Abstract: Provided are: a modified sulfide solid electrode containing a sulfide solid electrolyte having a BET specific surface area of 10 m2/g or more and containing a lithium atom, a sulfur atom, a phosphorus atom, and a halogen atom, and an epoxy compound, in which the modified sulfide solid electrolyte has a peak at 2800 to 3000 cm?1 in an infrared absorption spectrum obtained by FT-IR spectroscopy (ATR method); and a method for producing the modified sulfide solid electrolyte, which has excellent coating suitability when applied as a paste and is capable of efficiently exhibiting excellent battery performance even when a sulfide solid electrolyte having a large specific surface area is used.

Abstract: An object of the present invention is to provide a method of producing a modified sulfide solid electrolyte in which ionic conductivity reduction is suppressed, and a generation amount of a hydrogen sulfide gas is reduced even if a sulfide solid electrolyte comes in contact with moisture and hydrogen sulfide is generated, and the modified sulfide solid electrolyte, and an electrode combined material and a lithium ion battery using the same. The modified sulfide solid electrolyte producing method according to the present invention includes mixing the sulfide solid electrolyte with Li2S, in which (100-?) parts by mass of the sulfide solid electrolyte is used per a parts by mass of Li2S (a represents a number of 0.3 to 15.0).

Abstract: Provided are a method of manufacturing a modified sulfide solid electrolyte, which is excellent in coating suitability when applied as a paste even if a sulfide solid electrolyte has a large specific surface area, and can efficiently exhibit an excellent battery performance, the modified sulfide solid electrolyte obtained by the manufacturing method, and an electrode combined material and a lithium ion battery which exhibit an excellent battery performance. The method includes: mixing an organic halide and an organic solvent with a sulfide solid electrolyte having a BET specific surface area of 10 m2/g or more and containing a lithium atom, a sulfur atom, a phosphorus atom, and a halogen atom; and removing the organic solvent.

Abstract: Disclosed is a method for producing a sulfide solid electrolyte including a step of processing a slurry by at least one treatment selected from drying and heating, wherein a solid electrolyte raw material containing a lithium element, a sulfur element, a phosphorus element and a halogen element, and a complexing agent are mixed in a reactor to give a complex slurry containing a complex formed of the solid electrolyte raw material and the complexing agent, and the complex slurry is transferred into an intermediate tank equipped with a cooling device and cooled therein.

Abstract: A sulfide solid electrolyte, which is able to adjust the morphology unavailable traditionally, or is readily adjusted so as to have a desired morphology, the sulfide solid electrolyte having a volume-based average particle diameter measured by laser diffraction particle size distribution measurement of 3 ?m or more and a specific surface area measured by the BET method of 20 m2/g or more; and a method of treating a sulfide solid electrolyte including the sulfide solid electrolyte being subjected to at least one mechanical treatment selected from disintegration and granulation.

Abstract: A sulfide solid electrolyte, which is able to adjust the morphology unavailable traditionally, or is readily adjusted so as to have a desired morphology, the sulfide solid electrolyte having a volume-based average particle diameter measured by laser diffraction particle size distribution measurement of 3 ?m or more and a specific surface area measured by the BET method of 20 m2/g or more; and a method of treating a sulfide solid electrolyte including the sulfide solid electrolyte being subjected to at least one mechanical treatment selected from disintegration and granulation.

Abstract: The present invention provides a production method of a solid electrolyte containing a lithium element, a sulfur element, a phosphorous element, and a halogen element, wherein the solid electrolyte has a high ionic conductivity and capable of suppressing hydrogen sulfide by adopting a liquid-phase method, wherein the method includes mixing a complexing agent having an ester group and also having at least one branch with a solid electrolyte raw material. The present invention also relates to an electrolyte precursor.

Abstract: Disclosed is a method for producing a sulfide solid electrolyte including a step of processing a slurry by at least one treatment selected from drying and heating, wherein a solid electrolyte raw material containing a lithium element, a sulfur element, a phosphorus element and a halogen element, and a complexing agent are mixed in a reactor to give a complex slurry containing a complex formed of the solid electrolyte raw material and the complexing agent, and the complex slurry is transferred into an intermediate tank equipped with a cooling device and cooled therein.

Abstract: A solid electrolyte contains a thio-LISICON Region II-type crystal structure, where the solid electrolyte does not contain P2S64? structure. A solid electrolyte, where: (1) a signal of a thio-LISICON Region II-type crystal structure is observed in the solid 31P-NMR spectrometry, and (2) a signal of a P2S64? structure is not observed in the solid 31P-NMR spectrometry.

Abstract: A method of producing a solid electrolyte having a high ionic conductivity, which adopts a liquid-phase method and suppresses the generation of hydrogen sulfide, wherein a raw material inclusion containing a lithium element, a sulfur element, a phosphorus element, and a halogen element is mixed with a complexing agent containing a compound having at least two tertiary amino groups; and an electrolyte precursor constituted of a lithium element, a sulfur element, a phosphorus element, a halogen element, and a complexing agent containing a compound having at least two tertiary amino groups.

Abstract: A method of producing a solid electrolyte having a high ionic conductivity, which adopts a liquid-phase method and suppresses the generation of hydrogen sulfide, wherein a raw material inclusion containing a lithium element, a sulfur element, a phosphorus element, and a halogen element is mixed with a complexing agent containing a compound having at least two tertiary amino groups; and an electrolyte precursor constituted of a lithium element, a sulfur element, a phosphorus element, a halogen element, and a complexing agent containing a compound having at least two tertiary amino groups.

Abstract: A sulfide solid electrolyte, which is able to adjust the morphology unavailable traditionally, or is readily adjusted so as to have a desired morphology, the sulfide solid electrolyte having a volume-based average particle diameter measured by laser diffraction particle size distribution measurement of 3 ?m or more and a specific surface area measured by the BET method of 20 m2/g or more; and a method of treating a sulfide solid electrolyte including the sulfide solid electrolyte being subjected to at least one mechanical treatment selected from disintegration and granulation.