than 50% by mass of the total amount of the PTFE particles (A) and the polymer (B), and (3) the precipitation ratio of the PTFE particles after 48 hours is not higher than 60% when the total solids concentration of the PTFE particles (A) and the polymer (B) is 5% by mass.Type: GrantFiled: May 9, 2011Date of Patent: August 18, 2015Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Takuji Ishikawa, Atsuko Tanaka, Taku Yamanaka, Nobuhiko Tsuda, Kazunobu Uchida, Takahiro Kitahara, Tomoyuki Fukatani
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Patent number: 9096701Abstract: The present invention provides a tetrafluoroethylene polymer aqueous dispersion obtained by carrying out a TFE polymerization in an aqueous medium in the presence of a fluorovinyl group-containing emulsifier, wherein the TFE polymer aqueous dispersion contains a particle comprising a TFE polymer dispersed in the aqueous medium, the fluorovinyl group-containing emulsifier comprises a fluorovinyl group-containing compound, and the TFE polymer aqueous dispersion has a fluorine-containing surfactant content of not higher than 1000 ppm by mass.Type: GrantFiled: August 30, 2012Date of Patent: August 4, 2015Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Nobuhiko Tsuda, Yoshinori Nanba, Yasuhiko Sawada, Tetsuo Shimizu
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Patent number: 9080035Abstract: The present invention provides an aqueous fluoropolymer dispersion that shows favorable dispersion stability and is less likely to have a pH decrease even after storage for a long period of time. The present invention provides an aqueous fluoropolymer dispersion including: a fluoropolymer; a fluorine free surfactant; at least one organic electrolyte selected from the group consisting of hydroxy monocarboxylic acids, hydroxy dicarboxylic acids, tricarboxylic acids, and amino acids; and a fluorine-containing anionic surfactant containing not more than 7 carbon atoms.Type: GrantFiled: March 29, 2012Date of Patent: July 14, 2015Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Kenjiro Tanimoto, Junya Iida, Takeshi Shimono, Takayuki Hirao, Nobuhiko Tsuda, Taketo Kato
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Publication number: 20150183898Abstract: The present invention provides an aqueous dispersion of a low-molecular-weight polytetrafluoroethylene (PTFE), which contains an easily removable surfactant, and has a good dispersion stability. Specifically, the present invention provides an aqueous dispersion of a low-molecular-weight PTFE comprising tetrafluoroethylene (TFE) units, or TFE units and modifying monomer units which are copolymerizable with the TFE units, wherein the aqueous dispersion contains from 70 to 9,000 ppm, based on the aqueous dispersion, of a fluorine-containing compound of the formula (1) below: X—(CF2)m—Y??(1) where X is H or F; m is an integer from 3 to 5; and Y is —SO3M, —SO4M, —SO3R, —SO4R, —COOM, —PO3M2 or —PO4M2, M being H, NH4 or an alkali metal, and R being an alkyl group having 1 to 12 carbons, and the low-molecular-weight PTFE has an average primary particle size of from 100 to 350 nm.Type: ApplicationFiled: March 12, 2015Publication date: July 2, 2015Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Taku YAMANAKA, Nobuhiko TSUDA, Masayuki TSUJI, Yasuhiko SAWADA
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Publication number: 20150065624Abstract: The present invention aims to provide an aqueous dispersion that contains particles of a fluoropolymer at high concentrations and has a less variable pH, and in which aggregates are less likely to be generated even after the aqueous dispersion has been stored for a long time. The present invention relates to an aqueous dispersion, including: particles of a fluoropolymer having an average primary particle size of 0.1 to 0.5 ?m in an amount of 50 to 70% by mass; a nonionic surfactant in an amount of 2 to 10% by mass based on the amount of the fluoropolymer; and ammonium lauryl sulfate in an amount of 0.0001 to 1% by mass based on the amount of the fluoropolymer, wherein an amount of a fluorine-containing anionic surfactant is less than 10 ppm.Type: ApplicationFiled: March 27, 2013Publication date: March 5, 2015Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Nobuhiko Tsuda, Hiromichi Momose, Toshirou Miura
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Patent number: 8969437Abstract: The invention provides a compound which is useful in production of a fluoropolymer and easy to be removed from the produced fluoropolymer, a method of producing the compound, and a method of producing a fluoropolymer using the compound. The invention provides a compound which is represented by Rf1—CH2O—CF2—CHF—Rf2—X, wherein Rf1 represents a fluoroalkyl group containing 1 to 5 carbon atoms, Rf2 represents a fluoroalkylene group containing 1 to 3 carbon atoms, X represents —COOM or —SO3M, and M represents one of H, K, Na, and NH4.Type: GrantFiled: January 18, 2013Date of Patent: March 3, 2015Assignee: Daikin Industries, Ltd.Inventors: Nobuhiko Tsuda, Akinari Sugiyama
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Publication number: 20140200310Abstract: The present invention aims to provide a novel method for producing an aqueous dispersion containing non-melt-processable polytetrafluoroethylene particles. The present invention relates to a method for producing an aqueous dispersion containing non-melt-processable polytetrafluoroethylene particles, the method including polymerizing tetrafluoroethylene in an aqueous medium in the presence of perfluoro hexanoic acid or its salt.Type: ApplicationFiled: August 27, 2012Publication date: July 17, 2014Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Takahiro Taira, Taku Yamanaka, Yoshinori Nanba, Atsuko Tanaka, Makoto Ono, Nobuhiko Tsuda, Taketo Kato
