Abstract: Radically polymerizable dental material which contains at least one radically polymerizable oligomer or polymer with strongly acidic groups, which has a number-average molecular weight of 1,000 to 200,000 g/mol.

Abstract: ?-Ketophosphonic acid according to general formula I: in which A=an aliphatic C1-C18 radical which can be interrupted by —O—, —S—, —CO—O— or —O—CO—C—; n=1, 2, 3 or 4; m=1 or 2; X=absent or a C1-C10 radical which can be interrupted by —O—, —S—, —CO—C—, —O—CO—NH— or —CO—NR1—, wherein R1 is H or C1-C7-alkyl; and PG=a group which can undergo free radical polymerization. The ?-ketophosphonic acids are suitable in particular for the preparation of dental materials.

Abstract: Acidic monomer according to Formula I: in which A is a linear or branched aliphatic C1-C18-hydrocarbon group, which can be interrupted by one or more —O—, —S—, —CO—O—, —O—CO—NH—, —HN—CO—NH— or —CO—NR1—; R1 is H or a C1-C6 alkyl group; X is absent or is a linear or branched aliphatic C1-C10 hydrocarbon group, which can be interrupted by one or more —O—, —S—, —CO—O—, —O—CO—NH—, —HN—CO—NH— or —CO—NR2—; R2 is H or a C1-C6 alkyl group; PG is a radically polymerizable group, preferably vinyl, allyl, CH2?CR3—CO—Y— or R4O—CO—C(?CH2)—CH2—Y—; Y?O or NR5 or is absent; R3 is H or CH3; R4 is H or a C1-C7 alkyl group; R5 is H or a C1-C7 alkyl group; n is 1, 2, 3 or 4; m=1 or 2; p=1, 2 or 3; and q=1, 2 or 3. The monomers are particularly suitable as components of dental material.

Abstract: Radically polymerizable dental material which contains (a) at least one polyfunctional radically polymerizable monomer, (b) at least one further radically polymerizable monomer which can be monofunctional or polyfunctional, (c) at least one photoinitiator for the radical polymerization and (d) at least one filler. The material is characterized in that the mixture of the monomers (a) and (b) has a refractive index of from 1.50 to 1.70 and in that the refractive index of the monomer mixture before the curing corresponds to the refractive index of the filler used or is higher by up to 0.013 and after the curing is higher than the refractive index of the filler by at least 0.02.

Abstract: Radically polymerizable dental material, which contains at least one compound of Formula I: The material preferably additionally contains a radically polymerizable monomer, an initiator for the radical polymerization and filler. It is characterized by a low polymerization contraction stress.

Abstract: Radically polymerizable dental material, which contains at least one compound of Formula I: and at least one thermolabile radically polymerizable compound and/or at least one photolabile radically polymerizable compound. The materials are characterized by debonding-on-demand properties.

Abstract: The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l??Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2?CR1—CO—O— and CH2?CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing

Abstract: Monomer mixture for the preparation of dental materials, which contains at least one low-volatile monomethacrylate, at least one highly viscous polyfunctional methacrylate and at least one low-viscosity polyfunctional methacrylate.

Abstract: Radically polymerizable dental material which contains as initiator for the radical polymerization a combination of a thiourea derivative and a bisacyldialkylgermanium compound.

Abstract: Radically polymerizable dental material which contains at least one radically polymerizable oligomer or polymer with strongly acidic groups, which has a number-average molecular weight of 1,000 to 200,000 g/mol.

Abstract: Dental material, which contains an ene compound with two or more C—C multiple bonds and a thiol according to general Formula (1) or an oligomer based on such a thiol, wherein n, p and m are chosen such that the thiol has a total of at least 3 SH groups.

Abstract: The invention relates to a composition with at least one polymerizable binder, wherein the composition contains a photoinitiator mixture which contains (a) at least one diacylgermanium compound of general formula (I) in which R1, R2 independently of each other are a linear C1-4-alkyl, or C2-4-alkenyl radical, which can be substituted by one or more polymerizable groups; R3, R4 independently of each other are in each case H, halogen, a branched or linear C1-4-alkyl or —O—C1-4-alkyl radical; R5, R6, R7 independently of each other are in each case H, halogen, a linear C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, which can be interrupted by one or more —O—, —S— or —NR8— radicals and substituted by one or more polymerizable groups; and R8 independently is in each case H, a C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, (b) at least one ?-diketone and (c) at least one accelerator, as well as the use of the composition for example for producing a filling composite.

