Abstract: Curable film-forming sol-gel compositions that are essentially free of inorganic oxide particles are provided. The compositions contain: a tetraalkoxysilane; a solvent component; and non-oxide particles, and further contain either i) a mineral acid or ii) an epoxy functional trialkoxysilane and a metal-containing catalyst. Coated articles demonstrating antiglare properties are also provided, comprising: (a) a substrate having at least one surface; and (b) a cured film-forming composition applied thereon, formed from a curable sol-gel composition comprising a silane and non-oxide particles. A method of forming an antiglare coating on a substrate is also provided.

Abstract: Curable film-forming sol-gel compositions that are essentially free of inorganic oxide particles are provided. The compositions contain: a tetraalkoxysilane; a solvent component; and non-oxide particles, and further contain either i) a mineral acid or ii) an epoxy functional trialkoxysilane and a metal-containing catalyst. Coated articles demonstrating antiglare properties are also provided, comprising: (a) a substrate having at least one surface; and (b) a cured film-forming composition applied thereon, formed from a curable sol-gel composition comprising a silane and non-oxide particles. A method of forming an antiglare coating on a substrate is also provided.

Abstract: The invention includes a method of preparing an aqueous dispersion of particles at least partially encapsulated by a polymer, the method comprising dispersing inorganic particles in an aqueous phase; functionalizing at least a portion of the surfaces of the inorganic particles with a coupling agent, the coupling agent having pendent reactive groups; polymerizing the reactive groups on the functionalized particles with a first polymerizable component to produce inner polymer shells surrounding the inorganic particles; polymerizing a second polymerizable component to form outer polymer shells at least partially encapsulating the inner polymer shells; and producing voids within the outer polymer shells, such that the inorganic particles are received within the voids.

Abstract: Curable film-forming sol-gel compositions that are essentially free of inorganic oxide particles are provided. The compositions contain: a tetraalkoxysilane; a solvent component; and non-oxide particles, and further contain either i) a mineral acid or ii) an epoxy functional trialkoxysilane and a metal-containing catalyst. Coated articles demonstrating antiglare properties are also provided, comprising: (a) a substrate having at least one surface; and (b) a cured film-forming composition applied thereon, formed from a curable sol-gel composition comprising a silane and non-oxide particles. A method of forming an antiglare coating on a substrate is also provided.

Abstract: The invention includes a method of preparing an aqueous dispersion of particles at least partially encapsulated by a polymer, the method comprising dispersing inorganic particles in an aqueous phase; functionalizing at least a portion of the surfaces of the inorganic particles with a coupling agent, the coupling agent having pendent reactive groups; polymerizing the reactive groups on the functionalized particles with a first polymerizable component to produce inner polymer shells surrounding the inorganic particles; polymerizing a second polymerizable component to form outer polymer shells at least partially encapsulating the inner polymer shells; and producing voids within the outer polymer shells, such that the inorganic particles are received within the voids.

Abstract: Disclosed herein are adhesive compositions comprising (a) a first component; (b) a second component that chemically reacts with said first component; and (c) graphenic carbon particles having a compressed density of 0.9 or less. Disclosed herein are associated methods for forming the adhesive compositions and applying the adhesive compositions to a substrate to form a bonded substrate.

Abstract: Disclosed herein are adhesive compositions comprising (a) a first component; (b) a second component that chemically reacts with said first component; and (c) graphenic carbon particles having a compressed density of 0.9 or less. Disclosed herein are associated methods for forming the adhesive compositions and applying the adhesive compositions to a substrate to form a bonded substrate.

Abstract: A method of producing a radiation diffractive sensor that diffracts radiation according to Bragg's law is disclosed. The sensor is produced by forming an ordered periodic array of particles on a substrate, coating the array of particles with a polymeric matrix, curing the matrix to fix the array of particles within the matrix and contacting the fixed array with an activator, wherein the activator shifts the wavelength of radiation diffracted by the sensor from a first wavelength to a second wavelength.

Abstract: A method of producing a radiation diffractive sensor that diffracts radiation according to Bragg's law is disclosed. The sensor is produced by forming an ordered periodic array of particles on a substrate, coating the array of particles with a polymeric matrix, curing the matrix to fix the array of particles within the matrix and contacting the fixed array with an activator, wherein the activator shifts the wavelength of radiation diffracted by the sensor from a first wavelength to a second wavelength.

Abstract: An electrodepositable coating composition is provided including a resinous phase and corrosion resisting particles dispersed in an aqueous medium. Methods of preparing and using the composition also are provided.

Abstract: Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating layer is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.

Abstract: Disclosed are methods for making ultrafine silica particles in a plasma system, apparatus for making ultrafine silica particles, and coating compositions comprising ultrafine silica particles made by such methods and/or apparatus.

Abstract: An electrodepositable coating composition is provided including a resinous phase and catalyst nanoparticles dispersed in an aqueous medium, the resinous phase including (a) at least one active hydrogen-containing, ionic salt group-containing resin; and (b) at least one curing agent; and the catalyst nanoparticles for effecting cure between the resin (a) and the curing agent (b). The catalyst nanoparticles have an average BET specific surface area greater than 20 square meters per gram (m2/g). Methods of preparing and using the composition also are provided.

Abstract: Disclosed are composite transparencies and methods for their production. The colored composite transparencies include a surface at least partially coated with a transparent tinted coating deposited from a coating composition comprising polymer-enclosed color-imparting particles.

Abstract: Disclosed are ink compositions comprising a liquid vehicle and a colorant, wherein the colorant comprises polymer-enclosed color-imparting particles, wherein the particles are enclosed by a friable polymer. Also disclosed are methods for making an ink composition and methods for improving the transparency of an ink composition comprising a pigment colorant.

Abstract: Articles are disclosed wherein a color-imparting non-hiding coating layer is deposited on a surface thereof. The coating layer is deposited from a protective coating composition comprising color-imparting particles having a maximum haze of about 10% and a film-forming resin. Methods of using the coatings, and the substrates coated therewith, are also disclosed.

Abstract: A protective and decorative coating composition including about 2 to 10 different colorants which in combination with a resinous composition produce a desired visible coating. A majority of the colorants has a maximum haze of about 10% and exhibits an absorbance peak in the visible spectrum wherein at least about 50% of the total absorbance in the visible spectrum occurs at wavelengths within about 50 nm of the wavelength of the peak absorbance.

Abstract: A protective and decorative coating composition including semiconductor particulate colorants which in combination with a resinous composition produce a desired color. The colorants are semiconductor particles which exhibit sized-quantized absorption of visible light and have a particle size of up to about 12 nm.