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Publication number: 20140031469Abstract: The present invention provides an aqueous fluoropolymer dispersion that shows favorable dispersion stability and is less likely to have a pH decrease even after storage for a long period of time. The present invention provides an aqueous fluoropolymer dispersion including: a fluoropolymer; a fluorine free surfactant; at least one organic electrolyte selected from the group consisting of hydroxy monocarboxylic acids, hydroxy dicarboxylic acids, tricarboxylic acids, and amino acids; and a fluorine-containing anionic surfactant containing not more than 7 carbon atoms.Type: ApplicationFiled: March 29, 2012Publication date: January 30, 2014Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Kenjiro Tanimoto, Junya Iida, Takeshi Shimono, Takayuki Hirao, Nobuhiko Tsuda, Taketo Kato
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Patent number: 8540901Abstract: The present invention provides an aqueous fluororesin dispersion comprising a melt-processable fluororesin which is low in fluorinated surfactant concentration and excellent in dispersion stability even when the concentration of the melt-processable fluororesin is high. The present invention is related to an aqueous fluororesin dispersion comprising a melt-processable fluororesin particle dispersed in an aqueous medium, wherein a concentration of the melt-processable fluororesin is 55 to 75% by mass relative to the aqueous fluororesin dispersion, and a fluorinated surfactant content in the aqueous fluororesin dispersion is not higher than a level corresponding to 100 ppm of the melt-processable fluororesin.Type: GrantFiled: December 8, 2011Date of Patent: September 24, 2013Assignee: Daikin Industries, Ltd.Inventors: Chie Sawauchi, Nobuhiko Tsuda
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Patent number: 8399703Abstract: The invention provides a compound which is useful in production of a fluoropolymer and easy to be removed from the produced fluoropolymer, a method of producing the compound, and a method of producing a fluoropolymer using the compound. The invention provides a compound which is represented by Rf1—CH2O—CF2—CHF—Rf2—X, wherein Rf1 represents a fluoroalkyl group containing 1 to 5 carbon atoms, Rf2 represents a fluoroalkylene group containing 1 to 3 carbon atoms, X represents —COOM or —SO3M, and M represents one of H, K, Na, and NH4.Type: GrantFiled: July 24, 2008Date of Patent: March 19, 2013Assignee: Daikin Industries, Ltd.Inventors: Nobuhiko Tsuda, Akinari Sugiyama
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Patent number: 8362168Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.Type: GrantFiled: August 8, 2011Date of Patent: January 29, 2013Assignee: Daikin Industries, Ltd.Inventors: Chie Sawauchi, Nobuhiko Tsuda
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Publication number: 20120322941Abstract: The present invention provides a tetrafluoroethylene polymer aqueous dispersion obtained by carrying out a TFE polymerization in an aqueous medium in the presence of a fluorovinyl group-containing emulsifier, wherein the TFE polymer aqueous dispersion contains a particle comprising a TFE polymer dispersed in the aqueous medium, the fluorovinyl group-containing emulsifier comprises a fluorovinyl group-containing compound, and the TFE polymer aqueous dispersion has a fluorine-containing surfactant content of not higher than 1000 ppm by mass.Type: ApplicationFiled: August 30, 2012Publication date: December 20, 2012Applicant: DAIKIN INDUSTRIES, LTD.Inventors: Nobuhiko TSUDA, Yoshinori NANBA, Yasuhiko SAWADA, Tetsuo SHIMIZU
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Patent number: 8299155Abstract: An object of the present invention is to provide an aqueous fluoropolymer dispersion inhibited from viscosity rising and excellent in mechanical stability in spite of a low fluorinated surfactant concentration. The invention provides an aqueous fluoropolymer dispersion comprising particles of a fluoropolymer as dispersed in an aqueous medium wherein a fluorinated surfactant (A) having a molecular weight lower than 1000 amounts to not higher than 100 ppm of the mass of the fluoropolymer, the aqueous fluoropolymer dispersion containing an anionic surfactant (B) other than the fluorinated surfactant (A) as well as a water-soluble polymer (C).Type: GrantFiled: February 24, 2011Date of Patent: October 30, 2012Assignee: Daikin Industries, Ltd.Inventors: Chie Sawauchi, Nobuhiko Tsuda, Wade Martin Simpson
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Patent number: 8202955Abstract: The present invention provides an aqueous fluoropolymer dispersion having good mechanical characteristics and storage stability and containing substantially no fluorinated surfactant. The present invention is related to an aqueous fluoropolymer dispersion comprising a dispersed fluoropolymer particle with an average primary particle diameter of 50 to 400 nm, a surface layer of the dispersed fluoropolymer particle being obtained by emulsion polymerization of a monomer composition consisting of 99.999 to 98 mole percent of tetrafluoroethylene and 0.001 to 2 mole percent of a modifier monomer, a fluorinated surfactant content being not higher than 50 ppm, a fluoropolymer content being 20 to 75% by mass, and a nonfluorinated nonionic surfactant content being 2 to 15% by mass relative to 100% by mass of the fluoropolymer.Type: GrantFiled: July 5, 2007Date of Patent: June 19, 2012Assignee: Daikin Industries, Ltd.Inventors: Chie Sawauchi, Nobuhiko Tsuda