Abstract: The invention relates to a dental restorative material on the basis of at least one compound of one of the Formulae The invention also relates to the use of the dental restorative materials according to the invention for preparing dental composites, preferably composite blanks, which are suitable in particular for mechanical processing by means of computer-aided processing techniques such as milling and grinding processes, and which are suitable above all for preparing dental restoration materials such as inlays, onlays, crowns, bridges or veneering materials.

Abstract: A process for the preparation of a ceramic or glass ceramic shaped article using stereolithography and using a slip based on a radically polymerizable binder, polymerization initiator and filler, which comprises (A) at least one acidic monomer of general formula I (B) photoinitiator, and (C) ceramic and/or glass ceramic particles.

Abstract: Dental material which contains a polymerizable phthalic acid derivative of the general Formula I: with R1=H, methyl or a C1-C5 alkyl residue; R2=H, a phenyl, benzyl or C1-C8 alkyl residue; Q1=is absent or is a C1-C15 alkylene residue, wherein the carbon chain can be interrupted by O or S; Q2=is absent or a (n+1)-valent aliphatic C1-C20 residue, wherein the carbon chain can be interrupted by O or S and wherein Q1 and Q2 cannot be absent simultaneously; X=is absent, is O, S or (—CO—NR4—)—, wherein R4 is H, CH3 or C2H5; Y=is absent, is O, S or (—CO—NR5—)—, wherein R5 is H, CH3 or C2H5; n, m=independently of one another in each case mean 1, 2 or 3; R3=H, CH3, C2H5, Cl, Br or OCH3, and wherein the two carboxyl groups of the benzene ring can together form an anhydride group.

Abstract: The invention relates to the use of a composite resin composition comprising (a) at least one polyreactive binder, (b) a first photopolymerization initiator having an absorption maximum at a wavelength of less than 400 nm, (c) a second photopolymerization initiator having an absorption maximum at a wavelength of at least 400 nm and (d) an absorber having an absorption maximum at a wavelength of less than 400 nm, for the stereolithographic production of a dental shaped part based on composite resin. The invention also relates to a process for the stereolithographic production of a dental shaped part and the use of the composite resin composition in this process.

Abstract: Dental material which contains a urea derivative according to general formula I, in which R1 and R2 are in each case independently of each other an aliphatic C1-C15 radical which can be interrupted by —O—, —S—, —CO—O—; X is a radically polymerizable group; Y is a radically polymerizable group or an acid group; n, m are in each case independently of each other 1, 2, or 3.

Abstract: ?-Ketophosphonic acid according to general formula I: in which A=an aliphatic C1-C18 radical which can be interrupted by —O—, —S—, —CO—O— or —O—CO—C—; n=1, 2, 3 or 4; m=1 or 2; X=absent or a C1-C10 radical which can be interrupted by —O—, —S—, —CO—C—, —O—CO—NH— or —CO—NR1—, wherein R1 is H or C1-C7-alkyl; and PG=a group which can undergo free radical polymerization. The ?-ketophosphonic acids are suitable in particular for the preparation of dental materials.

Abstract: The invention relates to a dental restorative material on the basis of at least one compound of Formula I A-[X-Q-(Y-CG)n]m?? Formula I, wherein CG represents in each case independently an azide group N3 or an alkyne group selected from the group consisting of —CR1R2—C?CH, with the proviso that the dental restorative material comprises at least one compound of Formula I comprising an azide group and at least one compound of Formula I comprising an alkyne group. The invention also relates to the use of the dental restorative materials according to the invention for preparing dental composites, preferably composite blanks, which are suitable in particular for mechanical processing by means of computer-aided processing techniques such as milling and grinding processes, and which are suitable above all for preparing dental restoration materials such as inlays, onlays, crowns, bridges or veneering materials.

Abstract: The invention relates to a dental restorative material which comprises a thermolabile compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l??Formula I, in which T represents a thermolabile unit which contains at least one thermolabile group based on non-covalent interactions, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2?CR1—CO—O— and CH2?CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —