Abstract: A method of preparing a solid electrolyte and an all-solid battery including a solid electrolyte prepared by the method, the method including: contacting a first solvent and a first starting material comprising an alkali metal, sulfur, phosphorus, an element M, or a combination thereof to form a first solution; precipitating a first precursor from the first solution; contacting a second solvent, the first precursor, and a second starting material comprising an alkali metal, sulfur, phosphorus, an element M, or a combination thereof to form a second solution; precipitating a second precursor from the second solution; and heat treating the second precursor to prepare the solid electrolyte, wherein the element M comprises an element of Group 14 of the Periodic Table of the Elements, and the element M and the alkali metal in the first starting material and the second starting material are the same or different.

Abstract: A method of preparing a sulfide solid electrolyte, the method including: first contacting a starting materials including Li2S, P2S5, and LiI in a first solvent to provide a precursor; and second contacting the precursor with a second solvent to prepare the sulfide solid electrolyte, wherein the first solvent includes a C1-C3 alkyl group or a cyclic ether compound which is unsubstituted or substituted with a C1-C3 alkoxy group, and the second solvent includes a C1-C10 hydrocarbon substituted with a C1 to C6 alkoxy group.

Abstract: A method of preparing a solid electrolyte and an all-solid battery including a solid electrolyte prepared by the method, the method including: contacting a first solvent and a first starting material comprising an alkali metal, sulfur, phosphorus, an element M, or a combination thereof to form a first solution; precipitating a first precursor from the first solution; contacting a second solvent, the first precursor, and a second starting material comprising an alkali metal, sulfur, phosphorus, an element M, or a combination thereof to form a second solution; precipitating a second precursor from the second solution; and heat treating the second precursor to prepare the solid electrolyte, wherein the element M comprises an element of Group 14 of the Periodic Table of the Elements, and the element M and the alkali metal in the first starting material and the second starting material are the same or different.

Abstract: A method of preparing a sulfide solid electrolyte, the method including: first contacting a starting materials including Li2S, P2S5, and LiI in a first solvent to provide a precursor; and second contacting the precursor with a second solvent to prepare the sulfide solid electrolyte, wherein the first solvent includes a C1-C3 alkyl group or a cyclic ether compound which is unsubstituted or substituted with a C1-C3 alkoxy group, and the second solvent includes a C1-C10 hydrocarbon substituted with a C1 to C6 alkoxy group.

Abstract: A lithium battery and a method of preparing the lithium battery, wherein the lithium battery includes: a cathode layer including a cathode active material including a core, and an ion conductive phosphate coating layer on a surface of the core; an anode layer; and a solid electrolyte layer that is disposed between the cathode layer and the anode layer, wherein the solid electrolyte layer includes a sulfide solid electrolyte.

Abstract: A sulfide solid electrolyte including a sulfide product prepared by mixing at least Li2S and P2S5 in an organic solvent, wherein the organic solvent includes a tetrahydrofuran compound optionally substituted with a C1-C6 hydrocarbon group or a C1-C6 hydrocarbon group including an ether group, or a C2-C7 non-cyclic ether compound.

Abstract: A lithium battery and a method of preparing the lithium battery, wherein the lithium battery includes: a cathode layer including a cathode active material including a core, and an ion conductive phosphate coating layer on a surface of the core; an anode layer; and a solid electrolyte layer that is disposed between the cathode layer and the anode layer, wherein the solid electrolyte layer includes a sulfide solid electrolyte.