Patents by Inventor Norbert Hasenbein

Norbert Hasenbein has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6245864
    Abstract: A copolymer of (a) from 96 to 99.6% molar of ethylene and (b) from 0.4 to 4% molar of a C3-C6-alkenoic acid or an ester thereof having not more than 14 carbon atoms or a mixture of these monomers, which copolymer may be prepared by polymerization in a continuously operated tubular reactor under a pressure of from 500 to 5,000 bar and at elevated temperature in the presence of free-radical initiators by feeding a mixture of the said reactants to the inlet port of the reactor only, restricting the temperature in a first reaction zone to approximately 240° C. and, after the temperature has dropped by from 5°to 20° C., metering further initiator to the beginning of a second reaction zone and completing the reaction at a temperature of up to 300° C.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: June 12, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Thomas Muehlenbernd, Gernot Koehler
  • Patent number: 5194509
    Abstract: In a process for the peroxide-free grafting of ethylenically unsaturated carboxylic acids, carboxylic anhydrides and/or their derivatives to a homopolymer or copolymer of ethylene having a density equal to or greater than 0.930 g/cm.sup.3, the monomers to be grafted are used in a concentration of from 0.01 to 0.5% by weight and the grafting reaction is carried out at from 210.degree. to 300.degree. C. in a conventional extruder or mixer in the absence of a free radical initiator. The graft copolymers are used for the preparation of ionomers and adhesion promoters.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: March 16, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Peter Bauer, Lothar Schlemmer, Alfred F. Hauss, Hans Gropper, Rainer Ohlinger
  • Patent number: 5189113
    Abstract: Ionically crosslinked ethylene copolymers are prepared by reacting the corresponding ethylene copolymer in a mixing zone of a twin-screw extruder with a solid metal compound and subsequently pumping in water, and are used as adhesion promoters, laminating films, injection molded articles or cable sheathing.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: February 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Muehlenbernd, Norbert Hasenbein, Gernot Koehler, Lothar Schlemmer
  • Patent number: 5189120
    Abstract: In a process for the peroxide-free grafting of ethylenically unsaturated carboxylic acids, carboxylic anhydrides and/or their derivatives to a homopolymer or copolymer of ethylene having a density less than 0.930 g/cm.sup.3, the monomers to be grafted are used in a concentration of from 0.01 to 0.5% by weight and the grafting reaction is carried out at from 210.degree. to 300.degree. C. in a conventional extruder or mixer in the absence of a free radical initiator. The graft copolymers are used for the preparation of ionomers and adhesion promoters.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: February 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Peter Bauer, Lothar Schlemmer, Alfred F. Hauss, Hans Gropper, Rainer Ohlinger
  • Patent number: 5100978
    Abstract: Polyethylene and copolymers of predominant amounts of ethylene and minor amounts of comonomers which are polymerizable with ethylene are obtainable by free radical polymerization of the monomers under from 1,500 to 5,000 bar and at from 40.degree. to 250.degree. C. by means of an initiator with virtually complete exclusion of oxygen in not less than n=3 polymerization stages, by a method in which, in the first stage, the total amount of the predominant part of the monomers are subjected to polymerization using some of the initiator required, until said polymerization comes virtually to a stop, thereafter a further part of the initiator and, if required, of the monomers are added to the mixture, which has been cooled by 20.degree.-60.degree. C., and this process is repeated in the subsequent stages until the n th stage, with the proviso that the initiators used in the (n-1) th stage have a half-life temperature of from 80.degree. to 160.degree. C.
    Type: Grant
    Filed: April 12, 1990
    Date of Patent: March 31, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Wolfgang Ball, Juergen Schmidt-Theummes, Gernot Koehler
  • Patent number: 5003001
    Abstract: Ionically crosslinked ethylene copolymers prepared by mixing a carboxyl-containing copolymer with an aqueous metal salt solution in the reaction zone of a twin-screw extruder and transferring the product to a devolatilization zone, and are used as adhesion promoters, injection molded articles or laminating films.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: March 26, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Lothar Schlemmer, Thomas Muehlenbernd, Gernot Koehler
  • Patent number: 4996259
    Abstract: Aqueous synthetic wax dispersions which contain, as an essential component of the solid substance, a partially or completely neutralized copolymer of a C.sub.2 -C.sub.4 -olefin and an unsaturated mono- or dicarboxylic acid or dicarboxylic anhydride are prepared by neutralizing and dispersing the solid substance in an aqueous medium at above the melting point of the copolymer, by a method in which the processes of neutralization and of dispersion are carried out in one extruder or in a plurality of extruders connected in series.
    Type: Grant
    Filed: August 23, 1989
    Date of Patent: February 26, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Gernot Koehler, Juergen Schmidt-Thuemmes, Norbert Hasenbein, Lothar Schlemmer, Wolfram Dietsche
  • Patent number: 4956414
    Abstract: Ionically crosslinked ethylene coolymers prepared by neutralizing the corresponding ethylene copolymers with the addition of an ionomer to a feed zone of an extruder of an ethylene high pressure polymerization system are used for film production, for cable sheathing and as adhesion promoters.
    Type: Grant
    Filed: June 9, 1989
    Date of Patent: September 11, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Muehlenbernd, Norbert Hasenbein
  • Patent number: 4948850
    Abstract: A high molecular weight ethylene copolymer is prepared by high-pressure copolymerization of ethylene with an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, carboxylic anhydride or a derivative thereof in the presence of a tertiary organic monoamine, preferably from 10 to 100 mol % thereof, based on the unsaturated carboxylic acid used, and can be used for preparing adhesion promoters and cable sheathing.
    Type: Grant
    Filed: January 5, 1990
    Date of Patent: August 14, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Thomas Muehlenbernd, Gernot Koehler
  • Patent number: 4935476
    Abstract: A high molecular weight ethylene copolymer is prepared by high-pressure copolymerization of ethylene with an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, carboxylic anhydride or a derivative thereof in the presence of a tertiary organic monoamine, preferably from 10 to 100 mol % thereof, based on the unsaturated carboxylic acid used, and can be used for preparing adhesion promoters and cable sheathing.
    Type: Grant
    Filed: August 30, 1989
    Date of Patent: June 19, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Hasenbein, Thomas Muehlenbernd, Gernot Koehler
  • Patent number: 4906690
    Abstract: Ethylenically unsaturated carboxylic acids and/or carboxylic anhydrides are grafted onto polyolefin blends by a process in which the polyolefin blend consists of from 5 to 49 parts by weight of an ethylene/propylene block copolymer having an ethylene content of less than or equal to 20% by weight and from 51 to 95 parts by weight of a homopolymer or copolymer of ethylene, and the resulting graft copolymer blends are used as adhesion promoters, in particular for polyethylene/adhesion promotor/steel composites, and for the preparation of ionomers.
    Type: Grant
    Filed: January 4, 1989
    Date of Patent: March 6, 1990
    Assignee: Basf Aktiengesellschaft
    Inventors: Norbert Hasenbein, Guenther Schweier, Hans Gropper, Rainer A. Werner